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61.
海水营养盐测定中水样的保存技术 总被引:9,自引:0,他引:9
水样的保存和前处理技术直接关系到分析结果的精确度。针对海水氮、磷营养元素测定中影响水样保存期的容器和保存剂的选择进行了讨论 ,通过实验研究探索其行之有效又方便实用的保存方法以提高实验数据的精确度。 相似文献
62.
Katsumi Matsumoto 《Journal of Oceanography》2006,62(6):887-902
Iron fertilization of nutrient-rich surface waters of the ocean is one possible way to help slow the rising levels of atmospheric
CO2 by sequestering it in the oceans via biological carbon export. Here, I use an ocean general circulation model to simulate
a patch of nutrient depletion in the subpolar northwest Pacific under various scenarios. Model results confirm that surface
fertilization is an inefficient way to sequester carbon from the atmosphere (Gnanadesikan et al., 2003), since only about 20% of the exported carbon comes initially from the atmosphere. Fertilization reduces future production
and thus CO2 uptake by utilizing nutrients that would otherwise be available later. Effectively, this can be considered as leakage when
compared to a control run. This “effective” leakage and the actual leakage of sequestered CO2 cause a significant, rapid decrease in carbon retention (only 30–45% retained after 10 years and less than 20% after 50 years).
This contrasts markedly with the almost 100% retention efficiency for the same duration using the same model, when carbon
is disposed directly into the northwest Pacific (Matsumoto and Mignone, 2005). As a consequence, the economic effectiveness
of patch fertilization is poor in two limiting cases of the future price path of carbon. Sequestered carbon in patch fertilization
is lost to the atmosphere at increasingly remote places as time passes, which would make monitoring exceedingly difficult.
If all organic carbon from one-time fertilization reached the ocean bottom and remineralized there, acidification would be
about −0.05 pH unit with O2 depletion about −20 μmol kg−1. These anomalies are probably too small to seriously threaten deep sea biota, but they are underestimated in the model because
of its large grid size. The results from this study offer little to advocate purposeful surface fertilization as a serious
means to address the anthropogenic carbon problem. 相似文献
63.
64.
秋茄和榕树叶片中正构烷烃分布和单体化合物δ13C值及其光合作用 总被引:1,自引:0,他引:1
对深圳福田、阳江、海南新竹红树林秋茄Kandelia candel及海口榕树Ficusm icrocarpa叶中类脂物进行萃取,分离出正构烷烃,通过气相色谱(GC)及色谱-质谱(GC MS)分析,测出了正构烷烃的碳数分布和相对含量.气相色谱-稳定同位素比质谱仪(GC-IRMS)测定了正构烷烃单体化合物的稳定同位素组成δ13C.秋茄叶和榕树叶正构烷烃的碳数分布均为C17C33,主要集中在C23-C31(>90%).化合物含量最高为C27的有深圳福田秋茄、海南新竹秋茄、海口榕树,而阳江秋茄为C25.单体化合物的稳定同位素δ13C深圳福田秋茄为-31.42‰-34.48‰,阳江秋茄为-31.69‰-33.62‰,海南新竹秋茄为-30.30‰-33.04‰,海口榕树为-29.92‰33.56‰;平均值分别为-32.95‰、32.67‰、31.67‰、-31.74‰.结果表明,秋茄和陆地植物榕树的光合作用都是通过C3途径,是典型C3植物. 相似文献
65.
The common assumption that the ratio between particulate organic carbon (POC) and particulate 234Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / 234Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / 234Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / 234Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / 234Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex 234Th (i.e., high POC / 234Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly 234Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / 234Th) of the total spectrum of particles settling out of the upper ocean. 相似文献
66.
The physical and chemical variability of the water column at subtidal station of an estuary in the Seto Inland Sea, Japan,
was studied over a 24-hour period during a spring tide (tidal range ca. 2 m) in May 1995. Surface water and several depths through the water column were monitored every one and two hours, respectively.
