利用小波阈值消噪改进M-W组合周跳探测性能     

戚国宾  甘雨  隋立芬  肖国锐  刘乾坤 《测绘科学技术学报》2015,(1):22-26,31

受伪距噪声的影响,Turbo Eidt法中M-W组合难以探测所有周跳。分析了M-W组合观测量的误差特性,指出伪距误差导致周跳漏检、探测延迟的原因。采用小波阈值消噪方法对M-W组合观测值进行处理,阈值估计使用Visushrink方法可削弱伪距噪声、增加周跳的辨识度。消噪后,周跳会发生扩散,除当前历元外,前后多个历元均会超出阈值,便于探测。实测数据结果表明:经小波消噪后的M-W组合观测值能够准确定位小至1周的所有周跳,避免漏检现象,增强周跳探测的可靠性。  相似文献   

Linking pesticides and human health: A geographic information system (GIS) and Landsat remote sensing method to estimate agricultural pesticide exposure     

《Applied geography (Sevenoaks, England)》2015

Accurate pesticide exposure estimation is integral to epidemiologic studies elucidating the role of pesticides in human health. Humans can be exposed to pesticides via residential proximity to agricultural pesticide applications (drift). We present an improved geographic information system (GIS) and remote sensing method, the Landsat method, to estimate agricultural pesticide exposure through matching pesticide applications to crops classified from temporally concurrent Landsat satellite remote sensing images in California. The image classification method utilizes Normalized Difference Vegetation Index (NDVI) values in a combined maximum likelihood classification and per-field (using segments) approach. Pesticide exposure is estimated according to pesticide-treated crop fields intersecting 500 m buffers around geocoded locations (e.g., residences) in a GIS. Study results demonstrate that the Landsat method can improve GIS-based pesticide exposure estimation by matching more pesticide applications to crops (especially temporary crops) classified using temporally concurrent Landsat images compared to the standard method that relies on infrequently updated land use survey (LUS) crop data. The Landsat method can be used in epidemiologic studies to reconstruct past individual-level exposure to specific pesticides according to where individuals are located.  相似文献   

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS          下载免费PDF全文

Richard M. Gaschnig  Roberta L. Rudnick  William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.  相似文献   

A Review of the IAG GeoPT™ and Certification Programmes,their Protocols,and the Differences between the Original and Potential Modifications to the Certification Protocol          下载免费PDF全文

Jean S. Kane 《Geostandards and Geoanalytical Research》2015,39(4):419-432

The IAG conducts two programmes, the GeoPT ^? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ^? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.  相似文献   

The Reliability of Assigned Values from the GeoPT Proficiency Testing Programme from an Evaluation of Data for Six Test Materials that have been Characterised as Certified Reference Materials          下载免费PDF全文

Philip J. Potts  Michael Thompson  Peter C. Webb 《Geostandards and Geoanalytical Research》2015,39(4):407-417

Assigned values derived from the GeoPT proficiency testing programme were compared with certified values for six certified reference materials that have been used as test materials in the GeoPT programme. Statistical analysis showed that there were few significant differences between these sets of data and that these differences had no significant impact on the GeoPT assessment when fitness‐for‐purpose criteria were taken into account.  相似文献   

Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer          下载免费PDF全文

Maurizio Gemelli  Massimo D'Orazio  Luigi Folco 《Geostandards and Geoanalytical Research》2015,39(1):55-69

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.  相似文献   

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS          下载免费PDF全文

Zaicong Wang  Harry Becker  Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.  相似文献   

Seasonal inundation patterns in two large savanna floodplains of South America: the Llanos de Moxos (Bolivia) and the Llanos del Orinoco (Venezuela and Colombia)     

Stephen K. Hamilton  Suzanne J. Sippel  John M. Melack 《水文研究》2004,18(11):2103-2116

Inundation patterns in two of the largest savanna floodplains of South America were studied by analysis of the 37‐GHz polarization difference observed by the Scanning Multichannel Microwave Radiometer (Nimbus‐7 satellite). Flooded area was estimated at monthly intervals for January 1979 through to August 1987 using mixing models that account for the major landscape units with distinctive microwave emission characteristics. Results are presented separately for five subregions in each of the two floodplain regions to show the spatial as well as temporal variability in inundation patterns. The total area inundated during the 9 years varied between 2069 and 78 460 km² in the Llanos de Moxos (also spelled as Mojos; median area, 23 383 km²) and 1278 and 105 454 km² in the Llanos del Orinoco (median, 25 374 km²), not including the open‐water area of permanent lakes and river channels. The correlation between flooded area and river stage was used to extend the inundation records over a 30‐year period in the Moxos (1967–97) and a 58‐year period (1927–85) in the Orinoco. Interannual variability in inundation is greater in the Moxos than the Orinoco. Comparison of these data, however, with a previously published analysis of the Pantanal wetland shows that inundation patterns in these two floodplain regions are not as variable across years as they are in the Pantanal. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Low correlation between redshift and intrinsic brightness for quasars and galaxies in a de sitter universe     

John B. Miller  Thomas E. Miller 《Astrophysics and Space Science》1995,227(1-2):53-60

Since the discovery of quasars, it has been recognized that these objects must have either an extraordinary intrinsic brightness or a nonlinear redshift. The most widely accepted current belief incorporates a linear (Hubble) redshift- distance relation and time evolution within a Big Bang model. We reconsider the possibility of a nonlinear (de Sitter) redshift-distance relation and find quasar intrinsic brightness to be not at all extraordinary. Given a de Sitter law, intrinsic brightness is found to be independent of redshift over five orders of magnitude.  相似文献   

湿浸硫酸镍工艺中的二次浸取     

李天才 《青海国土经略》1997,(1)

湿法浸取硫酸镍工艺研究中,净化提纯工艺采取了蒸发浓缩浸液、分步沉淀杂质的技术方案。中试表明,采用此种工艺生产效率很低,还导致生产流水线上的设备匹配性差。为此,作者提出了二次浸取的技术方案。实验室及中试试验表明:采用二次浸取工艺替代蒸发浓缩工艺,行之有效。  相似文献