Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements          下载免费PDF全文

Guillaume Siron  Lukas Baumgartner  Anne‐Sophie Bouvier  Benita Putlitz  Torsten Vennemann 《Geostandards and Geoanalytical Research》2017,41(2):243-253

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.  相似文献   

阿尔泰造山带南缘昆格依特岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义   总被引：1，自引：0，他引：1  

张亚峰  蔺新望  王星  郭岐明  赵端昌  吕军利  王旭 《现代地质》2014,28(1):16-28

昆格依特岩体出露于阿尔泰造山带南缘青河县大青格里河昆格依特一带,主要为角闪黑云英云闪长岩。LA-ICP-MS锆石U-Pb定年结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为(403.4±7.4)Ma,表明该岩体形成于早泥盆世。岩体的SiO₂含量介于52.39%~71.89%之间,里特曼指数为0.68~1.53,A/CNK 值为0.76~1.06,属中钾、钙碱性、准铝质-弱过铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Hf、Ti等高场强元素和重稀土元素,弱的负Eu异常(δEu=0.56~0.86)的岛弧岩浆岩特征。结合区域地质资料,认为阿尔泰造山带南缘早泥盆世昆格依特岩体形成于活动大陆边缘的陆缘弧构造环境,是古亚洲洋俯冲过程中幔源的基性岩浆底侵下地壳使之熔融,并发生了岩浆混合和分异作用的产物。  相似文献   

内蒙古化德县沙拉哈达石英脉型钨矿床成矿地质特征     

王佳新  张雪旎  张赋 《地质与资源》2014,23(2):154-157

沙拉哈达钨矿区处于内蒙地轴北缘和大兴安岭地槽褶皱系的交接处.矿化主要分布在安山玢岩内,矿体主要由含矿石英脉组成,矿脉中普遍含黑钨矿、白钨矿、黄铁矿及多金属硫化物.与钨矿有关的侵人岩体主要是燕山期黑云母花岗岩及花岗斑岩.围岩蚀变以硅化、云英岩化、绢云母化为主.该矿床属高温热液成因类型.  相似文献   

江西金鸡窝铜矿床花岗闪长斑岩黑云母矿物学特征及其对岩石成因与成矿的指示     

杜后发  赖天功  江媛媛  范鹏飞  龚维强 《岩石矿物学杂志》2017,36(3):329-342

通过对金鸡窝铜矿区花岗闪长斑岩进行详细的岩相学研究和黑云母成分的电子探针原位分析,厘定了黑云母形成的物理化学条件,并探讨了其成岩成矿意义。电子探针研究显示:花岗闪长斑岩中黑云母的Ti为0.44~0.47apfu,Mg/(Mg+Fe)比值范围为0.58~0.62,结合其化学成分在10 TiO_2-Fe O*-Mg O图解和Mg-(Fe2++Mn)-(AlⅥ+Fe3++Ti)图解中的投影,认为该岩体中黑云母具有富镁贫铁特征,属于原生黑云母。黑云母氧化系数(fO)范围为0.31~0.67,MF值范围为0.38~0.41,Mg O含量为13.27%~14.28%,K2O为3.59%~8.93%,Na2O为0.26%~3.28%,Fe O为15.74%~17.30%,TiO_2为3.93%~4.19%,Al2O3为13.52%~14.19%,单位分子中阳离子数AlⅣ为2.00~2.24 apfu,AlⅥ为0.15~0.41 apfu,指示其岩体属于高钾质钙碱性系列的同熔型(或I型)花岗岩,具有壳幔混源成因的特征。黑云母结晶温度为734~748℃,结晶压力为71~89 MPa,相当于深度2.7~3.3 km,平均深度为3.0 km。黑云母化学成分投点主要落在Fe2O3-Fe3O4缓冲线之上,表明其形成于高氧逸度环境,且有利于铜矿的形成。  相似文献   

赣中盛源盆地及邻区橄榄玄粗岩系列火山岩中黑云母化学成分特征     

谭桂丽  吴俊奇  凌洪飞  陈培荣 《火山地质与矿产》2010,(1):19-24

本文利用电子探针技术对赣中盛源盆地及邻区橄榄玄粗岩系列火山岩中黑云母的类型、化学成分及结晶时的温度和氧逸度条件等进行了研究。黑云母为镁质黑云母;结晶时温度的大致范围为1060℃～1100℃,氧逸度大致范围为10^-7bar-10^9bar。本文研究表明,黑云母的化学成分研究是揭示岩石成因类型的一种有效途径,可为研究岩体成因类型以及成岩时的物理化学条件提供依据,并对成岩具有重要的指示意义。  相似文献   

