2013年济南市大气能见度与相对湿度和PM10、PM2.5的关系     

吕建华  彭岩波  谢刚 《气象与环境科学》2016,39(4):93-97

对济南市2013年1—12月的能见度、相对湿度、PM10及PM2.5逐时监测数据分析,结果表明：能见度、相对湿度、PM10和PM2.5浓度有明显的月变化和日变化规律。在各项污染物中,能见度与颗粒物的相关性最高,与PM10的相关系数为-0.6718,与PM2.5的相关系数为-0.7422;在气象因子中,与相对湿度的相关性最高,相关系数为-0.6501。不同季节条件下,能见度与PM2.5的相关性明显优于PM10的,冬季能见度与颗粒物的相关性明显优于其他季节的。  相似文献   

气候变化情景下黄淮海区域热量资源及夏玉米温度适宜度   总被引：2，自引：0，他引：2       下载免费PDF全文

李萌  申双和  吕厚荃  韩艳  褚荣浩  沙修竹 《大气科学学报》2016,39(3):391-399

利用黄淮海区域90个站点1971—2000年逐日气象资料以及国家气候中心发布的未来气候变化情景(A1B)下区域气候模式(Reg CM3)模拟的黄淮海区域1951—2070年0.25°×0.25°格点气象资料,结合夏玉米主要生育期对温度的需求,构建了黄淮海区域的温度适宜度和变异系数模型,并对1951—2070年黄淮海区域热量资源、夏玉米主要生育期的温度适宜度及其变异系数的时空变化特征进行分析。结果表明:1)黄淮海区域≥10℃积温和80%保证率下日平均温度≥10℃的初日均呈现由北向南依次增加的趋势,且随时间推移,分别呈增加和提前趋势。2)黄淮海区域夏玉米播种—出苗期的温度适宜度随时间整体呈逐渐上升的变化趋势、其变异系数随时间呈降—升—降的变化趋势;出苗—抽雄期的温度适宜度随时间呈先降后升的变化趋势、其变异系数呈降—升—降—升的变化趋势;抽雄—成熟期的温度适宜度空间上呈现2010年前北低南高、未来情景下中部低四周高的分布趋势,时间上呈2010年前稳定、未来情景下先降后升的变化趋势,其变异系数呈相反变化趋势;3)黄淮海区域夏玉米温度适宜度及其变异系数从播种—出苗期—出苗—抽雄期—抽雄—成熟期均呈反相位的变化关系。  相似文献   

Re-parameterization of a quasi-analytical algorithm for colored dissolved organic matter dominant inland waters     

《International Journal of Applied Earth Observation and Geoinformation》2016

Quasi-Analytical Algorithms (QAAs) are based on radiative transfer equations and have been used to derive inherent optical properties (IOPs) from the above surface remote sensing reflectance (R_rs) in aquatic systems in which phytoplankton is the dominant optically active constituents (OACs). However, Colored Dissolved Organic Matter (CDOM) and Non Algal Particles (NAP) can also be dominant OACs in water bodies and till now a QAA has not been parametrized for these aquatic systems. In this study, we compared the performance of three widely used QAAs in two CDOM dominated aquatic systems which were unsuccessful in retrieving the spectral shape of IOPS and produced minimum errors of 350% for the total absorption coefficient (a), 39% for colored dissolved matter absorption coefficient (a_CDM) and 7566.33% for phytoplankton absorption coefficient (a_phy). We re-parameterized a QAA for CDOM dominated (hereafter QAA_CDOM) waters which was able to not only achieve the spectral shape of the OACs absorption coefficients but also brought the error magnitude to a reasonable level. The average errors found for the 400–750 nm range were 30.71 and 14.51 for a, 14.89 and 8.95 for a_CDM and 25.90 and 29.76 for a_phy in Funil and Itumbiara Reservoirs, Brazil respectively. Although QAA_CDOM showed significant promise for retrieving IOPs in CDOM dominated waters, results indicated further tuning is needed in the estimation of a(λ) and a_phy(λ). Successful retrieval of the absorption coefficients by QAA_CDOM would be very useful in monitoring the spatio-temporal variability of IOPS in CDOM dominated waters.  相似文献   

陕北风沙区含砾石工程堆积体坡面产流产沙试验   总被引：1，自引：0，他引：1       下载免费PDF全文

康宏亮  王文龙  薛智德  郭明明  李建明  白芸  邓利强  李艳富 《水科学进展》2016,27(2):256-265

采用室内人工模拟降雨方法,研究了陕北风沙区含砾石工程堆积体边坡的产流产沙过程。结果表明:①砾石存在改变了坡面入渗速率,径流系数受入渗速率的影响,随砾石含量的增加先线性递减后线性递增,并在10%砾石含量处存在阈值;径流系数随降雨强度的增加线性递增。②含砾石堆积体坡面流速较纯土堆积体降低,且随雨强增大,砾石延缓径流流动的作用越显著;雨强对径流流速的影响随砾石含量增加持续减弱。③土壤剥蚀率在产流24~33 min后显著增加,砾石主要对显著增加后的平均剥蚀率产生影响。④雨强1.0 mm/min时,砾石存在促进降雨侵蚀,产沙量增大;雨强大于1.0 mm/min时,砾石具有显著的减沙效应。  相似文献   

