Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden   总被引：7，自引：2，他引：7  

Zhixun Lin  Roger B. Herbert Jr. 《Environmental Geology》1997,33(1):1-12

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997  相似文献   

Electrokinetic remediation of metal contaminated glacial tills   总被引：2，自引：0，他引：2  

K.R. Reddy  A.B. Shirani 《Geotechnical and Geological Engineering》1997,15(1):3-29

This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed.  相似文献   

提高地方地震台网地震速报水平初探     

王登伟  管勇  马付红 《四川地震》2004,(2):12-15,20

总结了西昌遥测地震台网地震速报处理技术经验，针对地方台网地震速报中常出现的地震参数误差提出了改进思路。  相似文献   

Seasonal and Diurnal Variation of Surface Ozone and a Preliminary Analysis of Exceedance of its Critical Levels at a Semi-arid Site in India   总被引：1，自引：0，他引：1  

Gur Sumiran Satsangi  A. Lakhani  P. R. Kulshrestha  A. Taneja 《Journal of Atmospheric Chemistry》2004,47(3):271-286

The mixing ratios of surface O₃ were measured at St. John's College, Agra, an urban and traffic influenced area for the period of 2000–2002. The monthly averaged O₃ mixing ratios ranged between 8 to 40 ppb with an annual average of 21 ppb. Strong diurnal and seasonal variations in O₃ mixing ratios were observed throughout the year except for monsoon season. The mixing ratios of O₃ follow the surface temperature cycle and solar radiation (r = 0.72 and r = 0.65 with temperature and solar radiation, respectively). Concentrations were higher with winds associated with NE and NW direction indicating the impact of pollution sources on surface O₃ concentration. Exceedance of ozone critical level was calculated using the AOT 40 index and found to be 840 ppb.h and 2430 ppb.h for summer and winter seasons, respectively. The present O₃ exposures are lower than the critical level of O₃ and suggest that the present level of O₃ does not have any impact on reduction in crop yields.  相似文献   

长春市城市土壤中重金属元素的积累及其微生物特性研究   总被引：10，自引：2，他引：10  

刘乃瑜  马小凡  谢忠雷  郭平 《吉林大学学报(地球科学版)》2004,(Z1)

由于人为活动的影响,长春市城市土壤中重金属Cu、Zn、Pb、Cd已有了显著积累。在重金属的胁迫下,土壤微生物特征发生了明显变化,微生物代谢活动明显增强,但微生物生物量却有较大的降低。微生物生理生态参数土壤微生物量碳与总有机碳的比值(Cmic/Corg)和代谢商QCO2(微生物呼吸作用强度与微生物量碳的比值)变化异常。研究表明,微生物特性可作为城市土壤环境中重金属含量变异的有效指标。  相似文献   

多年冻土地区砂砾路面路堤临界高度数值分析     

张明义  赖远明  张建明  齐吉琳 《冰川冻土》2004,26(Z1):76-82

In permafrost regions of Qinghai-Tibetan Plateau, the critical embankment height must be considered in the process of the construction of highway, especially for the global climatic warming. In this paper, the two-dimensional numerical analysis for the critical embankment height (for gravel road surface and coarse-grained soil) has been performed by using thefinite element method. In the calculation, we think that the service life of the construction is at least 50 years. The mean annual air temperatures applied to the calculation model are -6.5 ℃, -6.0 ℃, -5.5 ℃, -5.0 ℃, -4.5 ℃ and -4.0 ℃, respectively, and the value of temperature rise are taken as 1.10℃ in the coming 50 years. The minimum embankment heights derived from the analysis are 0.85 m, 0.92 m, 1.01 m, 1.18 m, 1.60 m and 2.66 m for the different mean annual air temperatures and the maximum embankment heights are 7.68 m,7.55 m, 7.34 m, 7.00 m, 6.45 m and 5.85m, accordingly. On condition that the service life of embankment is 50 years, the critical value of the mean annual air temperature is -3.5 ℃. Namely, in the areas where the mean annual air temperature is higher than -3.5 ℃, the critical embankment height does not exist.  相似文献   