西藏甲玛铜多金属矿床角岩中黑云母矿物化学特征及地质意义   总被引：3，自引：0，他引：3  

王崴平  唐菊兴  应立娟 《地球学报》2012,33(4):444-458

甲玛铜多金属矿床角岩中黑云母按其产状可区分为原生黑云母和热液黑云母,本文采用扫描电镜对两类产出状态的黑云母进行了观察,采用电子探针(EPMA)对这两类黑云母进行了微区原位成分分析,并根据电子探针数据计算了黑云母的矿物化学式。角岩中的原生黑云母和热液黑云母均属于镁质黑云母,二者都经受了热液流体的改造作用。从原生黑云母到热液黑云母Fe3+和Fe2+分异程度加大,Fe3+含量升高,Fe2+含量降低,指示了岩浆-热液流体逐渐向氧化态过渡。相比于原生黑云母,Cu元素更易于在热液黑云母中富集。角岩型矿石中的Cu含量与热液黑云母的Fe2+/(Fe2++Mg2+)比值呈正相关,与其Fe3+/Fe2+比值呈负相关,对于热液黑云母所在的角岩型岩矿石样品,其矿化强度或可以黑云母的Fe2+/(Fe2++Mg2+)比值来衡量;而Mo元素在两类黑云母中均广泛分布,不具有选择性赋存的特征。  相似文献   

三江北段纳日贡玛黑云母花岗斑岩LA-ICP-MS锆石U-Pb定年及其地质意义     

宋忠宝  贾群子  张雨莲  陈博  陈向阳  王富春  田永革  栗亚芝  张晓飞  全守村 《中国区域地质》2012,(2):439-447

西南三江北段是青海省重要的斑岩型铜钼矿成矿带,纳日贡玛铜钼矿是近年来在三江北段发现的与侵入岩有关的斑岩型铜钼矿。利用锆石U-Pb方法测得纳日贡玛黑云花岗斑岩的形成年龄为41.53Ma±0.24Ma,属于喜马拉雅早期。纳日贡玛斑岩型铜钼矿的成矿时代主要在40.86~40.80Ma之间。在多期热液叠加、多期成矿作用中,纳日贡玛斑岩型铜钼矿的热液应是纳日贡玛黑云花岗斑岩（41.53Ma±0.24Ma）和纳日贡玛斜长花岗斑岩（41.00Ma±0.18Ma）共同提供的。由于该区有较多的中酸性岩体存在,因而确定这些侵入体的形成年龄,对于在该区寻找同时代的斑岩型铜钼矿有重要的理论意义和现实意义。  相似文献   

冀北赤城红旗营子群黑云斜长片麻岩的岩石学、地球化学及原岩特征   总被引：1，自引：0，他引：1  

张静  倪志耀  翟明国  卢俊生  严刚  孔旭  周新 《岩石矿物学杂志》2012,31(3):307-322

冀北赤城红旗营子群黑云斜长片麻岩具斑状变晶结构,变基质为中、细粒鳞片粒状变晶结构,片麻状构造,局部保留有变余砂状结构。岩石主要由斜长石(28%~32%)、石英(35%~40%)、黑云母(18%~25%)及少量石榴石(2%~8%)和石墨(1%~4%)等组成,其变质演化可能是一个降温、降压的过程。黑云斜长片麻岩样品具有较宽的常量元素变化范围,稀土元素含量不是很高且变化较大,ΣREE介于49.45×10-6~140.10×10-6之间,具有轻稀土富集、重稀土平坦的球粒陨石标准化稀土配分模式,轻、重稀土元素比值为5.23~9.16,(La/Yb)CN值为5.07~8.70。大多数样品具中等程度的负Eu异常和不太明显的负Ce异常,(Eu/Eu*)CN和(Ce/Ce*)CN值分别为0.63~0.81和0.82~1.01。岩石中Rb、Sr、Cs、Ba、Zr、Hf、Nb、Ta、Th和U等微量元素含量均低于上地壳的平均含量,但Sr/Ba和Th/U值高于上地壳的平均值。红旗营子群黑云斜长片麻岩的地球化学特征表明其原岩应为泥质(或含泥质)砂岩,可能形成于大陆岛弧环境。  相似文献   

Early Miocene post-collisional magmatism in NW Turkey: geochemical and geochronological constraints     

《International Geology Review》2012,54(9):1098-1119

The Alaçam region of NW Turkey lies within the Alpine collision zone between the Sakarya continent and the Menderes platform. Four different tectonic zones of these two continents form imbricated nappe packages (including the Afyon zone), intruded by the Alaçam granite. Newly determined U-Pb zircon ages of this granite are 20.0 ± 1.4 and 20.3 ± 3.3 Ma, indicating early Miocene emplacement. Rb-Sr biotite ages of the granite are 20.01 ± 0.20 and 20.17 ± 0.20 Ma, suggesting fast cooling at a shallow crustal level. Geochemical characteristics show that the Alaçam granite is similar to numerous EW-trending plutons in NW Anatolia.

