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71.
江西武山花岗闪长斑岩与矽卡岩铜矿在成因上密切相关,通过对其中的黑云母进行的岩相学观察和详细的矿物化学分析来探讨黑云母的形成条件及其成岩成矿意义。电子探针分析结果表明,武山花岗闪长斑岩中的黑云母富镁贫铁低铝高钛,属镁质黑云母。其AlⅥ为0.03~0.19,w(ΣFeO)/w(ΣFeO+MgO)为0.531~0.567,w(MgO)为12.80%~14.06%,指示武山花岗闪长斑岩属壳幔混源的I型花岗岩。黑云母结晶的温度为720℃~750℃,logfO2为-11.6~-12.5,压力为86 MPa~103 MPa,对应的侵位深度为2.84 km~3.39 km,表明该岩体形成于相对高温较浅环境,具有较大成矿潜力,有利于武山铜矿的形成。  相似文献   
72.
73.
Abstract: The Mamut deposit of Sabah, East Malaysia, is a porphyry type Cu‐Au deposit genetically related to a quartz monzonite (“adamellite”) porphyry stock associated with upper Miocene Mount Kinabalu plutonism. The genesis of the Mamut deposit is discussed based on petrology of the intrusives in the Mount Kinabalu area combined with ore– and alteration–petrography, fluid inclusion and sulfur isotope studies. Groundmass of the adamellite porphyry at Mamut is rich in K which suggests vapor transport of alkaline elements during the mineralizing magmatic process, while the groundmass of the post‐ore “granodiorite” porphyry at Mamut contains small amounts of normative corundum suggesting depletion in alkaline elements at the root zone of the magma column. Sub‐dendritic tremolitic amphibole rims on hornblende phenocrysts in the Mamut adamellite porphyry suggest interaction between the mineralizing magma and the exsolved fluids. Occurrences of clinopyroxene microphenocrysts and pseudomor‐phic aggregates of shredded biotite and clinopyroxene after hornblende phenocrysts in the barren intrusives imply lower water fugacity and decreasing in water fugacity, respectively. Compositional gap between the core of hornblende phenocrysts and the tremolitic amphibole rims and those in the groundmass of the Mamut adamellite porphyry suggests a decrease in pressure. Higher XMg (=Mg/(Mg+Fe) atomic ratio) in the tremolitic amphibole rims in the Mamut adamellite porphyry compared to those of the barren intrusions suggests high oxygen fugacity. High halogen contents of igneous hydrous minerals such as amphiboles, biotite and apatite in the Mamut adamellite porphyry suggest the existence of highly saline fluids during the intrusion and solidification of the mineralizing magma. Fluid inclusions found in quartz veinlet stockworks are characterized by abundant hypersaline polyphase inclusions associated with subordinate amounts of immiscible gaseous vapor. Both Cu and Au are dispersed in disseminated and quartz stockwork ores. Chalcopyrite and pyrrhotite as well as magnetite are the principal ore minerals in the biotitized disseminated ores. Primary assemblage of intermediate solid solution (iss) and pyrrhotite converted to the present assemblage of chalcopyrite and pyrrhotite during cooling. Subsequent to biotitization, quartz veinlet stockworks formed associated with retrograde chlorite alteration. The Cu‐Fe sul–fides associated with stockwork quartz veinlet are chalcopyrite and pyrite. Overlapping Pb and Zn and subsequent Sb mineralizations were spatially controlled by NNE‐trending fractures accompanying the phyllic and advanced argillic alteration envelope. Sulfur isotopic composition of ore sulfides are homogeneous (about +2%) throughout the mineralization stages. These are identical to those of the magmatic sulfides of Mount Kinabalu adamellitic rocks.  相似文献   
74.
Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion originated during the late stage of plate subduction. Its related Ta'ergou and Xiaoliugou deposits are two of the few large tungsten deposits formed in the plate subduction environment in the world. The U-Pb dating of the zircons from the biotite granite gave a discordant lower intercept age of 183±4 Ma, which implies that the Yanshanian event was probably superimposed on the North Qilian region.  相似文献   
75.
Biotite‐rich selvedges developed between mafic schollen and semipelitic diatexite in migmatites at Lac Kénogami in the Grenville Province of Quebec. Mineral equilibria modelling indicates that partial melting occurred in the mid‐crust (4.8–5.8 kbar) in the range 820–850°C. The field relations, petrography, mineral chemistry and whole‐rock composition of selvedges along with their adjacent mafic schollen and host migmatites are documented for the first time. The selvedges measured in the field are relatively uniform in width (~1 cm wide) irrespective of the shape or size of their mafic scholle. In thin section, the petrographic boundary between mafic scholle and selvedge is defined by the appearance of biotite and the boundary between selvedge and diatexite by the change in microstructure for biotite, garnet, plagioclase and quartz. Three subtypes of selvedges are identified according to mineral assemblage and microstructure. Subtype I have orthopyroxene but of different microstructure and Mg# to orthopyroxene in the mafic scholle; subtype II contain garnet with many mineral inclusions, especially of ilmenite, in contrast to garnet in the diatexite host which has few inclusions; subtype III lack orthopyroxene or garnet, but has abundant apatite. Profiles showing the change in plagioclase composition from the mafic schollen across the selvedge and into the diatexite show that each subtype of selvedge has a characteristic pattern. Four types of biotite are identified in the selvedges and host diatexite based on their microstructural characteristics. (a) Residual biotite forms small rounded red‐brown grains, mostly as inclusions in peritectic cordierite and garnet in diatexite; (b) selvedge biotite forms tabular subhedral grains with high respect ratio; (c) diatexite biotite forms tabular subhedral grains common in the matrix of the diatexite; and (d) retrograde biotite that partially replaces peritectic cordierite and garnet in the diatexite. The four groups of biotite are also discriminated by their major element (EMPA) and trace elements (LA‐Q‐ICP‐MS) compositions. Residual biotite is high in TiO2 and low in Sc and S, whereas retrograde biotite has high Al2O3, but low Sc and Cr. Selvedge and diatexite biotite are generally very similar, but selvedge biotite has higher Sc and S contents. Whole‐rock compositional profiles across the selvedges constructed from micro‐XRF and LA‐Q‐ICP‐MS analyses show: (a) Al2O3, FeO, MgO and CaO all decrease from mafic scholle across the selvedge and into the diatexite; (b) Na2O is lowest in the mafic scholle, rises through the selvedge and reaches its maximum about 20–30 mm into the diatexite host; (c) K2O is lowest in the mafic scholle and reaches its highest value in the first half of the selvedge, then declines before reaching a higher, but intermediate value, about 20 mm into the diatexite. Of the trace elements, Cs and Rb show distributions very similar to K2O.  相似文献   
76.
