等离子体发射光谱法测定重晶石中钡铁和硅   总被引：3，自引：0，他引：3  

杨德君  陈利平 《岩矿测试》1998,17(4):317-318

重晶石经Ｎａ２ＣＯ３熔融,水浸取,过滤。沉淀经ＨＣｌ溶解后,用电感耦合等离子体发射光谱法同时测定主成分ＢａＳＯ４和次量成分Ｆｅ２Ｏ３以及滤液中的ＳｉＯ２,结果与部颁标准方法符合。方法精密度好,主量组分ＢａＳＯ４测定的ＲＳＤ（ｎ＝６）为０．２４％,次量组分Ｆｅ２Ｏ３和ＳｉＯ２的ＲＳＤ（ｎ＝６）分别是３．６９％和１．４５％。  相似文献   

钍石的新变种——铅钍石     

严春杰  杨光明 《地质科技情报》1997,16(2):29-31

铅钍石是钍石的新变种，属首次发现。其ＰｂＯ含量达９．０４％，由此引起其性质的变化，如比重、硬度、折光率和晶胞参数均小于铀钍石，并可根据红外吸收谱判断铅钍石的变生程度。  相似文献   

Geochemical Investigations of Stratabound Gunga Barite Deposits of Khuzdar (Balochistan), Pakistan     

Viqar HUSAIN  Hameedullah KHAN  Klaus GERMANN  Karel ZAK 《Resource Geology》2002,52(1):49-58

Abstract: The Gunga barite deposits occur in carbonate clastic marine sequence of Jurassic age. These rocks are widely spread in Khuzdar-Lasbela belt which host important stratabound barite and zinc-lead deposits of Pakistan. These rocks are intricately folded and extensively faulted. The Gunga are low temperature hydrothermal deposits occurring as a series of disconnected lenses a few meters thick. Two mineralized horizons are recognized: barite in the upper zone, sphalerite and galena in the lower zone. Four types of barite mineralization occurs in Gunga stratabound replacement associated with 1) fracture filling, 2) open space fillings in solution collapsed breccia, 3) replacement in fault, and 4) veinlets associated with all these three types. The wall rocks of the Gunga deposits have also been altered by silicification, leaching and ferruginization.
The sulfur isotope values of most of the Gunga barite samples range from 23.8 to 27.8 per mil with an average of 26.4 per mil, which is very close to the average of isotopic values of epigenetic carbonate hosted Late Paleozoic Missouri barite deposits. The Gunga like other barite and sulfide deposits of Khuzdar-Lasbela belt are Mississippi Valley type, stratabound and of replacement origin precipitated from connate brines expelled during the incipient rifting of India from Gondwana land in the Late Jurassic and Early Cretaceous periods. The low content of copper, lead and zinc in the Gunga barite deposits suggests that these deposits were not formed in proximity to an igneous source of the ore solution.
The Gunga deposits are epigenetic and stratabound as their mineralization is structure controlled. There is an evidence of transgressive nature of host rock and wall rock alteration which are absent in stratiform or bedded deposits.  相似文献   

天柱大河边-新晃重晶石矿床矿物组成特征的电子探针研究   总被引：10，自引：0，他引：10  

夏菲  马东升  潘家永  陈少华  曹双林  孙占学  刘成东  郭国林 《矿物学报》2005,25(3):289-294

通过对天柱大河边—新晃重晶石矿床系统的剖面勘查和采样分析,对矿石和围岩进行了系统的电子探针研究。发现在该矿床的矿石中广泛分布有钡冰长石。在研究钡冰长石及其共生矿物（重晶石、黄铁矿等）的化学组成、光学性质及其相互关系的基础上,对钡冰长石的成因进行了分析,进而对矿床的成因作了进一步探讨,为天柱大河边—新晃重晶石矿床热水沉积成因提供了新的证据。  相似文献   

几种矿物的超细加工及对建材防氡防辐射性能的影响   总被引：3，自引：0，他引：3  

何登良  董发勤  邓跃全  徐光亮 《矿物岩石》2005,25(3):127-130

采用湿法搅拌磨和气流磨,对用作防氡防辐射基元材料原料的重晶石、沸石进行超细加工和激光粒度分布测试,结果表明：重晶石、沸石通过湿法和干法粉磨加工,在一定的时间内都可以超细粉碎到d90小于10μm,从粉磨时间以及粉磨成本来比较干磨法要明显优于湿磨法;重晶石进行超细加工后所制备的水泥砂浆的外照射指数从0．51降到0．23,重晶石所配腻子的氡和放射性屏蔽率提高20％～30％。当沸石的粒度减小时,水泥砂浆对氡的屏蔽率提高的屏蔽率最大达26％。沸石从119μm降到18μm时,腻子的防氡率从37．9％提高到53．1％。防辐射性能从整体上来看是粒度越细性能越好。  相似文献   

