伊利石结晶度在恢复地层剥蚀量中的应用--以合肥盆地安参1井白垩系剥蚀量的恢复为例   总被引：2，自引：0，他引：2  

徐春华  朱光  刘国生  李春华 《地质科技情报》2005,24(1):41-44

针对合肥盆地勘探程度低、地热史资料缺乏的现状,提出利用伊利石结晶度与埋藏深度和成岩温度之间的对应关系来确定古地温梯度,进而利用温度资料求取原始地层厚度和剥蚀量,并利用包裹体测温和镜质体反射率两种方法计算出安参1井白垩系的原始地层厚度和剥蚀量,其结果具有较好的可比性,为深化盆地下侏罗统和下白垩统烃源岩的热演化研究提供了保证.  相似文献   

Metamorphism,graphite crystallinity,and sulfide anatexis of the Rampura–Agucha massive sulfide deposit,northwestern India     

Biswajit Mishra  Heinz-Jurgen Bernhardt 《Mineralium Deposita》2009,44(2):183-204

Located adjacent to the Banded Gneissic Complex, Rampura–Agucha is the only sulfide ore deposit discovered to date within the Precambrian basement gneisses of Rajasthan. The massive Zn–(Pb) sulfide orebody occurs within graphite–biotite–sillimanite schist along with garnet–biotite–sillimanite gneiss, calc–silicate gneisses, amphibolites, and garnet-bearing leucosomes. Plagioclase–hornblende thermometry in amphibolites yielded a peak metamorphic temperature of 720–780°C, whereas temperatures obtained from Fe–Mg exchange between garnet and biotite (580–610°C) in the pelites correspond to postpeak resetting. Thermodynamic considerations of pertinent silicate equilibria, coupled with sphalerite geobarometry, furnished part of a clockwise P–T–t path with peak P–T of ∼6.2 kbar and 780°C, attained during granulite grade metamorphism of the major Zn-rich stratiform sedimentary exhalative deposits orebody and its host rocks. Arsenopyrite composition in the metamorphosed ore yielded a temperature [and log f(S ₂)] range of 352°C (−8.2) to 490°C (−4.64), thus indicating its retrograde nature. Contrary to earlier research on the retrogressed nature of graphite, Raman spectroscopic studies on graphite in the metamorphosed ore reveal variable degree of preservation of prograde graphite crystals (490 ± 43°C with a maximum at 593°C). The main orebody is mineralogically simple (sphalerite, pyrite, pyrrhotite, arsenopyrite, galena), deformed and metamorphosed while the Pb–Ag-rich sulfosalt-bearing veins and pods that are irregularly distributed within the hanging wall calc–silicate gneisses show no evidence of deformation and metamorphism. The sulfosalt minerals identified include freibergite, boulangerite, pyrargyrite, stephanite, diaphorite, Mn–jamesonite, Cu-free meneghinite, and semseyite; the last three are reported from Agucha for the first time. Stability relations of Cu-free meneghinite and semseyite in the Pb–Ag-rich ores constrain temperatures at >550°C and <300°C, respectively. Features such as (1) low galena–sphalerite interfacial angles, (2) presence of multiphase sulfide–sulfosalt inclusions, (3) microcracks filled with galena (±pyrargyrite) without any hydrothermal alteration, and (4) high contents of Zn, Ag (and Sb) in galena, indicate partial melting in the PbS–Fe_0.96S–ZnS–(1% Ag₂S ± CuFeS₂) system, which was critical for metamorphic remobilization of the Rampura–Agucha deposit.  相似文献   

Illite crystallinity study of the Cretaceous Shimanto Belt in the Akaishi Mountains, eastern Southwest Japan   总被引：1，自引：0，他引：1  

