Multiple sulfur isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,China: Implications for a shoaling model of toxic deep-waters     

Masafumi Saitoh  Yuichiro Ueno  Yukio Isozaki  Naohiro Yoshida 《Island Arc》2021,30(1):e12398

Previous studies on multiple sulfur isotopes (³²S, ³³S, and ³⁴S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ³⁴S (<−40 ‰) and high ∆³³S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆³³S values are observed only in the oxic limestones, and no substantial ∆³³S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H₂S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆³³S value of the bulk sediments. The observed ∆³³S variation on a global scale suggests a substantial variation in H₂S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition.  相似文献   

基于元素Mn、Co、Cd、Mo的海相沉积岩有机质 富集因素判别指标在四川盆地北缘的应用     

肖斌  刘树根  冉波  杨迪  韩雨樾 《地质论评》2019,65(6):1316-1330

基于金属元素Mn、Co、Cd、Mo的海洋富有机质沉积岩沉积环境和有机质富集主控因素判别指标Al—Co·Mn和Co·Mn—Cd/Mo,能够有效地区分促进有机碳埋藏的两种海洋端元沉积环境:大陆边缘开放/上升洋流环境和滞留的边缘海盆环境。利用这种方法研究了四川盆地北缘城口县月亮坪剖面五峰组和龙马溪组页岩沉积时期的水体环境和有机质富集的主控因素。研究表明五峰组Mn、Co富集程度低,Mo富集程度自下而上明显增大;龙马溪组Mn整体亏损,Co富集程度低,Mo富集程度自下而上明显减小。Al—Co·Mn方法的使用发现滞留环境主要出现在五峰组早期和龙马溪组晚期,以及观音桥段附近,而五峰组中晚期和龙马溪组早—中期水体主要处于开放/上升洋流区。剖面[w(Co)/(μg/g)]·[w(Mn)/(%)]值均小于平均页岩值1.615;五峰组Cd/Mo值整体大于正常海水值0.006,全部小于平均页岩值0.308,龙马溪组整体小于正常海水值。Co·Mn—Cd/Mo联合图版的使用发现月亮坪剖面五峰组和龙马溪组有机质富集主要受到保存条件控制,与使用U/Th、V/Cr、P/Ti、Ba/Al与TOC相关性分析得出的结论一致。基于金属元素Mn、Co、Cd、Mo的判别指标对于判断古生代大陆边缘地区富有机质页岩沉积环境及有机质富集主控因素有较好的效果。  相似文献   

岩石圈—软流圈物质循环促进大陆增生的新方式     

杨文采 《地质论评》2019,65(5):1039-1053

大陆动力学研究地球内能量和物质的运动和伴随的信息传播,上地幔中的软流圈是地球内部的物质运动的关键部位之一。由于观测的技术方法少,人类对软流圈内部的地质作用过程所知甚少。在青藏高原,过去地震波三维层析成像的分辨率不高,难以对地壳上地幔构造进行准确的定位。我们收集和整理了地方地震台的数字化观测数据,使地震体波三维层析成像的准确度大大提高,为解决软流圈的地质构造准确成像提供了新的可能性。根据地震体波三维层析的成像结果,在古特提斯洋和特提斯洋俯冲板块前沿的软流圈底部410 km间断面上方,存在反映古大洋俯冲板块的高速体,它们在青藏高原、苏鲁和伊朗都有出现。清晰和稳定的高波速异常的位置表明,特提斯洋俯冲板块现在已经拆沉在软流圈的底部,古特提斯洋俯冲板块也可能曾经拆沉在软流圈的底部。对比青藏高原和苏鲁的地壳上地幔波速结构推测,拆沉造成软流圈中的轻元素物质上涌,进入大陆岩石圈,造成岩浆活动。上涌还使碰撞造山带地壳厚度减小,而岩石圈厚度增加。大约100 Ma后,俯冲下去的大洋残块会被软流圈物质磨蚀交代,使岩石圈厚度增加, 形成大陆下方的大陆根,造成大陆克拉通化和体积增生。大洋板块俯冲后在软流圈拆沉是岩石圈—软流圈物质循环的一种重要方式,对软流圈中物质均衡和体积稳定也起重要作用。  相似文献   