Gneissic granites of the Afyon tectonic zone were intruded by the Miocene Alaçam granite and have been interpreted in earlier studies as sheared parts of the Alaçam granite, which formed along a crustal-scale detachment zone under an extensional regime. We determined a U-Pb zircon age of 314.9 ± 2.7 Ma for a gneissic granite sample of the Afyon zone, demonstrating that these rocks are unrelated to the Miocene Alaçam granite. The early Miocene granitic plutons bear post-collisional geochemical features and are interpreted as products of Alpine-type magmatism along the Izmir–Ankara suture zone in NW Turkey, and seem to have no genetic relation to the detachment zone.  相似文献   

Mineral chemistry of Plio-Quaternary subvolcanic rocks,southwest Yazd Province,Iran     

《International Geology Review》2012,54(13):1497-1531

The NW–SE-trendingLate Cretaceous–Cenozoic Urumieh-Dokhtar Magmatic Arc (UDMA) in southwest Iran hosts numerous Plio-Quaternary subvolcanic porphyritic andesitic to rhyodacitic domes intruded into a variety of rock sequences. Bulk-rock geochemical data show that the calc-alkaline dacitic to rhyodacitic subvolcanic rocks share compositional affinities with high-silica adakites, including high ratios of Na₂O/K₂O >1, Sr/Y (most >70), and La/Yb (>35), high Al₂O₃ (>15 wt.%), low Yb (<1.8 ppm) and Y (<18 ppm) contents, no significant Eu anomalies, and flat to gently upward-sloping chondrite-normalized heavy rare-earth element (HREE) patterns. All analysed rocks are characterized by enrichment in large-ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). They also display typical features of subduction-related calc-alkaline magmas. In chondrite-normalized rare-earth element patterns, the light rare-earth elements (LREEs) are enriched ((La/Sm) _N = 3.49–7.89) in comparison to those of the HREE ((Gd/Yb) _N = 1.52–2.38). Except for the G-Aliabad Dome, plagioclase crystals in the Shamsabad, Ostaj, Abdollah, and Bouragh Domes are mostly oligoclase to andesine (An_19–49). Amphibole and biotite are abundant ferromagnesian minerals in the subvolcanic rocks. Calcic amphiboles are dominantly magnesiohornblende, magnesiohastingsite, and tschermakite with Mg/(Mg + Fe_tot) ratios ranging from 0.58 to 0.78. In all the studied domes, amphiboles are typically ferric iron-rich, but that those the Shamsabad Dome have the highest Fe³⁺/(Fe³⁺ + Fe²⁺) ratios, between 0.69 and 0.98. Amphiboles from the Ostaj and Shamsabad Domes are relatively rich in F (0.39–1.01 wt.%) in comparison to the other studied domes. This phase commonly shows pargasitic and hastingsitic substitutions with a combination of tschermakitic and edenitic types.

Temperature-corrected Al-in-hornblende data show that amphibole phenocrysts from the Ostaj, Abdollah, and G-Aliabad Domes crystallized at pressures ranging from 2.14 to 3.42 kbar, 3.49 to 3.96 kbar, and 2.02 to 3.47 kbar, respectively. Temperatures of crystallization calculated with the amphibole–plagioclase thermometer for the Ostaj, Abdollah, and G-Aliabad subvolcanic domes range from 735°C to 826°C (mean = 786 ± 29), 778°C to 808°C (mean = 791 ± 13), and 866°C to 908°C (mean = 885 ± 12), respectively. In the annite–siderophyllite–phlogopite–eastonite quadrilateral, biotite from the G-Aliabad, Bouragh, and Ostaj Domes are characterized by relatively low total Al contents with variable Fe_tot/(Fe_tot + Mg) values from 0.26 to 0.43. All biotite analyses define a nearly straight line in the X _Mg versus Fe_tot plot, with r = –0.96 correlation coefficient. In comparison to other domes, the F content of biotite from the G-Aliabad Dome shows high concentrations in the range of 1.80–2.57 wt.% (mean = 2.20). Inferred pre-eruptive conditions based on the calcic amphibole thermobarometric calculations for the Shamsabad, Abdollah, and Ostaj Domes show that the calc-alkaline subvolcanic magma chamber, on average, was characterized by a water content of 6.10 wt.%, a relatively high oxygen fugacity of 10^–10.66 (ΔNNO + 1.28), a temperature of 896°C, and a pressure of 2.75 kbar.  相似文献