Infrared estimates of aliphatic kerogen carbon in sedimentary rocks     

H.J. Schenk  E.G. Witte  P.J. Müller  K. Schwochau 《Organic Geochemistry》1986,10(4-6)

An infrared routine has been developed to estimate the aliphatic portion of kerogen carbon in sedimentary rocks. The procedure does not require isolation of the organic matter and is based on a computer-assisted determination of global band areas in the region of the aliphatic carbon-hydrogen stretching vibrations around 2900cm⁻¹. From these integrated absorptions the amount of aliphatic carbon C_al (mg of aliphatic carbon per gram of solvent-extracted rock) is calculated by means of a calibration with model rocks. Carbonate overtones which interfere in the case of limestones are eliminated by comparison to a CaCO₃ standard.The method has been applied to rocks containing kerogens of different types and maturities at TOC levels of 0.5 to 12%. The aliphatic carbon concentrations range from 0.5 to 60mg·g⁻¹ and correlate reasonably well with the residual genetic potentials of the rocks as measured by S₂ values from Rock-Eval pyrolysis. The ratio S₂/C_al is found to decrease with burial depth reflecting a maturity enhanced conversion of aliphatic carbon to fixed aromatic carbon under Rock-Eval conditions.  相似文献   

非渠化海相碳酸盐岩滩储集地质体的构型研究   总被引：1，自引：0，他引：1       下载免费PDF全文

蔡忠贤  贾振远 《地球科学》1995,20(3):290-298

１９８５年Ｍｉａｌｌ创立于河流沉积体系的构型单元分析方法可通过旋回性分级特征运用于非渠化海相碳酸盐岩滩沉积体中，并且在构型界面和构型 与河流沉积体的划分可进行对比，所获得的非均质性储层地质模型表明，沉积体最小的均一性单元是由二级界面所限定的较小规模中层型，该构型规模以上的非均质性特征受构型界面级次和构型单元多样性的控制。  相似文献   

Fossil worm tubes from the presumed cold-seep carbonates of the Miocene Hayama Group, Central Miura Peninsula, Japan     

Takeshi  Naganuma  Yuichi  Okayama  Mutsuo  Hattori Yasumitsu  Kanie 《Island Arc》1995,4(3):199-208

Abstract Fossil worm tubes were collected from the Hayama Group, Miura Peninsula, Japan, together with abundant fossils of Calyptogena-Acharax clams. The fossil worm tubes were well preserved and coated with milky white amorphous silica. Most of the tubes were 1-3 mm in diameter, and up to 10 cm in length. Worm tubes were found in siltstone and limestone, and formed network-like assemblages. Elemental mapping on the tube cross-sections revealed the localization of sulfur, zinc and iron at the worm tubes, which suggests that sulfur-related metabolism and deposition occurred in association with the worm tubes. High resolution analysis revealed the localization of zinc-sulfur (sphalerite, ZnS) on the tubes, while iron-sulfur (pyrite, FeS₂) was localized at the center of the tubes. The spatially separate sphaleritization and pyritization imply that epiphytic and endosymbiotic microorganisms perform different sulfur metabolisms, such as sulfate-reduction and sulfide-oxidation.  相似文献   

新矿物——白云鄂博矿   总被引：1，自引：0，他引：1  

傅平秋  苏贤泽 《矿物学报》1987,(4)

白云鄂博矿产于内蒙古白云鄂博稀土铁铌矿床中,它是一种钠钡铈稀土氟碳酸盐新矿物——NaBaCe_2[F|(CO_3)_4]。作者对其进行了基础矿物学、矿物谱学、X射线晶体学研究及精确的成分测定,获得了详细的矿物学实验数据及晶体结构基本参数,并对该矿物进行X射线晶体结构精测。此外,作者对其作了高分辨电镜研究,拍摄了该矿物的结构象,肯定其X射线晶体结构的分析结果。综合上述实验资料,与类似矿物对比,作者确认白云鄂博矿为一新矿物。  相似文献   

混合沉积和混积岩的讨论   总被引：36，自引：6，他引：30  

沙庆安 《古地理学报》2001,3(3):63-66

混合沉积物是指陆源碎屑与碳酸盐(包括异化粒等)在沉积上的混合。混合沉积可分为狭义的和广义的,狭义的是指陆源碎屑与碳酸盐组份的混合(在同一岩层内),而广义的混合则包括了狭义的和陆源碎屑与碳酸盐层构成交替互层或夹层的混合。混合沉积很早就引起了人们的注意,尽管碎屑岩和碳酸盐岩的研究与应用已很成熟,但对混积岩的研究多被忽视了。对狭义的混合沉积物有必要起一成因名称——混积岩。当人们接触到混合沉积时,除了分析研究它们的组分和结构特征外,还必须去思考,它们为什么能经常频繁地交互出观,或是直接混合在一起?倒底是：①陆源碎屑跑到碳酸盐的沉积背景里?②碳酸盐跑到陆源碎屑的沉积背景里?③二分别从各自的源地跑到第三种沉积背景里?还是④二本来就在同一沉积背景里?接下来就要思考是什么动力条件使它(们)能从这个沉积背景(环境)“跑”到另一个沉积背景(环境)里去?是水?是风?是自身?还是别的什么力量?那么,又是怎样的水动力或风动力条件呢?是正常条件,还是突发事件?很明显,要分析研究混合沉积和混积岩。这些问题就不得不细细加以考虑,深入进行研究。  相似文献   

