酸化压裂工艺在地热井中的应用          下载免费PDF全文

马忠平 杜槟鲍卫和  李会娟王艳宏 《探矿工程》2007,34(2):45-47

酸化压裂是保持油田高产、稳产的有效措施之一，是对油气层的一种增产技术。根据多年地热井的施工经验，酸化压裂技术完全可以应用于碳酸盐基岩裂隙地热井，作为一项有效的增产技术手段。介绍了酸化压裂技术在WR95地热井中的应用。  相似文献   

广西桂林庙头上泥盆统融县组中的灰岩脉和角砾灰岩体及其成因   总被引：3，自引：3，他引：3       下载免费PDF全文

彭阳  李岩  胡贵昂  陆刚  乔秀夫 《地质论评》2007,53(6):736-742

广西桂林庙头上泥盆统融县组台地边缘相具鸟眼或溶孔砂屑生屑藻粘结灰岩中发育了大量灰岩脉，灰岩脉呈岩墙状近直立地切过围岩，露头上可见连续垂直延伸长度达十余米，脉内仍是上泥盆统融县组灰岩组分，仅比围岩稍晚或同时代的：角砾状退白云石化藻粘结灰岩、角砾状藻粘结灰岩（快速堆积，角砾多数来自围岩）、细鲕粒颗粒灰岩、含钙球砂屑粒泥灰岩、藻砂屑腹足泥粒灰岩（正常沉积或液化变形软沉积流，均高于围岩层位）及大量栉壳状方解石脉（张性环境）等，灰岩脉内可见软沉积物变形痕迹及液化脉（地震液化），晚期灰岩脉可穿插早期灰岩脉；在其西侧同层位共生有一套楔状（地裂缝）、不规则状角砾灰岩体，角砾棱角状，大小不等，成分是灰色中厚层角砾状藻粘结灰岩、含钙球砂屑粒泥灰岩等。笔者等注意到灰岩脉均出露在北东向正断层的下盘（东侧），而角砾灰岩体则均出露在该断层的上盘（西侧），事实上，灰岩脉及角砾灰岩体分布走向与北东向断层走向一致，角砾灰岩体中的角砾成分显示其来自较灰岩脉围岩稍高层位，与灰岩脉内充填岩性相近，因此，是该断层控制了当时的沉积，此断层是晚泥盆世台地边缘同沉积正断层；灰岩脉是与断层伴生的张性裂隙被围岩角砾或稍晚时段的沉积物充填；角砾灰岩体是同沉积正断层形成的断层崖崩落角砾岩，指示一个消失殆尽的晚泥盆世碳酸盐岩同沉积正断层陡崖，因而，桂林台地，至少西段台地边缘，是与右江各孤立台地边缘一样——在地质图上应标示为同沉积正断层边界。其构造意义是：庙头地区的灰岩脉、角砾灰岩体及同沉积断层是桂林台地对晚泥盆世构造伸展作用的响应，从而说明广西晚古生代的板块拉张，不是从二叠纪才开始的，而是至少从晚泥盆世就开始了；晚古生代至早三叠世持续的孤立台地与深水盆地相间的古地理格局，是在晚泥盆世就奠定了基础。  相似文献   

中太平洋WX海山富钴结壳磷酸盐矿物学研究及成因类型分析   总被引：2，自引：0，他引：2  

汪在聪李胜荣  刘鑫施娘华  初凤友佟景贵 《岩石矿物学杂志》2007,26(5):441-448

大洋富钴结壳普遍发生磷酸盐化,磷酸盐化对富钴结壳的各种属性存在显著影响,而磷酸盐的成因问题一直没有得到很好解决。中太平洋WX海山富钴结壳老壳层中发育着两期磷酸盐化事件所产生的上下两层磷酸盐,本文运用反光显微镜、扫描电子显微镜、电子探针、微量粉晶X衍射等手段分别对其进行了矿物学特征观察和测试,研究了老壳层上下两层磷酸盐特征并探讨其可能成因。上层磷酸盐由大量形态结构清楚的磷酸质有孔虫和超微化石以及非生物碳氟磷灰石(CFA)组成,成分均一,杂质少,表现出生物成因和原生自沉积特点;下层磷酸盐变化复杂,具有特征的交代结构,混杂较高的Si、Al、K、Fe成分,显示以磷酸盐交代碳酸盐成因为主。这表明不同磷酸盐化期形成的磷酸盐有不同的成因类型。  相似文献   

酸碱滴定法测定天然石膏中的碳酸盐(无水碳酸)   总被引：3，自引：0，他引：3  

蔡玉曼  陆丽君  周泳德  高孝礼 《江苏地质》2007,31(2):127-129

建立了用溴百里酚蓝—酚红作指示剂,酸碱滴定法测定天然石膏中碳酸盐的方法。在确定了试验条件的基础上,对石膏国家一级标准物质GBW03109a和GBE03110分析,相对标准偏差分别为0.08%、1.05%;分析3个天然石膏样品,相对标准偏差分别为1.47%、1.67%和0.25%;对试样进行加标回收,回收率在95.53%～97.02%之间;方法检出限为0.15%。表明用该方法测试,结果准确可靠。  相似文献   

