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41.
J. P. BUTLER R. A. JAMIESON H. M. STEENKAMP P. ROBINSON 《Journal of Metamorphic Geology》2013,31(2):147-163
Ultrahigh‐pressure (UHP) rocks from the Western Gneiss Region (WGR) of Norway record subduction of Baltican continental crust during the Silurian to Devonian Scandian continental collision. Here, we report a new coesite locality from the island of Harøya in the Nordøyane UHP domain, the most northerly yet documented in the WGR, and reconstruct the P–T history of the host eclogite. The coesite–eclogite lies within migmatitic orthogneiss, interpreted as Baltica basement, that underwent multiple stages of deformation and partial melting during exhumation. Two stages of metamorphism have been deduced from petrography and mineral chemistry. The early (M1) assemblage comprises garnet (Pyr38–41Alm35–37Grs23–26Spss1) and omphacite (Na0.35–0.40Ca0.57–0.60Fe2+0.08–0.10Mg0.53Fe3+0.01AlVI0.40–0.42)2(AlIV0.03–0.06Si1.94–1.97)2O6, with subordinate phengite, kyanite, rutile, coesite and apatite, all present as inclusions in garnet. The later (M2) assemblage comprises retrograde rims on garnet (Pyr38–40Alm40–44Grs16–21Spss1), diopside rims on omphacite (Na0.04–0.06Ca0.88–0.91Fe2+0.09–0.13Mg0.81–83Fe3+0.08AlVI0.03)2(AlIV0.07–0.08Si1.92–1.93)2O6, plagioclase, biotite, pargasite, orthopyroxene and ilmenite. Metamorphic P–T conditions estimated using thermocalc are ～3 GPa and 760 °C for M1, consistent with the presence of coesite, and ～1 GPa and 813 °C for M2, consistent with possible phengite dehydration melting during decompression. Comparison with other WGR eclogites containing the same assemblage shows a broad similarity in peak (M1) P–T conditions, confirming suggestions that large portions of the WGR were buried to depths of ～100 km during Scandian subduction. Field relations suggest that exhumation, accompanied by widespread partial melting, involved an early phase of top‐northwest shearing, followed by subhorizontal sinistral shearing along northwest‐dipping foliations, related to regional transtension. The present results add to the growing body of data on the distribution, maximum P–T conditions, and exhumation paths of WGR coesite–eclogites and their host rocks that is required to constrain quantitative models for the formation and exhumation of UHP metamorphic rocks during the Scandian collision. 相似文献
42.
Silicon-bearing rutile has been found in chromitite from the Luobusa (罗布莎) ophiolite, Tibet. However, the extent of SiO2 solubility in rutile and the nature of its origin are still unclear. At high pressure, SiO2 takes a rutile structure with Si in 6-fold coordination. Thus, high pressures may enhance its solubility in rutile because of possible isovalent exchange in the oetabedral site. In this study, we report new experimental results on SiO2 solubility in rutile up to 23 GPa and 2 000 ℃. Starting materials were mixtures of powdered pure rutile and pure quartz, with compositions of (Ti0.5Si0.5)O2,(Ti0.93Si0.07)O2, and (Ti0.75Si0.25)O2. The mixtures were loaded into either platinum capsules (for a 10/5 assembly) or rhenium capsules (for an 8/3 assembly). The experiments were carried out using multi-anvil high-pressure apparatus with a rhenium resistance heater. Sample temperatures were measured with a W5%Re-W26%Re thermoeouple and were controlled within ±1 ℃ of the set temperature. TiO2-rich and SiO2-rich phases were produced in all the quenched samples. Microprobe analyses of the phases show that the solubility of SiO2 in rutile increases with increasing pressure, from 1.5 wt.% SiO2 at 10 GPa to 3.8 wt.% SiO2 at 23 GPa at a temperature of 1 800 ℃. The solubility also increases with increasing temperature from 0.5 wt.% SiO2 at 1 500 ℃ to 4.5 wt.% SiO2 at 2 000 ℃ at a pressure of 18 GPa. On the other hand, the solubility of TiO2 in coesite or stishovite is very limited, with an average of 0.6 wt.% TiO2 over the experimental P-T ranges. Temperature has a much larger effect on the solubility of SiO2 in rutile than pressure. At high pressure, the melting point of SiO2 is defmitely higher than that of TiO2 and the eutectic point moves towards SiO2 in the TiO2-SiO2 system. Lower oxygen fugacity decreases the solubility of SiO2 in rutile, whereas water has little effect on the solubility. Our experimental data are extremely useful for determining the depth of origin of the SiO2-bearing ruffle found in nature. 相似文献
43.
