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Ca-rich Garnet-Clinopyroxene Rocks at Hujialin in the Su-Lu Terrane (Eastern China): Deeply Subducted Arc Cumulates? 总被引:3,自引:0,他引:3
Layers of Ca-rich garnetclinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the SuLu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards FeTi gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crustmantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped PT pathsfor the garnetclinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnetclinopyroxene rocks; SuLu terrane; UHP metamorphism 相似文献
3.
准噶尔盆地基底火山岩中的辉石及其对盆地基底性质的示踪 总被引:4,自引:0,他引:4
根据钻井和航磁资料,准噶尔盆地基底可划分为西、北、南三区。3个地区火山岩中辉石的化学成分、种属名称各不相同。辉石化学成分反映出来的寄主岩的碱度、碱度演化趋势以及寄主岩形成的构造环境、构造环境演化史均各有差异,佐证了准噶尔盆地基底是由哈萨克斯坦板块东南缘、西伯利亚板块西南缘和塔里木板块北缘增生大陆拼合而成。其中西、北两区拼合较早,早石炭世末的早海西运动时抬升成陆;南区成陆较晚,晚古炭世末的晚海西运动使南区与西、北两区联合大陆对接,形成完整的准噶尔盆地海西褶皱基底。 相似文献
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The role of clinopyroxene in producing grandite garnet is evaluatedusing data from an ultrahigh-temperature metamorphosed calc-silicategranulite occurrence in the Eastern Ghats Belt, India. Peakpressuretemperature conditions of metamorphism were previouslyconstrained from associated high MgAl granulites as c.0·9 GPa, >950°C, and the rocks were near-isobaricallycooled to c. 750°C. Grandite garnet of variable compositionwas produced by a number of reactions involving phases suchas clinopyroxene, scapolite, plagioclase, wollastonite and calcite,in closely spaced domains. Compositional heterogeneity is preservedeven on a microscale. This precludes pervasive fluid fluxingduring either the peak or the retrograde stage of metamorphism,and is further corroborated by computation of fluidrockratios. With the help of detailed textural and mineral compositionalstudies leading to formulation of balanced reactions, and usingan internally consistent thermodynamic dataset and relevantactivitycomposition relationships, new petrogenetic gridsare developed involving clinopyroxene in the system CaOAl2O3FeOSiO2CO2O2in TaCO2fO2 space to demonstrate the importanceof these factors in the formation of grandite garnet. Two singularcompositions in garnet-producing reactions in this system arededuced, which explain apparently anomalous textural relations.The possible role of an esseneite component in clinopyroxenein the production of grandite garnet is evaluated. It is concludedthat temperature and fO2 are the most crucial variables controllinggarnet composition in calc-silicate granulites. fO2, however,behaves as a dependent variable of CO2 in the fluid phase. Externalfluid fluxing of any composition is not necessary to producechemical heterogeneity of garnet solid solution. KEY WORDS: grandite garnet; role of clinopyroxene; internal buffering; oxidationdecarbonation equilibria 相似文献
6.
本文利用电子探针对南海西沙群岛琛航岛珊瑚礁底部火山碎屑岩中的单斜辉石矿物的化学特征进行了研究。结果表明,该单斜辉石属于富钙透辉石,部分有正环带结构,从核部到边部Ca、Fe、Ti的含量逐渐增加,是岩浆正常结晶顺序的反映,说明该区域的岩浆演化是向着富Ca、Fe、Ti方向发展的。主量元素数据显示,单斜辉石具有低Si高Al的特征(SiO2=41.40%~48.44%,Al2O3=5.54%~10.20%),且AlⅣ含量较高,说明母岩浆为不饱和碱性岩浆系列;此外,单斜辉石Ca含量偏高,Ca/(Ca+Mg+Fe)值在46.1%~51.4%之间,推测是母岩浆的高Ca含量导致了大量高钙辉石的产出。结合西沙海域的地震和构造资料,推测琛航岛珊瑚礁的基底是玄武质火山碎屑岩组成的平顶状海山,系岩浆穿过断裂发育的岩石圈层在西沙群岛的海底喷发,随后火山碎屑物质经过堆积、固结作用而形成;该火山碎屑岩的原岩为板内碱性玄武岩。 相似文献
7.
Recent activity–composition models for clinopyroxene and amphibole are revised to provide better consistency with observed phase relations in natural rocks. For clinopyroxene, the calibration in NCFMAS is retained, but the incorporation of acmite is revised to improve the partitioning of ferric iron between coexisting clinopyroxenes. For amphibole, the NCFMASH calibration is retained, but the addition of ferric iron is changed to provide consistency with the clinopyroxenes. The thermodynamics of orthoamphibole (gedrite) is also adjusted to resolve an unrelated inconsistency. The effects of these improvements are illustrated through comparison of calculated pseudosections produced with the existing and new models with natural data from lawsonite eclogites. 相似文献
8.