Calcio-carbonatite melts and metasomatism in the mantle beneath Mt. Vulture (Southern Italy)     

Gianluigi Rosatelli  Frances Wall  Francesco Stoppa 《Lithos》2007,99(3-4):229-248

At Mt. Vulture volcano (Basilicata, Italy) calcite globules (5–150 μm) are hosted by silicate glass pools or veins cross-cutting amphibole-bearing, or more common spinel-bearing mantle xenoliths and xenocrysts. The carbonate globules are rounded or elongated and are composed of a mosaic of 2–20 μm crystals, with varying optical orientation. These features are consistent with formation from a quenched calciocarbonatite melt. Where in contact with carbonate amphibole has reacted to form fassaitic pyroxene. Some of these globules contain liquid/gaseous CO₂ bubbles and sulphide inclusions, and are pierced by quench microphenocrysts of silicate phases. The carbonate composition varies from calcite to Mg-calcite (3.8–5.0 wt.% MgO) both within the carbonate globules and from globule to globule. Trace element contents of the carbonate, determined by LAICPMS, are similar to those of carbonatites worldwide including ΣREE up to 123 ppm. The Sr–Nd isotope ratios of the xenolith carbonate are similar to the extrusive carbonatite and silicate rocks of Mt. Vulture testifying to derivation from the same mantle source. Formation of immiscibile silicate–carbonatite liquids within mantle xenoliths occurred via disequilibrium immiscibility during their exhumation.  相似文献   

北京周口店豹皮灰岩的变形特征   总被引：1，自引：0，他引：1  

陈云峰吴淦国  王根厚 《地质通报》2007,26(6):69-775

周口店地区广泛分布的寒武纪地层府君山组底部灰岩因其具典型的豹斑状构造而被称为豹皮灰岩。本文主要以出露于周口店黄院地区的豹皮灰岩为研究对象。组成豹皮灰岩的物质成分有2种,一为白云质成分的豹斑,其余部分为泥灰质。在露头尺度上,豹皮灰岩中的豹斑发生了明显的旋转变形并具有一定的定向性,而泥灰质成分则具有清晰的韧性变形特征,为较典型的碳酸盐糜棱岩;在微观尺度上,构成豹斑的白云石矿物未发生韧性变形,而泥灰质成分中的方解石具有明显的细粒化、拉长和定向。豹皮灰岩变形发生时岩石所处的温度介于200～250℃之间。豹皮灰岩的形成经历了原岩形成和后期构造变形改造2个阶段,于寒武纪由沉积作用形成了岩石的物质组分和原生层状构造,在前印支期受水平剪切作用形成岩石的豹斑状构造。  相似文献   

邻二氮菲分光光度法测定碳酸盐相中微量亚铁   总被引：2，自引：2，他引：2  

潘涵香胡超涌  王红梅马仲武 《岩矿测试》2007,26(3):198-200

建立了在超声波作用下，HAc—NaAc缓冲溶液和邻二氮菲选择性溶解分光光度法直接测定碳酸盐相中微量亚铁的方法。结果表明，在适宜条件下，含2g／L邻二氮菲的HAc—NaAc缓冲溶液（pH3）可选择性溶解并络合碳酸盐相中的Fe（Ⅱ），通过加入EDTA溶液有效地抑制了Fe（Ⅲ）的光还原作用。常见含铁矿物如赤铁矿、磁铁矿及硅酸盐等均对碳酸盐中Fe（Ⅱ）的测定无干扰。样品经30％的H2O2浸泡、过滤、晾干预处理，能有效地消除黄铁矿和有机物的干扰。方法用于石灰岩国家一级标准物质的测定，结果与标准值相符。  相似文献   

青藏高原北部新生代湖相碳酸盐岩碳氧同位素特征及古环境意义   总被引：3，自引：2，他引：3  

伊海生  林金辉  周恳恳  李军鹏 《古地理学报》2007,9(3):303-312

对青藏高原北部地区新生代陆相地层中湖相碳酸盐岩进行了系统采样分析，以碳氧同位素作为古环境和古气候变化的替代指标,试图从古湖泊演化的角度，阐明高原新生代早期环境演变历史和过程。研究结果表明，该区所有分析样品中生物碎屑灰岩类样品的δ¹⁸O和δ¹³C显示最低值，反映它们沉积在一个水体滞留时间短的开放性淡水湖泊系统中。泥晶灰岩类样品的δ¹⁸O和δ¹³C之间具有正相关关系，表明它们发育在蒸发作用明显的封闭性咸水湖泊体系中，而叠层石灰岩类明显富集13C可能与微生物活动有关。从始新世到渐新世至中新世，湖相碳酸盐岩δ¹⁸O值具有逐渐增大的趋势，δ¹³C则由古近纪的负值变为新近纪的正值，反映该区古湖泊系统经历了一个由开放到封闭的过程，预示古近纪到新近纪之交高原古气候格局发生了重大变革。  相似文献   