Petrology of coesite-bearing eclogite from Habutengsu Valley, western Tianshan, NW China and its tectonometamorphic implication 总被引：7，自引：0，他引：7
Coesite inclusions in garnet have been found in eclogite boudins enclosed in coesite‐bearing garnet micaschist in the Habutengsu Valley, Chinese western Tianshan, which are distinguished from their retrograde quartz by means of optical characteristics, CL imaging and Raman spectrum. The coesite‐bearing eclogite is mainly composed of porphyroblastic garnet, omphacite, paragonite, glaucophane and barroisite, minor amounts of rutile and dotted (or banded) graphite. In addition to coesite and quartz, the zoned porphyroblastic garnet contains inclusions of omphacite, Na‐Ca amphibole, calcite, albite, chlorite, rutile, ilmenite and graphite. Multi‐phase inclusions (e.g. Czo + Pg ± Qtz, Grt II + Qtz and Chl + Pg) can be interpreted as breakdown products of former lawsonite and possibly chloritoid. Coesite occurs scattered within a compositionally homogenous but narrow domain of garnet (outer core), indicative of equilibrium at the UHP stage. The estimate by garnet‐clinopyroxene thermometry yields peak temperatures of 420–520 °C at 2.7 GPa. Phase equilibrium calculations further constrain the P–T conditions for the UHP mineral assemblage Grt + Omp + Lws + Gln + Coe to 2.4–2.7 GPa and 470–510 °C. Modelled modal abundances of major minerals along a 5 °C km?1 geothermal gradient suggests two critical dehydration processes at ～430 and ～510 °C respectively. Computed garnet composition patterns are in good agreement with measured core‐rim profiles. The petrological study of coesite‐bearing eclogite in this paper provides insight into the metamorphic evolution in a cold subduction zone. Together with other reported localities of UHP rocks from the entire orogen of Chinese western Tianshan, it is concluded that the regional extent of UHP‐LT metamorphism in Chinese western Tianshan is extensive and considerably larger than previously thought, although intensive retrogression has erased UHP‐LT assemblages at most localities. 相似文献
44.
A paleo-alluvial 0.21 ct yellow diamond (L058) from Bingara (NSW) has three inclusions of coesite (two subequant crystals and one thin plate), each under more than 3.1 GPa internal pressure as measured by Raman spectroscopy. These inclusions cause overlapping birefringent retardation stress/strain haloes in the host diamond, visible under cross-polarised light. The complicated retardation pattern is quantified by mapping targeted retardation contours (170 nm, 270 nm and 380 nm) onto a photo of the diamond. A mathematical model of retardation is developed for each inclusion, and then the combined light retardations (CLR) are calculated using radial and tangential components with spherical and elliptical geometries. The CLR model reproduces most features of the measured data, but remaining differences may be due to local release of stress/strain by two short fractures radiating from one inclusion. 相似文献
45.
大别地区榴辉岩中几种超高压变质矿物研究 总被引：2，自引：0，他引：2
根据镜下观察,在大别地区东南部榴辉岩中陆续发现柯石英、金刚石和文石等三种超高压变质矿物,拉曼分子探针检测进一步证实了这些发现。柯石英和文石均被包裹于石榴石或绿辉石晶体之内,而基质中则分别以低压多型变体石英和方解石的形式存在,说明其保存除快速构造抬升的外部条件外,还与寄主矿物机械阻力及晶内低压缩性有关。作为榴辉岩相的早期共生矿物,它们的出现证明该区榴辉岩经历了超高压变质作用。 相似文献
46.