The effects of yawing motion with different frequencies on the hydrodynamic performance of floating vertical-axis tidal current turbines     

《Applied Ocean Research》2016

Under real sea conditions, the hydrodynamic performance of floating vertical-axis tidal current turbines is affected by waves and currents. The wave circular frequency is a significant factor in determining the frequencies of the wave-induced motion responses of turbines. In this study, the ANSYS-CFX software (manufacturer: ANSYS Inc., Pittsburgh, Pennsylvania, United States) is used to analyse the hydrodynamic performance of a vertical-axis turbine for different yawing frequencies and to study how the yawing frequencies affect the main hydrodynamic coefficients of the turbine, including the power coefficient, thrust coefficient, lateral force coefficient, and yawing moment coefficient. The time-varying curves obtained from the CFX software are fitted using the least-squares method; the damping and added mass coefficients are then calculated to analyse the influence of different yawing frequencies. The simulation results demonstrate that when analysing non-yawing turbines rotating under constant inflow, the main hydrodynamic coefficient time-varying curves of yawing turbines exhibit an additional fluctuation. Furthermore, the amplitude is positively correlated with the yawing frequency, and the oscillation amplitudes also increase with increasing yawing frequency; however, the average values of the hydrodynamic coefficients (except the power coefficient) are only weakly influenced by yawing motion. The power coefficient under yawing motion is lower than that under non-yawing motion, which means that yawing motion will cause the annual energy production of a turbine to decrease. The fitting results show that the damping term and the added mass term exert effects of the same level on the loads and moments of vertical-axis turbines under yawing motion. The results of this study can facilitate the study of the motion response of floating vertical-axis tidal current turbine systems in waves.  相似文献   

Axial friction response of full-scale pipes in soft clays     

《Applied Ocean Research》2016

The axial friction response of subsea pipelines in soft clays is a very important aspect for designers of subsea pipelines but the response is not well understood so far. There is a pressing need for the comprehension of the response. In this paper, model tests are performed using full-scale pipes coated with polyethylene (PE) to study the effects of the set-up period, the pipe diameter, the buried depth of the pipe, the shear strength of soft clays and the loading rate on the axial friction response of pipelines in soft clays. The variations of the axial friction coefficient are analyzed using the effective stress method based on model test results. The results show that the axial friction resistance increases with the increasing pipe diameter but the effect of the pipe diameter on the axial friction coefficient can be neglected. The ultimate axial resistance also increases with the increase of the buried depth of pipelines, the undrained shear strength of soft clays and the loading rate. The axial friction coefficient increases with the increasing loading rate. However, the axial friction coefficient decreases with the increasing buried depth. The method to determine the axial friction coefficient is developed by analyzing model test results, which considers the effects of the diameter, the buried depth, the undrained shear strength of soft clays and the loading rate. The study results not only extend the industry data base but also supply a basis to determine the axial friction coefficient of PE-coated pipes in soft clays for ocean engineering geological investigations.  相似文献   

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials          下载免费PDF全文

Pei‐Pei Zhao  Jie Li  Le Zhang  Zhi‐Bing Wang  De‐Xin Kong  Jin‐Long Ma  Gang‐Jian Wei  Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2016,40(2):217-226

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献   

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy          下载免费PDF全文

Atsuyuki Ohta  Ran Kubota 《Geostandards and Geoanalytical Research》2016,40(1):117-134

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).  相似文献   

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy          下载免费PDF全文

Jesse D. Ward  Mark Bowden  C. Tom Resch  Steven Smith  Bruce K. McNamara  Edgar C. Buck  Gregory C. Eiden  Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   

High Precision Sr‐Nd‐Hf‐Pb Isotopic Compositions of USGS Reference Material BCR‐2          下载免费PDF全文

Jason Jweda  Louise Bolge  Cornelia Class  Steven L. Goldstein 《Geostandards and Geoanalytical Research》2016,40(1):101-115

The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were ⁸⁷Sr/⁸⁶Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), ¹⁴³Nd/¹⁴⁴Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and ¹⁷⁶Hf/¹⁷⁷Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were ²⁰⁶Pb/²⁰⁴Pb = 18.8029 ± 10 (2s, 55 ppm), ²⁰⁷Pb/²⁰⁴Pb = 15.6239 ± 8 (2s, 52 ppm), ²⁰⁸Pb/²⁰⁴Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions.  相似文献