大陆岩石圈伸展与斑岩铜矿成矿作用   总被引：1，自引：0，他引：1  

李晓峰  华仁民  马东升  徐净  张龙  齐有强  武丽艳  朱艺婷 《岩石学报》2019,35(1):76-88

华南地区自古生代以来一直属于陆内构造演化环境。华南陆内伸展型斑岩铜矿主要形成于早侏罗世、晚侏罗世和早白垩世3个时期,其中晚侏罗世成矿期与华南中生代大规模钨锡成矿作用的形成基本属于一个时期。这些斑岩型矿床的时空分布与同时期的俯冲带在时间上和空间上具有明显不协调的关系,且与俯冲有关的、后俯冲伸展背景以及陆陆碰撞有关的斑岩铜矿的线性分布特点明显不同,尤其是早白垩世斑岩铜矿的分布明显呈面状分布,与华南中生代地壳明显减薄的区域基本一致。虽然这3个时期的斑岩型铜矿在地球化学上显示出弧岩浆岩的特点,但是地质事实证明在这3个时期,华南岩石圈发生了明显的伸展作用,尽管每个时期华南不同地区岩石圈伸展的程度可能不同。因此,我们把华南这种类型的斑岩铜矿归称之为"陆内伸展型"斑岩铜矿。陆内伸展型斑岩铜矿的成矿机制可能是岩石圈伸展背景下软流圈上涌导致陆下岩石圈地幔或者下地壳被改造有关。  相似文献   

华北新构造：印欧碰撞远场效应与太平洋俯冲地幔上涌之间的相互作用   总被引：1，自引：0，他引：1  

张岳桥  施炜  董树文 《地质学报》2019,93(5):971-1001

作为大陆内部典型的伸展断陷区和强震活动区,华北地区处于东部太平洋板块俯冲构造和西部印欧大陆碰撞构造的双重大地构造背景之下,其新构造运动相当复杂:西部沿鄂尔多斯地块周缘两个地堑盆地系引张伸展断陷作用、中部太行山块体的局部断陷和整体隆升、东部华北平原区和渤海湾海域区的区域沉降,南缘沿秦岭构造带的左旋走滑拉张活动,东缘沿郯庐断裂带的右旋挤压走滑活动。这些不同类型的断裂构造在晚新生代的阶段性活动,产生了复杂的构造地貌组合特征。综合研究发现,华北晚新生代经历了3期伸展断陷-挤压隆升演化阶段:新近纪晚期(10～2.5 Ma)、早中更新世和晚更新世以来。地壳引张应力方向或NW-SE、或NE-SW向;地块隆升导致湖盆的消亡,挤压应力方向为NE-SW至W-E向。研究认为,华北地区新构造受两个岩石圈构造过程的相互影响:印欧碰撞产生的远程效应和东部岩石圈地幔的上涌。一方面,青藏高原东北缘地块的持续推挤及其构造应力向东的传递导致鄂尔多斯地块反时针旋转和秦岭山地的向东挤出逃逸,这个挤出构造动力学统治了华北地区晚新生代的引张伸展、斜张走滑和挤压变形。尤其是,新近纪晚期强烈的NW-SE向地壳伸展变形与青藏东缘挤出造山作用同步(10～9 Ma至4.2 Ma);上新世末期(约2.5 Ma)、晚更新世早期(约200～70 ka)和晚更新世晚期—全新世(约20 ka以来)3次构造挤压事件与青藏高原东缘构造事件基本对应。另一方面,岩石圈地幔上涌主导了华北东部平原区的区域地壳沉降,同时伴随着早、中更新世的5期幔源火山活动。这两个岩石圈构造作用力此消彼长,深刻统治着华北地区新构造与现今活动构造以及地震构造。  相似文献   

Effects of the seasonal variation in chlorophyll concentration on sea surface temperature in the global ocean     

Jinfeng Ma  Hailong Liu  Pengfei Lin  Haigang Zhan 《海洋学报(英文版)》2021,40(11):50-61

The effects of biological heating on the upper-ocean temperature of the global ocean are investigated using two ocean-only experiments forced by prescribed atmospheric fields during 1990–2007, on with fixed constant chlorophyll concentration, and the other with seasonally varying chlorophyll concentration. Although the existence of high chlorophyll concentrations can trap solar radiation in the upper layer and warm the surface, cooling sea surface temperature (SST) can be seen in some regions and seasons. Seventeen regions are selected and classified according to their dynamic processes, and the cooling mechanisms are investigated through heat budget analysis. The chlorophyll-induced SST variation is dependent on the variation in chlorophyll concentration and net surface heat flux and on such dynamic ocean processes as mixing, upwelling and advection. The mixed layer depth is also an important factor determining the effect. The chlorophyll-induced SST warming appears in most regions during the local spring to autumn when the mixed layer is shallow, e.g., low latitudes without upwelling and the mid-latitudes. Chlorophyll-induced SST cooling appears in regions experiencing strong upwelling, e.g., the western Arabian Sea, west coast of North Africa, South Africa and South America, the eastern tropical Pacific Ocean and the Atlantic Ocean, and strong mixing (with deep mixed layer depth), e.g., the mid-latitudes in winter.  相似文献   

