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贵州苗龙金矿床毒砂中金的赋存状态研究 总被引：3，自引：2，他引：1
苗龙矿区赋矿地层为寒武系上统三都组灰岩和泥灰岩,矿体严格受断裂构造控制,矿体主要赋存于东西向Fm1、Fm14断裂中。矿床成矿作用可划分为3个期次,即沉积成岩期、热液成矿期和表生氧化期。毒砂为热液成矿期主阶段重要产物之一,主要呈菱形体、针状、柱状及放射柱状集合体产出。通过对毒砂进行电子探针分析及面扫描分析,结果表明毒砂中主成分稳定,w(Fe)为32.47%~35.71%,平均34.05%;w(S)为21.01%~26.38%,平均为23.13%;w(As)为38.50%~44.73%,平均为41.86%。其成分(FeAs0.80S1.17~FeAs1.02S1.21)明显偏离理论毒砂的成分(FeAs1.12S1-x≤|0.13|),具有富硫亏砷等低温热液特征。毒砂含金性较好,w(Au)为0.05%~0.14%,平均为0.06%。面扫描图像中,Au元素分布均匀,说明Au主要以晶格金(固溶体金)形式存在于毒砂中。 相似文献
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川西北地区微细浸染型金矿床，主要产于具轻微变质的沉积岩地层中；矿石中除见极少中一细粒显微状自然金外，金主要呈超（次）显微状赋存于含金矿物中；矿石中与黄铁矿、辉锑矿、雄黄等紧密共生的毒砂，呈针状和梭状，低显微硬度，矿物成分以富硫高铁贫砷，并含金贫银及多种杂质元素。成分复杂的含金低温型毒砂，为寻找该类型金矿的标志矿物之一，并具有成因标型意义。 相似文献
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Benony K. Kortatsi Collins K. Tay Geophrey Anornu Ebenezer Hayford Grace A. Dartey 《Environmental Geology》2008,53(8):1651-1662
Alumino-silicate mineral dissolution, cation exchange, reductive dissolution of hematite and goethite, oxidation of pyrite
and arsenopyrite are processes that influence groundwater quality in the Offin Basin. The main aim of this study was to characterise
groundwater and delineate relevant water–rock interactions that control the evolution of water quality in Offin Basin, a major
gold mining area in Ghana. Boreholes, dug wells, springs and mine drainage samples were analysed for major ions, minor and
trace elements. Major ion study results show that the groundwater is, principally, Ca–Mg–HCO3 or Na–Mg–Ca–HCO3 in character, mildly acidic and low in conductivity. Groundwater acidification is principally due to natural biogeochemical
processes. Though acidic, the groundwater has positive acid neutralising potential provided by the dissolution of alumino-silicates
and mafic rocks. Trace elements’ loading (except arsenic and iron) of groundwater is generally low. Reductive dissolution
of iron minerals in the presence of organic matter is responsible for high-iron concentration in areas underlain by granitoids.
Elsewhere pyrite and arsenopyrite oxidation is the plausible process for iron and arsenic mobilisation. Approximately 19 and
46% of the boreholes have arsenic and iron concentrations exceeding the WHO’s (Guidelines for drinking water quality. Final
task group meeting. WHO Press, World Health Organization, Geneva, 2004) maximum acceptable limits of 10 μg l−1 and 0.3 mg l−1, for drinking water. 相似文献
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位于高要市境内的河台金矿床是目前广东省最大的金矿床,被普遍认为是韧性剪切带型金矿床。为了进一步认识金矿床的成矿环境,对采自河台矿区高村矿段的矿石进行了详细的研究,利用电子探针(EPMA)分析了矿石中毒砂、绿泥石和闪锌矿等矿物的成分。通过矿物温度计计算,毒砂的形成温度在330℃左右,绿泥石的形成温度集中在230~250℃之间,闪锌矿的形成温度在205~230℃之间,可能分别代表成矿早、中、晚期的温度;结合前人包裹体测试结果,推测河台金矿床成矿温度可能在205~250℃之间,属于中低温热液矿床。而糜棱岩的形成温度可能在300~500℃之间,明显高于金矿床的形成温度,因此,河台金矿床可能是动力变质期形成的糜棱岩带在热液期又发生脆性变形,并伴随含矿热液活动,最终导致成矿。在成矿过程中,绿泥石和闪锌矿是随着温度降低而相继连续产出的。在此过程中硫逸度也在不断降低,表现出比较宽泛的特征,lgf(S2)可能介于-20~-1,lgf(O2)可能介于-50~-30。 相似文献
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新疆齐求Ⅰ金矿床毒砂及其在金的成矿过程中的作用 总被引：1，自引：0，他引：1