断陷湖盆碳酸盐与陆源碎屑混合沉积——以东营凹陷金家地区古近系沙河街组第四段上亚段为例   总被引：3，自引：0，他引：3       下载免费PDF全文

张金亮  司学强 《地质论评》2007,53(4):448-453,I0001

混合沉积是一种特殊的沉积类型,研究程度较低。金家地区处于东营凹陷的斜坡带,该区古近系沙河街组第四段上亚段发育了碳酸盐与陆源碎屑的混合沉积,研究认为该混合沉积为古湖泊内的混合沉积,可划分为混积砂滩亚相、混积砂坝亚相及半深湖混积亚相,混合沉积物既包括同层混合沉积物（灰质砂岩、砂质灰岩、泥质灰岩等）,又包括互层混合沉积物（砂岩与颗粒灰岩互层沉积等）,研究区的混合沉积受当时构造运动、碎屑物质供给量、湖平面的变化等诸多因素控制。  相似文献   

萃取富集-火焰原子吸收法测定碳酸钙中铅和镉     

黄俭惠  邱丽 《矿产与地质》2007,21(4):479-481

将碳酸钙试样用盐酸溶解后,在0.6mol/L的盐酸介质中,用KI-MIBK萃取试样中微量的铅和镉,有机相用原子吸收分光光度法测定。该方法测定铅的相对标准偏差为2.38%-6.31%,回收率为96.5%-97.0%;测定镉的相对标准偏差为4.50%-5.52%,回收率为96%-102.8%。结果可靠,具有灵敏、准确、快速、选择性好等优点。适用于碳酸钙中铅、镉的测定。  相似文献   

Principal stages in evolution of Precambrian organic world: Communication 1. Archean and Early Proterozoic     

V. N. Sergeev  M. A. Semikhatov  M. A. Fedonkin  A. F. Veis  N. G. Vorob’eva 《Stratigraphy and Geological Correlation》2007,15(2):141-160

Expounded in this work are the results of critical consideration of published and original data on biologic nature and appearance chronology of different groups of Archean and Lower Proterozoic (3.5–1.65 Ga) paleontological remains known from geological record. Conclusions are substantiated by morphological analysis of structurally preserved microfossils, their facies distribution, and by inferable genesis and principal evolutionary trends of Archean stromatolites. A special attention is paid to variations of organic and carbonate carbon isotope composition in sedimentary successions with paleontological remains and to recent information about discovered, most ancient biomarkers of large groups of organic world. As a result of this approach, a detailed model of Precambrian organic world evolution is suggested.  相似文献   

Carbonate deposits on submerged seamounts in the northwestern Pacific Ocean     

Hideko  Takayanagi  Yasufumi  Iryu  Tsutomu  Yamada  Motoyoshi  Oda  Kazuyuki  Yamamoto  Tokiyuki  Sato  Shun  Chiyonobu  Akira  Nishimura  Tsutomu  Nakazawa  Satoshi  Shiokawa 《Island Arc》2007,16(3):394-419

Abstract   The lithology of shallow-water carbonates collected from 19 sites on 16 seamounts in six areas of the northwestern Pacific Ocean using the Deep-sea Boring Machine System are described. The areas include the Amami Plateau, Daito Ridge, Oki-Daito Ridge, Urdaneta Plateau, Kyushu-Palau Ridge and Ogasawara Plateau. Chronological constraint is provided by calcareous nannofossil biostratigraphy, planktonic foraminiferal biostratigraphy, larger foraminiferal biostratigraphy and strontium (Sr) isotope stratigraphy. Large amounts of shallow-water carbonates accumulated on the seamounts during the Oligocene, a relatively cool period, whereas limited carbonate deposits formed during the Early Miocene, a relatively warm period. This might indicate that deposition of shallow-water carbonates on seamounts in the northwestern Pacific Ocean was not necessarily controlled by climatic conditions, but was related to volcanism and tectonics that served as foundations for reef/carbonate-platform formation. Remarkable differences in biotic composition exist between Cretaceous and Cenozoic shallow-water carbonates. Late Cretaceous shallow-water carbonates are distinguished by the occurrence of rudists, solenoporacean algae and microencrusters. Middle Eocene to Early Oligocene shallow-water carbonates are dominated by Halimeda or nummulitid and discocyclinid larger foraminifers. Scleractinian corals became common from the Oligocene onward. Nongeniculate coralline algae and larger foraminifers were common to abundant throughout the Eocene to the Pleistocene. The replacement of major carbonate producers in the shallow-water carbonate factory during post-Cretaceous time is in accordance with previous studies and is considered to reflect a shift in seawater chemistry.  相似文献   

北京十三陵地区中—新元古界碳酸盐岩Pb—Pb年龄研究   总被引：8，自引：0，他引：8  

张巧大宋天锐  和政军丁孝忠 《地质论评》2002,48(4):416-423

对北京十三陵地区中一新元古界碳酸盐岩进行了系统地采样和207pb/204pb-206Pb/204Pb年龄测定.共测定了63个样品(大部分样品采取两种溶解方式),得到中元古界雾迷山组第三段的207Pb/204pb-206Pb/204pb等时线年龄为1373±92Ma(95%置信度误差,下同,MSWD＝4.7),杨庄组为1488±55Ma(MSWD＝14),高于庄组第三段为1608±74Ma(MSWD＝8.1).这些年龄数据与目前已有地质记录相吻合.串岭沟组的碳酸盐相的206Pb/204Pb-207Pb/204Pb未构成等时线,但全岩的206Pb/204pb-207Pb/204Pb比碳酸盐相具有更明显的线性趋势,其原因尚待进一步研究.另外,根据同一个样品用稀盐酸溶解和用氢氟酸加硝酸混合酸溶解的铅同位素比值的接近的现象,显示碳酸盐岩中的硅质没有陆源的特征,是沉积盆地中的产物.  相似文献