黔东早寒武世早期重晶石富集机制研究——来自硫同位素的约束     

王富良  黄艺  付勇  龙克树  文星桥 《地球学报》2020,41(5):686-698

在中国, 早寒武世早期重晶石矿床主要展布于扬子地台北缘秦岭—大巴山一带及扬子地台东南缘湘黔地区, 而黔东天柱大河边重晶石矿床已探明的资源储量就达到了2亿多吨, 是全国, 乃至世界上所罕见的超大型重晶石矿床。近年来, 于大河边重晶石矿床北西翼亦发现了赋存于同一层位的云洞重晶石矿床, 但二者的成矿特征却表现出显著的差异。本文对比了含矿较差的云洞重晶石矿床与高品位大河边重晶石矿床的含矿岩系、沉积相、地球化学特征等。结果表明两者之间的缺氧程度、热水作用强度存在明显差异。综合矿床地质和有机质、硫同位素特征, 提出成矿作用与生物活动和同期海底热液活动关系密切, 矿床中SO2– 4来源于海水硫酸盐, Ba2+来自海水和海底热液。大河边地区与云洞地区相比, 水位更浅, 氧逸度更高, 硫酸盐还原程度更弱, 剩余硫酸盐的浓度更高, 从而导致云洞重晶石矿床表现出较大河边重晶石矿床成矿性差的特征。  相似文献   

广西大瑶山西侧层控矿床成因类型及成矿机理     

袁少平  张振贤  周怀玲 《南方国土资源》1989,(4)

本文根据《广西大瑶山西侧泥盆系铅锌黄铁矿床控矿条件及成矿预测研究》成果,按照沉积演化观点,将本区层控矿床成固类型划分为成岩矿床、成岩—后生矿床和后生矿床。成矿物质主要来源于赋矿地层下泥盆统及基底岩石,成矿溶液主要为大气降水经深循的渗流热卤水,成矿物质的聚集与成岩后生作用有关,矿床的形成可分为沉积、成岩、后生三个阶段,并建立了成矿模式。  相似文献   

Barite concretions as evidence of pauses in sedimentation in the Marnes Bleues Formation of the Vocontian Basin (SE France)     

Jean-G. Brhret  Hans-J. Brumsack 《Sedimentary Geology》2000,130(3-4):205-228

Several intervals rich in barite nodules occur in the mid-Cretaceous marls of the Vocontian Trough (SE France). These concretions, which grew on heterogeneities in the sediment, are arranged as horizons parallel to the bedding, and are often associated with carbonate and phosphate nodules. Detailed sedimentological and stratigraphical observations suggest that they represent the consequence of short-term pauses in sedimentation during early diagenesis, but the most important occurrences of barite are below prominent discontinuities. This may be explained by the frequency of pauses in sedimentation caused by a progressive starvation, or an increase in the energy of bottom-water currents. The high number of barite occurrences on the basin margins is directly linked to the recurrence of sedimentary breaks. The geochemical data show that the host sediment corresponds to a pelagic setting, far from hydrothermal influences, but generally in a restricted, dysoxic to suboxic, depositional environment. The sulphur isotopic composition of the barite sulphate (+16 to +76‰ rel. CDT) supports the hypothesis of an early diagenetic origin of the barite nodules. Their genesis may be explained by the fixation of a diagenetic front corresponding to the penetration of a sulphate reduction zone from the seawater–sediment interface down in the sediment which is in contact with barium-rich porewaters expelled upwards as a consequence of compaction. The barium of biogenic origin, initially stored in the underlying black shale, was mobilized under strongly reducing conditions. Such fixation is normally induced by a pause or a stop in sedimentation due to starvation or renewed bottom-water circulation. Together with other concretions, the barite nodules mark condensed stratigraphic intervals and often represent major breaks. As such they shed light on variations in sedimentary activity and their importance in the sedimentology and stratigraphy of pelagic marly sequences cannot be ignored.  相似文献   

贵州镇宁乐纪泥盆系重晶石矿热水沉积特征   总被引：6，自引：0，他引：6  

高军波  杨瑞东  陶平  魏怀瑞  刘坤 《沉积学报》2012,30(3):422-430

贵州镇宁乐纪泥盆系重晶石矿床地质储量3 302万t,属大型矿床类型。通过对矿床沉积结构、构造特征研究发现,矿床（体）中分布:纹层状构造、条带状构造、角砾状构造、碎屑状构造、块状构造等,它们与天柱-大河边重晶石矿、广西古潭热水沉积重晶石岩及北秦岭二郎坪群热水沉积重晶石岩类似,海底热水喷流形成的热水喷流通道相、单一热水沉积岩相及热水混合同生沉积相在镇宁重晶石矿层中广泛分布,共同构成了热水浊流沉积相,这与秦岭泥盆系热水沉积岩（矿）类似,矿层沉积结构、构造及岩相特征很好的记录了海底热水喷流、演化的信息,沉积韵律特征说明了热水喷流由弱-强-弱的变化过程。海底热水喷流沉积形成的镇宁重晶石矿中热水沉积结构、构造及热水沉积岩相发育,是研究古热水喷流沉积成岩、成矿、划分热水沉积岩相的理想场所。  相似文献   

X射线荧光光谱法测试重晶石中的多元素     

周国兴  赵恩好  岳明新  曹丹红  肖刚  张泉 《地质与资源》2014,23(3):292-295

采用玻璃熔片法制样,建立了重晶石中多元素X射线荧光光谱分析方法.准确称取待测样品0.5000 g,X射线荧光专用熔剂5.000 g;二者混合后,通过高频熔样机在1150℃进行熔片处理8 min;将最终得到的样片放入干燥器中冷却至室温,然后准确称取玻璃片质量;上机测试,所得到的数据为该元素在玻璃片中的含量;通过换算最终得到实际样品中的该元素含量.使用理论α系数法和经验系数法相结合来回归校正共存元素间的吸收增强效应.本方法对于重晶石中各元素的测试相对标准偏差处于0.2%~4.7%之间,方法检出限在3.3×10^-6~170.6×10^-6之间.测试数据通过与国家标准物质比对,结果合理.  相似文献