磁学方法在环境污染研究中的应用   总被引：12，自引：0，他引：12  

闫海涛  胡守云  朱育新 《地球科学进展》2004,19(2):230-236

环境磁学方法问世20多年来，因其快速、灵敏、经济、无破坏性和信息量大的特点，在环境研究中得到广泛的应用。磁学方法可用于传统的污染分析技术（化学）之前的预研究，而后者一般耗费大量人力、物力和时间；它也可以作为环境污染评估的代用指标。近年来，随着世界环境污染问题的日益严重和倍受关注，磁学方法被广泛地应用于环境污染研究。欧洲环境磁学专家在重建污染历史、监测现代环境污染、追踪与分离污染源等方面，开展了大量的工作，并积累了一定的经验。介绍了磁学方法用于污染研究的显著特点、主要用途、野外工作方法以及相关仪器；展示了在大气、土壤、潮滩、河流、湖泊以及海洋等不同环境系统中，利用磁手段研究污染的成果和最新进展；对 于一些难点、热点问题，如磁性机理的研究、多源污染的分离、强烈多变的人类活动对获取有意义磁讯号的影响等，做了相应的分析和总结。  相似文献   

水泥土桩单桩荷载传递及临界桩长研究   总被引：7，自引：0，他引：7  

吴雄志 《岩土力学》2004,25(9):1491-1494

将克拉夫-邓肯模型作为传递函数，对水泥土桩荷载传递规律及临界桩长进行了研究，描述了桩周摩阻力的分布及发展规律，并详细讨论了临界桩长的确定标准及各种因素对临界桩长的影响。结果表明，该方法是可行的，该方法同样适用于其它形式的柔性桩。  相似文献   

区域滑坡泥石流灾害预警理论与方法研究   总被引：39，自引：4，他引：39  

刘传正 《水文地质工程地质》2004,31(3):1-6

根据数年来的调查观测研究和工作实践,提出了滑坡泥石流灾害的预警分类体系,包括按物理参量划分的空间、时间与强度预警和按诱发因素参量划分的气象、地震与人类活动预警以及多参数、多因素共同作用下的综合预警。初步创建了区域性滑坡泥石流灾害暴发的两种预警理论方法,一种是基于临界过程降雨量判据图的预警方法;另一种是基于GIS的地质环境空间分析预警理论方法,通过计算预警区的滑坡泥石流灾害"发育度"、"潜势度"、"危险度"和"危害度"来实现。阐述了滑坡泥石流灾害预警的技术和行政工作程序,指出建立临界过程降雨量判据与地质环境空间分析相耦合的滑坡泥石流灾害预警理论方法是研究的新方向。  相似文献   

云南会泽超大型铅锌矿床成因研究中的几个问题   总被引：6，自引：0，他引：6  

黄智龙  李文博  张振亮  韩润生  陈进 《矿物学报》2004,24(2):105-111

位于川-滇-黔铅锌多金属成矿域中南部云南会泽超大型铅锌矿床可能是一种新的铅锌矿床类型，该类铅锌矿床明显特征是规模大、品位富、伴生有用元素多，暗示其成矿环境较为特殊。从成矿时代、成矿物质来源、成矿流体来源与演化，以及峨眉山玄武岩与成矿的关系等方面分析了会泽超大型铅锌矿床的研究进展及国内外研究现状，认为矿床成矿时代与西南大面积峨眉山玄武岩成矿时代相近，成矿物质和成矿流体具有“多源性”，成矿流体存在均一化过程，区域大规模流体运移在该区铅锌成矿过程中具有重要意义，峨眉山玄武岩岩浆活动与铅锌成矿具有密切的成因联系，矿床可能为“均一化成矿流体贯入成矿”的产物。  相似文献