ZHI Xiachen CHEN Peng LIN Chengzhong CHEN Shuqing ZHANG Guilan LI Yuzhi LIN Lei 《《地质学报》英文版》2001,75(1):51-58
The Mössbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A‐A', B‐B', C‐C' and D‐D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D‐D' doublet assigned to Fe3+at the lattice site M***1 in previous papers. Particularly, the assignment and interpretation of the C‐C' doublet are diverse. The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000°C and oxygen fugacity of FMQ buffer in 1, 2, ***3 and 5 days respectively. The oxidized samples were then measured by X‐ray diffraction spectrometry and Mössbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe2+ → Fe3+at M1 under the subsolidus conditions, which is consistent with the increase of the area of the D‐D' doublet when the heating time increases. Accordingly, the area of the A‐A' and B‐B' doublets decreases with the increasing heating time. However, the area of C‐C' keeps almost constant. Therefore, the 4 sets of doublets can be assigned correctly as follows: A‐A' doublet to Fe+2at M1, B‐B' Fe2+at M1, C‐C' Fe2+at M2, and D‐D' Fe3+at M1. The M1 site splitting is due to the NNN (Next Nearest Neighbour) effect of the M2 site. The amount of Fe3+at the tetrohedral site of megacrystal clinopyroxene is negligible according to this study. 相似文献
9.
The Red Hills peridotite in the Dun Mountain ophiolite of SouthIsland, New Zealand, is assumed to have been produced in a paleo-mid-oceanridge tectonic setting. The peridotite is composed mostly ofharzburgite and dunite, which represent residual mantle andthe Moho transition zone (MTZ), respectively. Dunite channelswithin harzburgite blocks of various scales represent the MTZcomponent. Plagioclase- and clinopyroxene-bearing dunites occursporadically within common dunites. These dunites representproducts of meltwall-rock interaction. Chondrite-normalizedrare earth element (REE) patterns of MTZ clinopyroxenes showa wide compositional range. Clinopyroxenes in plagioclase dunitesare extremely depleted in light REE (LREE) ([Lu/La]N >100),and are comparable with clinopyroxenes in abyssal peridotitesfrom normal mid-ocean ridges. Interstitial clinopyroxenes inthe common dunite have flatter patterns ([Lu/La]N 2) comparablewith those for dunite in the Oman ophiolite. Clinopyroxenesin the lower part of the residual mantle harzburgites are evenmore strongly depleted in LREE ([Lu/La]N = 1001000) thanare mid-ocean ridge peridotites, and rival the most depletedabyssal clinopyroxenes reported from the Bouvet hotspot. Incontrast, those in the uppermost residual mantle harzburgiteand harzburgite blocks in the MTZ are less LREE depleted ([Lu/La]N= 10100), and are similar to those in plagioclase dunite.Clinopyroxenes in the clinopyroxene dunite in the MTZ are similarto those reported from mid-ocean ridge basalt (MORB) cumulates,and clinopyroxenes in the gabbroic rocks have compositions similarto those reported from MORB. Strong LREE and middle REE (MREE)depletion in clinopyroxenes in the harzburgite suggests thatthe harzburgites are residues of two-stage fractional melting,which operated initially in the garnet field, and subsequentlycontinued in the spinel lherzolite field. The early stage meltingproduced the depleted harzburgite. The later stage melting wasresponsible for the gabbroic rocks and dunite. Strongly LREEMREE-depletedclinopyroxene in the lower harzburgite and HREE-enriched clinopyroxenein the upper harzburgite and plagioclase dunite were formedby later reactive melt migration occurring in the harzburgite. KEY WORDS: clinopyroxene REE geochemistry; Dun Mountain ophiolite; Moho transition zone; orogenic peridotite; Red Hills 相似文献
10.
藏北戈木错渐新世碱性钾质火山岩中单斜辉石斑晶普遍出现正环带、反环带和韵律环带结构,多具有"绿核辉石"的结构特征。通过矿物电子探针测得"绿核辉石"的核部有高Mg#和低Mg#两种不同成分,两者都不同程度发育有筛孔状熔蚀结构,环带结构主要发育在辉石的幔部到边部,与绿色核部存在明显的成分间断,幔部环带结构的成分变化范围相对较窄。"绿核辉石"的成分和结构特征反映了同源碱性钾质岩浆在壳内岩浆房中发生了岩浆补给-混合作用,复杂的环带结构记录了混合岩浆的结晶过程。 相似文献