山东省大中型水库水化学性状研究──几种主要水化因子的变化及其在评价水库鱼产力中的作用     

刘新  李德尚  李静 《中国海洋大学学报(自然科学版)》1994,(4)

本文通过对山东省３８座代表性大、中型水库总氮（ＴＮ）、总磷（ＴＰ）、化学耗氧量、硬度及电导率（λ）五种主要水化因子连续两年（１９８９～１９９０）的调查与研究，探讨了水化因子与水库鱼产力的关系。用反映鲢、鳙生长状况的综合生长指数（ＧＩ）作为水库鱼产力的指标。它与水化因子相关分析表明，总磷是山东省３８座水库鱼产力的主要影响因子。提出ＧＩ与总磷、总氮及电导率等水化因子的逐步回归方程关系非常显著。证明利用水化因子作为水库鱼产力的评价指标是可行的。并指出：同一水库的相同水化因子存在年间差异，其主要原因在于降雨量和水库进水量的不同，鉴于此．同一水库鱼产力也存在年间差异。  相似文献   

论氢化物的形成及其在分析测试领域的应用          下载免费PDF全文

郑大中  王惠萍  郑若锋 《江苏地质》2008,32(1):5-11

论述了氢化物形成的普遍性、氢化物的物理化学性质、元素周期系各类元素的氢化物类型。认为一些金属离子、非金属离子在酸性介质中与硼氢化钾（钠）作用及金属锌等强还原剂作用生成氢化物。综述了氢化物的形成在分析测试领域的应用：试样分解、分离富集、容量分析、光度分析、原子光谱分析、质谱分析。  相似文献   

化学地层学研究中的若干注意事项     

刘疆  白志强 《物探与化探》2008,32(4):345-349

化学地层学因其交叉学科特点和研究对象的复杂性使得研究过程中任何一个环节的不足都将造成测试出现偏差,成果的可信度也将出现问题。高昂的成本也要求研究者把有限的资源集中到正确的目标上。近20年研究历程却恰恰将此类性质的问题陆续暴露了出来。如采样阶段获取原生性状考虑不充分或依据不足、测试阶段缺乏校验、数据分析阶段挖潜和综合利用有待完善以及化学岩、碎屑岩和生物岩各自的基础性和针对性研究有待提高等。有些问题带有相当程度的普遍性,有些甚至是严重的核心技术问题。笔者结合最新相关研究成果对上述问题进行了逐一分析和系统修正。  相似文献   

氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

三江平原旱田耕作对湿地土壤理化性质的累积影响初探   总被引：4，自引：5，他引：4  

袁兆华  吕宪国  周嘉 《湿地科学》2006,4(2):133-137

在中国科学院三江平原湿地生态试验站综合实验场,对不同耕作年限的湿地土壤(0~20 cm)进行环境累积效应分析。结果表明,随着开垦时间的增加,土壤的理化性质发生渐变,物理性质方面,土壤容重和比重逐渐增大,而孔隙度和田间持水量逐年减少;化学性质方面,土壤pH值随开垦时间的增加而增加,有机质和其他养分则随开垦时间的增加而逐年降低。弃耕后土壤性质有所恢复。土壤性质在开垦初期变化较明显,而后逐渐变缓。  相似文献   

Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used   总被引：1，自引：0，他引：1  

Hideki Shimada  Takashi Sasaoka  Saeid Khazaei  Yasuhiro Yoshida  Kikuo Matsui 《Geotechnical and Geological Engineering》2006,24(1):57-77

Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view, this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is also important.  相似文献   

Reply to comment by Y. Park and J.-H. Ree on 'Chemical remagnetization of the Upper Carboniferous-Lower Triassic Pyeongan Supergroup in the Jeongseon area, Korea: fluid migration through the Ogcheon Fold Belt'     

Yong-Hee Park  Seong-Jae Doh  Dongwoo Suk 《Geophysical Journal International》2006,167(1):20-23

In their comment, Park & Ree have raised several points against the interpretation by Park et al. , and argued that the remagnetization in the Jeongseon area was caused by the thermal effects of a Late Cretaceous pluton and/or associated short-range hydrothermal fluids, rather than by long-range fluids advocated by us.
We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data.  相似文献   

低温分解钾长石的热力学研究   总被引：2，自引：0，他引：2  

薛彦辉  潘兆科  张桂斋 《化工矿产地质》2006,28(3):167-170

通过不同温度、浓度、分压下ΔrGm的计算和不同条件下对平衡常数K的影响,作出ΔrGm～—T、ΔrGm—C、ΔrGm—P图,把热力学的一些规律应用于钾长石低温分解中,对参与低温分解钾长石的各物质能量转换进行分析判断反应进行的方向和限度,对钾长石的分解有指导作用。从热力学角度分析,在低温条件下分解钾长石的反应是可能的。  相似文献   

要十分重视另一类型地质灾害的防治     

蒋承菘 《中国地质灾害与防治学报》2006,17(3):96-97,102

文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。  相似文献