Abstract The Maksyutov Complex, situated in the southern Ural Mountains of Russia, is the first location where quartz aggregates within garnets exhibiting radial fractures were identified as coesite pseudomorphs (Chesnokov & Popov 1965). The complex consists of two tectonic units: a structurally lower eclogite-bearing schist unit and an overlying meta-ophiolite unit. Both units show evidence for multiple stages of metamorphism and deformation. The high-pressure metamorphism of the eclogite-bearing schist unit, discussed in this report, is suspected to be related to a collision between the Russian platform and a fragment of the Siberian continent during the early Cambrian. At least three stages of metamorphism (M1-3 ) and two stages of deformation (S1 and S2 ) were observed in thin sections: M1 ) garnet (Alm55-60 , Prp22-28 , Grs16-20 ) + omphacite (Jd46-56 ) + phengite (Si ≅ 3.5) + rutile; M2 ) garnet + glaucophane ± lawsonite + white mica; and M3 ) epidote + chlorite ± albite ± actinolite + white mica. Observed mineral parageneses define a retrograde P-T path for the eclogite. Mineral assemblages within the most representative eclogite from the lower unit of the Maksyutov Complex indicate minimum peak pressures of 15 kbar at temperatures of approximately 600°C. If the presence of coesite pseudomorph is confirmed, the peak ultrahigh-pressure metamorphism may be as high as 27 kbar at 615°C. 相似文献
47.
Abstract The Kokchetav Complex is a tectonic mega-melange consisting of seven pre-Ordovician units (units I-VII) of contrasting lithologies and P–T conditions of metamorphism, overlain and/or intruded by four post-recrystallization entities. Most of the constituent rock types display affinities with continental crust; paraschists and paragneisses, which carry biogenically produced carbon, clearly were laid down near the surface of the Earth. Microdiamond (and rare coesite) inclusions are contained in strong, refractory garnet, zircon, clinopyroxene, and kyanite, some of the constituent neoblastic phases of this metasedimentary unit. Systematic mineral parageneses and textural relationships support the hypothesis that the metamorphic assemblages represent a close approach to chemical equilibrium at the time of formation. Metamorphism of diamond-bearing paragneisses and schists transpired at 535 ± 5 Ma; physical conditions included minimum pressures of 40 kbar and temperatures exceeding 900 °C. Other associated units contain mineralogic evidence of somewhat lower to considerably lower pressures and temperatures: observed magnesite + diopside pairs, coesite, grossular-pyropic garnet, potassic clinopyroxene, Si-rich phengite, barroisite-crossite(?), aluminous titanite and/or Al-rutile, and the assemblage talc + kyanite + garnet all testify to relatively elevated pressures of formation. The metamorphosed lithotectonic units represent individual, discrete stages in what initially may have been a continuous P-T series, but intense post-metamorphic dislocation has resulted in the preservation of a chaotically mixed sequence rather than an unbroken gradation in preserved conditions of metamorphism. Only units I-III, and probably VIb may represent portions of a dismembered subduction zone lithologie assemblage. The uplift to mid-crustal levels and cooling of the mega-melange took place by about 515–517 Ma, at which time the complex was stabilized as a part of the Kazakhstan microcontinental collage. An hypothesized Late Vendian-Early Cambrian subduction of the Kazakhstan-North Tianshan(?) microcontinental salient to depths exceeding 125 km, followed by decoupling from the descending oceanic crust-capped lithospheric plate is held responsible for the ultrahigh-pressure metamorphism of the Kokchetav Complex. Inasmuch as vestiges of a calc-alkaline volcanic/plutonic arc of approximately Early Cambrian age are preserved as only scattered relics in the general region, the plate-tectonic setting may have involved an intra-oceanic, Marianas-type, incipient arc which was subsequently removed through transform faulting or erosion. 相似文献
48.