Hirotaka  Tanabe Ken-Ichi  Kano 《Island Arc》1996,5(1):56-68

Abstract Illite crystallinity (IC) analyses in the Upper Cretaceous Shimanto accretionary complex of the southern Akaishi Mountains, eastern Southwest Japan confirm the applicability of this technique for evaluating the grade of diagenesis/metamorphism in a sediment-dominated accretionary complex. Reproducibility analyses of IC values show a variance of about 15% from the mean. Data from three traverses, which transect across-strike sections of ∼25 km, clearly demonstrate that the IC distributions have specific overall trends. The IC values belong to the lQwer anchizone and the zone of diagenesis. The IC distributions may be controlled locally by structural features, but there are no distinct relationships with regional-scale geological structures. This may indicate that the heterogeneous geothermal rise affected the pre-existing structural and diagenetic/metamorphic framework of the accretionary sequence. Along-strike variations of grade tend to increase toward the northeast where a Middle Miocene granitoid occurs. Hence, the original diagenetic/metamorphic framework of this part of the Shimanto Belt was presumably overprinted during the Middle Miocene.  相似文献   

Epigenetic dolomitization of the Přaídolí formation (Upper Silurian), the Barrandian basin,Czech Republic: implications for burial history of Lower Paleozoic strata     

V. Suchý  I. Rozkošný  K. Žák  J. Franců 《International Journal of Earth Sciences》1996,85(2):264-277

Stratabound epigenetic dolomite occurs in carbonate facies of the Barrandian basin (Silurian and Devonian), Czech Republic. The most intense dolomitization is developed in bioclastic calcarenites within the transition between micritic limestone and shaledominated Přídolí and Lochkov formations deposited on a carbonate slope. Medium-crystalline (100–400 μm), inclusion-rich, xenotopic matrix dolomite (δ ¹⁸O=−4.64 to −3.40‰ PDB;δ ¹³C=+1.05 to +1.85‰ PDB) which selectively replaced most of the bioclastic precursor is volumetrically the most important dolomite type. Coarse crystalline saddle dolomite (δ ¹⁸O=−8.04 to −5.14‰ PDB;δ ¹⁸C=+0.49 to +1.49 PDB) which precipitated in fractures and vugs within the matrix dolomite represents a later diagenetic dolomitization event. In some vugs, saddle dolomite coprecipitated with petroleum inclusion-rich authigenic quartz crystals and minor sulfides which, in turn, were post-dated by semisolid asphaltic bitumen. The interpretation of the dolomitization remains equivocal. Massive xenotopic dolomite, although generally characteristic of a deeper burial setting, may have been formed by a recrystallization of an earlier, possibly shallow burial dolomite. Deeper burial recrystallization by reactive basinal pore fluids that presumably migrated through the more permeable upper portion of the Přídolí sequence appears as a viable explanation for this dolomitization overprint. Saddle dolomite cement of the matrix dolomite is interpreted as the last dolomitization event that occurred during deep burial at the depth of the oil window zone. The presence of saddle dolomite, the fluid inclusion composition of associated quartz crystals, and vitrinite paleogeothermometry of adjacent sediments imply diagenetic burial temperatures as high as 160°C. Although high geothermal gradients in the past or the involvement of hydrothermally influenced basinal fluids can account for these elevated temperatures, burial heating beneath approximately 3-km-thick sedimentary overburden of presumably post-Givetian strata, no longer preserved in the basin, appears to be the most likely interpretation. This interpretaion may imply that the magnitude of post-Variscan erosion in the Barrandian area was substantially greater than previously thought.  相似文献   

关于甚低级变质作用与近变质带研究中的几个问题     

王河锦 《地质学报》2022,96(5):1711-1723

本文集中讨论了甚低级变质作用研究中涉及到的几个问题，包括：① 近变质带的创立及其在解决划分成岩作用与变质作用界线这一国际难题中所取得的进步；② 伊利石结晶度对碎屑岩甚低级变质作用研究起到的作用与贡献；③ 仪器校正、粒度大小及其与Kübler指数的经验关系式；④ 泥质碎屑岩中的成岩指示矿物与变质指示矿物；⑤ 松潘 甘孜、巴颜喀拉造山带的甚低级变质作用的模式与新的成因解释；⑥ 讨论了涉及到的科学研究的相关规则。提出了运用指示矿物结合伊利石结晶度划分成岩作用/变质作用界线的方案和建立喜马拉雅伊利石结晶度标样的重要性与必要性；提出碎屑岩甚低级变质作用的新成因模式。  相似文献   