青岛近海物理-生物地球化学过程及其生态响应     

韦钦胜  王保栋  姚庆祯  于志刚  傅明珠  孙俊川  许博超  谢琳萍  辛明 《海洋学报(英文版)》2019,38(2):11-23

近些年来，夏季黄海浒苔大规模暴发，并在青岛近岸海域大面积聚集，引起了广泛的关注。本文基于在夏季和冬季所获得的多学科调查资料，重点研究了青岛近海的水文-生物地球化学过程及其生态影响，阐明了该海域物理-化学-生物等多参数之间的耦合响应。研究显示，夏季黄海冷水团的边界可扩展至青岛近岸海域，并在局部涌升至上层水体，形成沿岸上升流；该上升流可对上层营养盐产生一定的补充，进而促进浮游植物的繁殖，并于底层海域对应形成溶解氧（DO）和pH的低值。夏季青岛近海的上升流可能还有利于随南风漂移至此的浒苔的生长，并在一定程度上引起浒苔的局地旺发；同时，夏季该海域特定的锋面系统对浒苔聚集的影响也不容忽视。冬季黄海暖流在苏北浅滩外侧向山东半岛南部海域延伸，扩展至青岛近海的暖水舌与近岸低温水之间的锋面特征明显，而且在向岸暖水与近岸冷水间还对应形成了明显的营养盐和叶绿素（Chl-a）锋面。该项研究从多学科交叉的视角，增进了对青岛近海物理、化学和生物过程之间耦合关系的认识。  相似文献   

孟加拉湾的叶绿素a,海表温度和风速的趋势     

Danushka FERNANDO  唐丹玲  徐华兵 《南京气象学院学报》2018,10(3):334-341

孟加拉湾（BoB）是一个高能量活跃的地区,其短期内的动态变化将对浮游环境产生巨大影响."风泵"能够在BoB海域导致垂直的混合从而影响海表温度和叶绿素浓度.本文对2006——2016年的月平均Aqua-MODIS叶绿素a （chl-a）浓度数据和Sea WiFS月度气候态数据进行了分析,研究了叶绿素浓度的时间/季节变化和温度以及风速的关系.基于季风期间的chl-a变异与海表温度（SST）,评估了在BoB海域它们之间的关系和变化.chl-a浓度值的趋势分析表明,该区域的垂直混合非常低,冬季最高,夏季最低.冬季最大chl-a浓度值为0.50 mg/m³,并且从2月开始下降到夏季季风期间.与冬季季风相比,夏季季风期间叶绿素表现出较低的浓度.在夏季季风期间,特别是在7月和8月,由于云层密集,卫星传感器无法准确捕获chl-a浓度值.chl-a浓度和SST之间相关系数R²值为0.218 1.  相似文献   

Spatial Distribution of Shelf- and Slope-Dwelling Fishes Collected by Bottom Longline off Lanzarote and Fuerteventura, Canary Islands     

Franz  Uiblein  Fernando  Bordes  Ricardo  Castillo Antonio G.  Ramos 《Marine Ecology》1998,19(1):53-66

Abstract. A total of 1789 fish belonging to 38 families and 73 species were collected at depths between 18 and 1102 m during 216 bottom longline operations off Lanzarote and Fuerteventura, Canary Islands, between February 1994 and December 1995. For each species the depth distribution is provided. Length-weight and depth-size relationships are reported for three shelf-dwelling species. The bigger-deeper relationship found in two of them contrasts with the bigger-shallower pattern of the deeper living trichiurid Lepidopus caudatus . In November 1997, nine additional bottom longline operations were carried out off eastern Fuerteventura at depths between 805 and 1217 m. In this area, after earlier studies in October 1995, a spawning aggregation of the morid Mora moro was encountered for the second time. The catches of 1997 revealed a strongly male-biased sex ratio. Also, the males showed a significantly lower gonadosomal index than two years earlier. These findings indicate slight interannual variations in reproductive timing and an earlier arrival of male Mora moro at the spawning grounds. Clear variations in the number of fish collected at adjacent sites possibly reflect a preference for distinct microhabitats. Preliminary evidence of local upwelling of cold water above the spawning grounds is provided by satellite imagery.  相似文献   

Numerical studies of upwelling in coastalareas of the East China Sea——Ⅰ The tide-induced upwelling     

Luo Yiyong  Yu Guangyao  Huang Zuke 《海洋学报(英文版)》1998,17(1):15-25

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