At each occasion, water temperature, salinity and dissolved oxygen concentration were measured and water samples were collected
for the determination of nutrients and suspended particulate matter (SPM). Disruptive changes in the physical and chemical
characteristics of the water was produced by the tidal cycle and the mixing of water masses of different origin. These changes
were highly significant both spatially and temporally, yet with varying effects on physical parameters, nutrients and the
different components of SPM. Significant differences in nutrient concentrations were also observed when the data-set was divided
into ebb and flood components, irrespective of the depth. Nitrate and nitrite rose to 1.8 times higher during the flood. Spatial
differences of SPM were less marked than those of nutrients, only particulate organic carbon (POC) being significantly higher
at the surface than in the intermediate and the lower layer. Both POC and pheopigment concentrations increased markedly through
the water column, being highest shortly before the lower low tide. In contrast, suspended solid (SS) content increased sharply
after the lower low tide (>40 mg l−1) and this coincided with a marked decrease of the C/SS content (<20 mg g−1). The lagtime between POC and SS tidal transport was caused by particle resuspension from the exposed intertidal sediments
as the tidal level rose, and particle transport selection in relation to the tidal state.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
67.
大洋碳循环与气候演变的热带驱动 总被引:2,自引:0,他引:2
20世纪气候演变研究的最大突破,在于地球轨道变化驱动冰期旋回的米兰柯维奇理论。然而近年来学术界对热带过程和大气CO2浓度变化的研究进展,暴露了传统的轨道驱动理论存在着对低纬区和碳循环在全球气候系统中作用估计不足的严重缺陷。国家重点基础研究发展计划项目"大洋碳循环与气候演变的热带驱动"拟以南海与西太平洋暖池的深海记录为依据,进行全球性对比和跨越地球圈层的探索,通过观测分析结果与数值模拟的结合、地质记录与现代过程的结合,检验和论证大洋碳储库长周期变化机制的假说,对于不同时间尺度上低纬过程如何通过碳循环在全球气候环境演变中的作用,实现理论上的突破。同时简要介绍了该项目的目的、科学意义、关键科学问题及预期目标等。 相似文献
68.
69.
选取大洋钻探ODP184航次在南海北部采集的1144站为研究材料,通过分析中更新世0.4~1.4Ma期间506个样品中浮游有孔虫氧、碳稳定同位素的变化特征,并与南海南部ODP 1143站和西太平洋暖池ODP 807站的同位素资料进行比较,发现南海北部的氧、碳稳定同位素及其差值的变化响应中更新世气候转型事件,在中更新世距今约0.9Ma之后100ka的偏心率周期明显增强。在中更新世气候转型之前,南海北部、南海南部和赤道西太平洋都呈现出典型的热带气候特征,具有岁差和半岁差的气候周期;转型之后,随着北半球冰盖的进一步扩张,南海北部受东亚冬季风增强的影响而导致温度下降、温跃层变深,但南海南部与赤道西太平洋的温度变化较小且温跃层变浅,说明同属季风区的南海北部和南部对气候变化的响应有所不同。 相似文献
70.
为了探索海洋天然气水合物背景下有孔虫特征的响应,对综合大洋钻探计划(IODP) 311航次岩芯沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana进行了初步研究。通过对冷泉站位U1328和毗邻的非冷泉站位U1327沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana的显微形貌特征和碳、氧稳定同位素测试等,证实有孔虫壳体未受到后期成岩作用的改造和自生碳酸盐岩的交代影响,有孔虫壳体的碳稳定同位素呈现明显的负偏。其中U1327站位中U.peregrina δ13C为-0.67‰~-2.75‰(PDB),B.mexicana δ13C为-0.51‰~-1.52‰(PDB);U1328站位中U.peregrina δ13C为 -0.72‰~-2.71‰(PDB),B.mexicanaδ13C为 -0.58‰~-1.45‰(PDB)。底栖有孔虫壳体的碳稳定同位素负偏成因可能与水合物不稳定分解释放的甲烷厌氧氧化作用和食物源有关,因而可较好地指示海底天然气水合物系统地质背景。 相似文献