所研究的毒砂形成两个成矿阶段。成矿前阶段的毒砂具有颗粒粒大、裂隙发育和明显的成分环带等特征。成矿前的裂隙为金的迁移和沉淀提供了良好的空间。成矿期阶段的毒砂颗粒细小,无成分环带。根据形态、分布规律和成分特点,成矿期毒砂可划分为两个世代:早期的,自形程度高,无明显成分异常;晚期的,他形晶,含砷低。毒砂的特性反映了金的成矿作用的演变过程。 相似文献
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Barbara L. Sherriff Kristin A. Salzsauler Stephanie Simpson Nikolay V. Sidenko Jamie VanGulck 《中国地球化学学报》2006,25(B08):29-30
Local water contamination by arsenic can be caused by gold mining activities as in Snow Lake, Manitoba. This project was to f＇md the source （s） and pathways of the arsenic contamination and describe arsenic attenuation in ground and surface water. The project was initiated because arsenic concentrations average 16.0 mg/L in one groundwater monitoring well （MW17）. One potential source of arsenic is the 50 year-old Arsenopyrite Residue Stockpile （ARS）, 100 m upgrade of MW17. Between 1948 and 1959, 250000 tons of cyanide treated, arsenopyrite concentrate were stored in a waste rock impoundment, which was left open until 2000 when it was capped with layers of waste rock, clay and silt to minimize water infiltration and the oxidative release of arsenic. 相似文献
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The Magotteaux Mill® system was used to quantify the galvanic interaction between four types of grinding media (mild steel, 15% chromium, 21% chromium, and 30% chromium media) and arsenopyrite, in situ of the mill. The galvanic current was determined from the polarization curves of individual electrodes, in situ of the mill. The high chromium media had a significantly weaker galvanic interaction with arsenopyrite, and produced a very much lower amount of oxidized iron species in the mill discharge than mild steel medium. Increasing the dissolved oxygen in the mill slurry enhanced galvanic interaction. A theoretical model was developed to describe the relationship between galvanic current and oxidized iron species in the slurry, as measured by EDTA extraction. The electrochemical data were correlated with the measurement of oxidation products after grinding under different conditions. The stronger the galvanic interaction, the higher the amount of hydrophilic oxidized iron species in the mill discharge. 相似文献
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含金毒砂中晶格金的确定及其形成机理研究 总被引：7，自引：0，他引：7
利用电子探针(EPMA)和高分辨透射电子图像(HRTEM)分析技术,对湖南黄金洞金矿含金毒砂进行了背散射电子图像、X-射线面扫描、定量微区分析、线分析以及高分辨晶体结构观测等综合研究。结果表明,含金毒砂中没有发现纳米级乃至更小粒级的超显微包体金,毒砂晶格完整,无任何“异构体”,Au散布于整个毒砂颗粒中,以晶格金形式存在。此外,金含量在不同的生长环带中有显著变化,表明Au是在毒砂形成过程中进入其晶格的。金的加入导致毒砂晶体结构中(100)面网间距局部变宽,晶胞参数也发生了微弱变化,a轴变长。详细分析认为,Au主要是以Au~(3+)替代Fe~(3+)进入AsS~(3-)八面体空位中的,Eh值变化可能是控制毒砂中晶格金形成的主要因素。 相似文献
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毒砂是常见的含砷硫化物矿物。在金属硫化物矿山环境中,含毒砂矿石和尾矿的风化会导致严重的重金属污染,在其风化过程中,微生物能够显著促进毒砂的氧化分解。本文实验研究了Acidithiobacillus ferrooxidans氧化分解毒砂矿物的现象,利用X射线衍射和扫描电子显微镜,分析了毒砂微生物氧化作用形成的次生矿物类型,发现毒砂表面存在As含量明显不同的2类次生产物,观察到黄钾铁矾、臭葱石、自然硫和施威特曼石等矿物;借助光电子能谱仪重点分析了微生物作用前后毒砂晶面的表面化学组成,基本查明了Fe、As和S三种元素的价态变化,初步探讨了毒砂表面次生矿物成因和As的化学态转化。 相似文献