石榴石-黑云母地质温度计在四川拉拉铜矿床的应用   总被引:7,自引:0,他引:7  
何德锋  钟宏  朱维光 《矿物学报》2008,28(2):127-134
在晋宁运动中,拉拉铜矿床区发生了大规模的区域变质作用,由于其变质条件的资料较少,使得人们对矿床的成因机制存在诸多争论.采用石榴石-黑云母地质温度计和多硅白云母地质压力计,结合电子探针分析结果,对矿区内广泛出露的石榴石黑云母片岩进行了研究,得到区域变质作用的变质温度为500~560 ℃,变质压力上限为0.6~0.73GPa,变质程度为高绿片岩相.同时,根据野外观测及室内研究并结合前人工作,认为矿床主要存在两个成矿期次,即火山-喷气沉积成矿期和变质热液成矿期.  相似文献   
77.
The garnet (Grt) and biotite (Bt) from gneisses of the Ji’an Group are characterized by diffusion zoning at the rim, but equilibrium composition of metamorphic peak is usually remained in extensive interior area. Garnet with growth zoning is also found in the kyanite zone. In the light of microarea compositional variation of Grt and Bt, the temperature and pressure at the progressive, peak and post-peak metamorphic stages are determined by correctly using Grt-Bt thermometer and GASP barometer. On this basis, a counterclockwiseP-T-t path can be constructed, which reflects the closing process of an ensialic rift belt in this region during the Early Proterozoic. The project was financially supported by the State Educational Commission Ph. D. Station Foundation (No. 96018702).  相似文献   
78.
皖南中生代中酸性侵入岩中普遍含有黑云母,按其成分可分为:镁质黑云母、铁质黑云母和黑鳞云母3类,其MF值和∫O_2依次为0.56—0.60,0.42—0.46,0.06—0.13和10~(-12),10~(-14),10~(-18)左右。其寄主岩石的成因类型分别为扬子式同熔型、江南式同熔型和改造型。它们分别占据不同的地区,是不同大地构造单元上的产物。黑云母成分的变化是大地构造环境差异的标志。  相似文献   
79.
罗荣根 《岩矿测试》2016,35(4):420-424
载金炭对汞有较强的吸附性,易造成黄金生产工艺污染及活性炭吸附金的活性降低,需测定载金炭中的汞含量以监控汞的危害。应用目前测定汞的分析方法在样品前处理过程中需要高温去除基体炭,但容易造成汞的挥发损失。本文采用固体测汞仪在不需样品前处理及不加入其他试剂的情况下实现了载金炭中总汞的直接测定,载金炭最优热解条件为空气流速0.8~1.2 L/min,蒸发温度680~740℃,汞的回收率达到99%以上。样品在热解过程中基体炭转化成二氧化碳,二氧化碳的干扰可由仪器自动消除,所以基体炭对汞的测定无明显影响。全流程的管道不足50 cm,且整个管道处于较高温度之下,通过加大空气流速可快速消除管道上残余的汞,减少了记忆效应的影响。本方法的相对标准偏差小于8.0%,测定下限为0.014μg/g,汞的测试结果与原子荧光光谱法基本吻合。  相似文献   
80.
黑云母是花岗质岩石中常见的造岩矿物,其成分可以有效指示花岗岩形成的物理化学条件和岩石成因。巴斯铁列克矿床是近年来在新疆阿尔泰造山带南缘发现的首例二叠纪矽卡岩型钨多金属矿床。矿区出露多种类型二叠纪含钨花岗岩。为理清花岗质岩体之间、岩体与钨多金属矿化之间的关系,文章采用电子探针测定了黑云母花岗岩、二长花岗岩、二云母花岗岩和钾长花岗岩中的黑云母成分。结果表明,所有黑云母具有富铁、高铝、贫镁特征,含铁指数(Fe2+/(Mg+Fe2+))为0.66~0.80,二云母花岗岩属铁质黑云母而黑云母花岗岩、二长花岗岩和钾长花岗岩属铁叶黑云母。所有岩石是具有A型特征的I型花岗岩。不同类型岩石中黑云母的成分差异与岩浆来源、分异演化程度有关。二云母花岗岩中黑云母的w(MgO)与结晶温度最高,与黑云母平衡流体的log(fHF/fHCl)值(-1.13~-1.25)最低,log(fH2O/fHF)值(4.64~4.96)最高,母岩浆相对富Cl;黑云母花岗岩中log(fHF/fHCl)值最高,log(fH2O/fHF)最低,与二长花岗岩是同一岩浆房不同演化阶段的产物,与二云母花岗岩和钾长花岗岩属不同的岩浆体系,母岩浆相对富F元素。黑云母花岗岩与W矿化关系更密切。  相似文献   
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