Determination of Total Organic Carbon Content and δ¹³C in Carbonate-Rich Detrital Sediments     

Valier Galy  Julien Bouchez  Christian France-Lanord 《Geostandards and Geoanalytical Research》2007,31(3):199-207

The determination of total organic carbon content and composition in detrital sediments requires careful removal of their carbonate minerals. In detrital sediments containing large amounts of carbonates, including dolomite, this can only be achieved by liquid acid leaching that may solubilise a significant proportion of the organic carbon. For a set of detrital sediments from the Himalayan system and the Amazon River as well as five geological reference materials, we determined the proportion of organic carbon (C_org) solubilised during acid leaching. This proportion is significant for all analysed sediments and generally tends to increase with the organic carbon content. Compared to other types of sediments analysed, clay fractions extracted from river sediments and bed sediments with very low organic carbon content have high and low proportions of acid soluble C_org respectively. In Himalayan and Amazon river sediments, the proportion of C_org solubilised during acid leaching was relatively constant with average values of 14 and 19 % respectively. Thus, it is possible to correct the C_org content for the dissolved organic carbon content measured after decarbonation. Data presented here show that C_org dissolved during liquid acid leaching must be taken into account. After careful calibration, the method presented here should, therefore, be applied to any carbonate-rich detrital sediment.  相似文献   

Implications of the Precambrian Non-stromatolitic Carbonate Succession Making up the Third Member of Mesoproterozoic Gaoyuzhuang Formation in Yanshan Area of North China   总被引：4，自引：0，他引：4  

梅冥相 《中国地质大学学报(英文版)》2007,18(3):191-209

A particular non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang (高于庄) Formation might demonstrate that a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma besides other three events of the Proterozoic,respectively,occurred at ca. 2 000 Ma,ca. 1 000 Ma,and ca. 675 Ma. The forming duration of this non-stromatolitic carbonate succession can be generally correlative to that of a similar depositional succession in North America,i.e. a non-stromatolitic carbonate succession made up by the Helena Formation of the Belt Supergroup,which suggests that the stromatolite decline occurring at ca. 1 450 Ma may be a global event. This information endows the non-stromatolitic carbonate succession making up the third member of the Gaoyuzhuang Formation in the Yanshan (燕山) area with important significance for the further understanding of Precambrian sedimentology. The Mesoproterozoic Gaoyuzhuang Formation in Yanshan area is a set of more than 1 000 m thick carbonate strata that can be divided into four members (or subformations). The first member (or the Guandi (官地) subformation) is marked by a set of stromatolitic dolomites overlying a set of transgressive sandstones; the second member (or the Sangshu'an (桑树鞍) subformation) is a set of manganese dolomites with a few stromatolites; the third member (or the Zhangjiayu (张家峪) subformation) is chiefly made up of leiolite and laminite limestones and is characterized by the development of molar-tooth structures in leiolite limestone; the fourth member (or the Huanxiusi (环秀寺) subformation) is composed of a set of dolomites of stromatolitic reefs or lithoherms. Sequence-stratigraphic divisions at two sections,i.e. the Jixian (蓟县) Section in Tianjin (天津) and the Qiangou (千沟) Section of Yanqing (延庆) County in Beijing (北京),demonstrate that a particularly non-stromatolitic succession making up the third member of the Mesoproterozoic Gaoyuzhuang Formation is developed in the Yanshan area of North China,in which lots of grotesque matground structures (wrinkle structures and palimpsest ripples) are developed in beds of leiolite limestone at the Qiangou Section and lots of molar-tooth structures are developed in beds of leiolite limestone at the Jixian Section. The time scale of the Gaoyuzhuang Formation is deduced as 200 Ma (from 1 600 Ma to 1 400 Ma). The duration of an obvious hiatus between the Gaoyuzhuang Formation and the underlying Dahongyu (大红峪) Formation is deduced as 50 Ma to 100 Ma,thus the forming duration of the GaoyuzhuangFormation is thought as 100 Ma (1 500 Ma to 1 400 Ma). Furthermore,the age of the subface of the third member of the Gaoyuzhuang Formation that is just in the mid position of the Gaoyuzhuang Formation can be deduced as about 1 450 Ma,which is the basis to infer a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma. Importantly,several features of both the molar-tooth structure and the stromatolite,such as the particular forming environment,the important facies-indicative meaning,and the episodic distribution in the earth history,might express the evolutionary periodicity of the surface environment of the earth and can provide meaningful clues for the understanding of the Precambrian world,although their origin and forming mechanism is highly contentious. Therefore,like other three stromatolitic declines,respectively,occurring at ca. 675 Ma,ca. 1 000 Ma,and ca. 2 000 Ma,the identification of the stromatolite decline occurring at ca. 1 450 Ma during the Golden Age of stromatolites (2 800 Ma to 1 000 Ma) has important meaning for the further understanding of the evolving carbonate world of the Precambrian.  相似文献