Mineral parageneses and metamorphic P-T paths of ultrahigh-pressure eclogites from Kyrghyzstan Tien-Shan 总被引：3，自引：0，他引：3
Abstract Eclogites occur in three districts of the northern and southern parts of Tien-Shan. Three eclogites collected from the Aktyuz, Makbal and Atbashy districts were analyzed; the P-T paths of three eclogites were estimated by analyzing compositional growth zoning and retrograde reaction of garnet and omphacite. Aktyuz and Makbal eclogites have not preserved the prograde path. An Aktyuz eclogite that underwent a quartz eclogite facies metamorphism (about T = 600°C, P = 12 kbar) has recorded three stages of retrograde metamorphism. Four stages of retrograde metamorphism were recognized in a Makbal eclogite; the garnet-omphacite geothermometer gave about T = 560°C at 20 kbar as the highest metamorphic condition. Garnet from a garnetchloritoid-talc schist of the Makbal district includes quartz pseudomorphs after coesite; some units evidently underwent a low-temperature part of coesite eclogite fades metamorphism. Prograde and retrograde paths were recognized in an Atbashy eclogite; five stages of metamorphic reaction were observed in the Atbashy sample. The prograde path from stage I to stage III has been recorded in garnet and omphacite in which quartz pseudomorphs after coesite are included. The peak metamorphism of stage III took place at about 660°C at 25 kbar. The stages IV and V are retrograde. UHP eclogite facies metamorphism took place twice in Kyrghyzstan. The Aktyuz and Atbashy eclogites gave Rb-Sr mineral-isochron ages of about 750 Ma and 270 Ma, respectively. The K-Ar age of paragonite from the Makbal eclogite is about 480 Ma. 相似文献
49.
Abstract According to field occurrence and P-T condition, eclogites of southern Henan and northern Hubei Provinces can be divided into two types: medium temperature (MT) and low temperature (LT) eclogites. MT eclogite occurs as layers or lenticular bodies within migmatized gneiss of the Dabie Group. This study is the first to report an occurrence of the assemblages coesite and kyanite + talc in this area. Garnet exhibits a distinct prograde compositional zoning and has mineral inclusions with rotational textures indicating syntectonic growth. Five evolutionary stages are outlined. (1) Pre-eclogite stage, determined by the inclusions of barroisite + zoisite + quartz in the cores of zoned garnets. (2) Eclogite stage, characterized by garnet + omphacite + kyanite ± talc + coesite + rutile, represents the peak metamorphism. The peak conditions are estimated to be T = 600-700°C, P >27 kb. (3) Glaucophane stage, without an appearance of plagioclase, is assigned to a transitional stage. Blades of glaucophane form rims around garnet grains as a result of the reaction talc + jadeite = glaucophane. This marks the beginning of retrograde metamorphism. (4) Symplectite stage, where eclogitic minerals break down, and Amp + Pl symplectite develops around garnet or omphacite; (5) Later retrograde stage is represented by epidote-amphibolite assemblages. Low temperature eclogite appears as blocks in the Qijiaoshan Formation (part of the Susong Group). Four stages can be identified: (1) Pre-eclogite stage, amphibole + epidote + sphene inclusions occur in garnet core; (2) Eclogite stage, consists of garnet + omphacite + rutile + quartz + phengite + glaucophane + zoisite. The peak conditions are T = 490-560°C, P <15 kb; (3) Symplectitic stage, is characterized by the breakdown of eclogitic minerals; (4) Greenschist facies stage, is recorded by a greenschist facies assemblage. The difference between the two types of eclogites suggests contrasting processes. A model is proposed whereby partial melting of continental crust and the emplacement of tonalite occurs during the exhumation of ultrahigh-pressure eclogite terrain. 相似文献
50.
The ultrahigh- and high-pressure (UHP–HP) metamorphic belt of the Dabie Mountains, central China, formed by the Triassic continental subduction and collision, is divided into four metamorphic zones; from south to north, the greenschist facies zone, epidote amphibolite to amphibolite facies zone, quartz eclogite zone, and coesite eclogite zone, based on metabasite mineral assemblages. Most of the coesite-bearing eclogites consist mainly of garnet and omphacite with homogeneous compositions and have partially undergone hydration reactions to form clinopyroxene + plagioclase + calcic amphibole symplectites during amphibolite facies overprinting. However, the least altered eclogites sometimes contain garnet and omphacite that preserve compositional zoning patterns which may have originated during their growth at peak temperature conditions of ∼ 750 °C, suggesting a short duration of UHP metamorphic conditions and/or consequent rapid cooling during exhumation. Systematic investigation on peak metamorphic temperatures of coesite eclogite have revealed that, contrary to the general trend of metamorphic grade in the southern Dabie unit, the coesite eclogite zone shows rather flat thermal structure (T = 600 ± 50 °C) with the highest temperature reaching up to 850 °C and no northward increase in metamorphic temperature, which is opposed to the previous interpretations. This feature, along with the preservation of compositional zonation, implies complicated differential movement of each eclogite mass during UHP metamorphism and the return from the deeper subduction zone at mantle depths to the surface. 相似文献