由伊利石结晶度研究桂西右江地区区域极低级变质作用   总被引：10，自引：0，他引：10  

燕守勋  王志刚  黄永权 《地质科学》2003,38(1):107-113

运用伊利石结晶度Kübler指数将桂西右江地区下三叠统罗楼群和中三叠统百逢组下段划归为浅层变质带(K.I△2θ°为0.22～0.25);将中三叠统百逢组上段和河口组划归为近变质带,中三叠统百逢组上段为高级近变质带(K.I△2θ°为0.26～0.33);中三叠统上部河口组为低级近变质带(K.I△2θ°为0.38～0.40),不排除局部为成岩带的可能.地层柱自下向上,伊利石结晶度Kübler指数由小变大,变质程度由高变低,而且,变质作用级别与岩层在地层柱中位置协调以及变质带边界与地层界线趋于一致,证明为区域埋藏极低级变质作用.凌云明山金矿区剖面矿体和百逢组各层段伊利石结晶度Kübler指数为0.42～0.50,属成岩带,且没有明显时空变化规律.  相似文献   

Diagenesis of the Lower Cretaceous Kanmon Group sandstones, SW Japan     

Kyung Hwan Sur  Yong Il Lee  Ken-ichiro Hisada 《Journal of Asian Earth Sciences》2002,20(8)

The Kanmon Group (Lower Cretaceous) is a non-marine sequence in the Inner Zone of southwest Japan and is divided into the lower Wakino (lacustrine) and the upper Shimonoseki (fluvial) subgroups. Major diagenetic changes in this group are compaction, iron-oxide cementation, calcite cementation and grain replacement, quartz overgrowth and pore-fill cementation, illite authigenesis, chlorite pore-fill cementation and grain replacement, albitization of feldspar, and grain replacement by pyrite. Two subgroups of the Kanmon Group present no significant differences in general diagenetic features, paragenetic sequence, or the degree of diagenetic changes despite differences in depositional environments (lacustrine vs. fluvial) and stratigraphic positions. However, some differences are recognized in the content and chemistry of authigenic minerals caused by different sandstone framework compositions. The content of authigenic clay minerals is higher in sandstones of the Shimonoseki Subgroup containing abundant volcanic rock fragments. In addition, the composition of chlorite, the most abundant authigenic clay mineral in Kanmon sandstones, is Mg-rich in the volcanoclastic Shimonoseki sandstones, compared to an Fe-rich variety in Wakino sandstones. The original sandstone composition played a significant role in pore-water composition and diagenetic reactions.The Wakino sandstones lost most of its porosity by compaction, whereas Shimonoseki sandstones are only compacted in the vicinity of the basin-bounding fault. The weakly compacted Shimonoseki sandstones, instead, were largely cemented by pore-filling calcite during early diagenesis; cementation prevented compaction during further burial. The Kanmon Group sediments were heated to about 300 °C based on illite crystallinity values.  相似文献   

物理化学条件对合成Mg／Al-LDH结晶度和结构的影响   总被引：5，自引：1，他引：5       下载免费PDF全文

陈天虎庆承松  谌香秀冯有亮孙捷  于少明 《岩石矿物学杂志》2005,24(4):324-328

采用共沉淀法在不同物理条件下合成了一系列镁铝层状双氢氧化物(LDH),用化学分析、XRD和红外光谱对产物的组成与结构进行了表征,并探讨了初始溶液Mg/Al比、平衡pH值、水热反应温度、干燥温度等因素对合成LDH产物的结晶度、Mg/Al比、结构以及镁铝水解率的影响。结果表明,在实验条件范围内,最佳的合成条件为:初始Mg/Al比为2∶1,pH值为10,合成温度50℃,在此条件下固体产物为单一LDH物相,合成LDH的Mg/Al比为2∶1,镁铝水解率分别为99.21%和98.97%,结晶度高,可以实现在较低的温度下水热合成LDH。由于在LDH结构中Al3 替代Mg2 的量不同,导致X衍射分析d值和晶胞参数呈规律性变化。  相似文献   

TEM and XRD determination of crystallite size and lattice strain as a function of illite crystallinity in pelitic rocks   总被引：2，自引：0，他引：2  

W.-T. JIANG  D. R. PEACOR  P. ÁRKAI  M. TÓTH  & J. W. KIM 《Journal of Metamorphic Geology》1997,15(2):267-281

Average crystallite size and mean-square strain of illite in rock specimens and clay separates were measured independently in TEM images and by single-line Fourier (Voigt method) profile analysis of the c. 1 nm peak of XRD patterns for a prograde sequence of pelitic rocks (illite crystallinity indices=0.17–0.58°Δ2θ) from the Gaspé Peninsula, Quebec. The TEM-determined crystallite sizes in clay separates approximate those determined by Fourier profile analyses and those calculated from illite crystallinity indices by the Scherrer equation, with the exception of the diagenetic sample. The crystallite sizes and mean-square strains of illite in rock samples exhibit a trend similar to that determined by profile analyses, but the average crystallite sizes are up to five times larger than those measured for clay separates. TEM images show that all rock samples have a wide range of crystallite sizes, and the proportions of larger crystallites increase with metamorphic grade. The diagenetic illite is defect-rich, fine-grained (mean thickness by volume=c. 70 nm), 1M_d material. Anchizonal illite tends to occur as separate aggregates of small 1M_d and larger 2M₁ crystals (c. 200 nm), comprising arrays of subparallel coalescing packets. The epizone sample has thick (c. 400 nm), defect-free crystals of muscovite occurring in stacks of parallel layers, or subhedral crystals intergrown with large-angle boundaries. Cleaved crystals that are free of intracrystalline layer terminations are dominant in clay separates of all samples, having ranges of smaller sizes with volume-average thicknesses of c. 43, 43, and 81 nm (c. 14, 28, 67 nm by the Voigt method), respectively, for the three zones. The results suggest that illite crystallinity indices do not provide a direct measure of a single microstructural state of illite in rocks, although they yield consistent limits for average crystallite sizes for the anchizone (23 & 48 nm here). Therefore, they serve as a general parameter of the degree of recrystallization on a relative basis, in part because the contributions of all peak-broadening variables (mixed layering, size and strain) decrease regularly with prograde regional metamorphism of pelites. The microstructural changes caused by rock disaggregation are probably a function of those variables as well. The data collectively demonstrate a trend from metastable, defect-rich, small crystals towards a stable assemblage of larger, defect-free crystals, through dissolution of strained crystals and neocrystallization, consistent with the Ostwald step rule.  相似文献   

高岭土矿物组分特征对纸张涂布粘浓度的影响   总被引：1，自引：0，他引：1  

许韩榕 《福建地质》1995,14(1):49-54

粘浓度是纸张涂布的一项重要指标，它受涂布高岭土的矿物组分特征所影响。蒙脱石、水云母类矿物的存在，特别是蒙脱石的混入对涂布高岭土是有害的。高岭石的结晶有序度与粘浓度存在一定联系。高岭石的结晶指数采用Ｈｉｎｃｋｌｅｙ方法测定，从０．３３变化至１．２７，其粘浓度的范围从４１．７－６６．５％。当结晶度指数大于１时，粘浓度大于６６％；当结晶度指数小于１时，粘浓度小于６６％。有序的高岭石有利于粘浓度的提高。进  相似文献