红土镍矿样品前处理方法和分析测定技术研究进展     

燕娜  赵小龙  赵生国  郑红文 《岩矿测试》2015,34(1):1-11

随着常规镍来源的硫化镍矿资源的日益枯竭,可直接生产氧化镍、镍锍和镍铁等产品的红土镍矿倍受关注。对于红土镍矿中主量、次量、痕量元素的检测,相同的检测项目存在多种测试方法,且部分相同原理的测试方法存在细节上的差异,使得检测者选择合适的检测方法变得困难。本文综述了近年来红土镍矿中24种元素测定的样品前处理方式及分析技术研究进展。样品前处理方式依据目标元素及后续的分析方法进行选择,其中酸溶法和碱熔法用途最广。酸溶法引入的盐分少,操作简单,但是分解过程中易导致挥发元素As、Sb、Bi、Hg的损失,Cr易随高氯酸冒烟损失。碱熔法分解能力强,适合分析Cr、Si、全铁等项目,但会引入大量的盐类和因坩埚材料损耗而带入其他杂质,给后续分析带来困难。红土镍矿的分析技术依据实验室条件及目标元素的性质和浓度进行选择。电感耦合等离子体发射光谱法(ICP-AES)是主量、次量元素的主要分析方法,适合于分析含量为10-5~30%级别的金属元素;X射线荧光光谱法主要用于分析含量为10-3~1级别的元素,尤其适合于测定Al、Si、Ti、V和P,由于该方法的准确性依赖于一套高质量的标准样品,故更适合炉前检测或检测大批红土镍矿样品。电感耦合等离子体质谱法(ICP-MS)最适合于分析10-4含量以下的重元素,特别是稀土和贵金属元素。原子吸收光谱法(AAS)适合于分析10-4~10-2级别的Ca、Mg、Ni、Co、Zn、Cr、Mn等低沸点、易原子化元素。分光光度法主要用于分析Ni和P。原子荧光光谱法(AFS)主要用于分析As、Bi、Sb等易形成气态氢化物的元素。容量法主要用于分析Al、Fe、Mg和Si O2等主含量元素。尽管AAS、分光光度法、AFS法和容量法检测周期长,但所用仪器为实验室常规配置,可满足缺乏相应大型仪器实验室的日常检测。本文认为,针对各种检测方法的适用性及存在问题,应从开发微波消解法、固体进样直接测汞法、ICP-MS法以及Cr与其他元素同时分析的快速分析方法等方面开展研究,建立灵敏、准确的检测方法,从而更好地服务于红土镍矿的贸易、检验和综合利用。  相似文献   

鄂尔多斯盆地大牛地地区致密砂岩石英溶解作用及其对优质储集层的影响     

邱隆伟  徐宁宁  周涌沂  高青松  张向津  宋璠  马晓芸 《矿物岩石地球化学通报》2015,34(1)

储集层孔隙成因机制是致密砂岩储集层评价和预测必须解决的基本问题。本文以储集层微观分析为基础,对鄂尔多斯盆地大牛地气田石炭-二叠系致密砂岩储集层孔隙成因类型及其和优质储集层成因的关系进行了研究。结果表明,研究区致密砂岩储集层中碎屑石英颗粒存在明显的直接溶解现象,并形成了以石英溶解为主的储集空间类型,这种石英溶解是碱性成岩环境作用的结果,致密砂岩储集层的发育程度仍然和孔隙度以及组分的溶解作用有密切关系,碱不稳定矿物的溶蚀量一般为1%~23%,石英溶解型孔隙对储集层孔隙的贡献率一般可以达到60%~90%,碱溶蚀量达到5%以上时有利于优质储集层的形成;石英溶解作用较强的位置主要是颗粒边部的粒间孔隙周围,这种类型的溶解形成于储集层经历较强的压实成岩改造之后,所形成的溶解孔隙在后期的持续性压实过程中损失程度较低;石英溶解作用的强弱决定了储集层物性的最终发育程度以及优质储集层的形成。  相似文献   

贵州施秉白云岩溶蚀特性及孔隙特征实验研究   总被引：3，自引：0，他引：3  

刘琦  顾展飞  卢耀如  刘之葵 《地球学报》2015,36(4):413-418

以贵州施秉白云岩为研究对象,从宏观和微观角度分析白云岩的溶蚀特性及孔隙特征,结果显示:(1)在众多影响施秉喀斯特发育的因素中,矿物成分是最基本的内因,水是最关键的外因,孔隙结构起辅助作用。(2)极细晶白云岩的单位表面积溶蚀量一般大于细晶白云岩的,在晶粒相同的情况下,白云岩的溶蚀量与Ca O和Mg O的含量分别成正比,且Mg O的含量影响较Ca O大。(3)施秉白云岩溶蚀速率不仅受岩石矿物颗粒粒径大小的控制,还受岩石内部孔隙结构特征的影响,颗粒粒径越大,孔隙度越高,连通性越好,越有利于水溶液进入,溶蚀量也就越大。(4)施秉白云岩的溶蚀特性是多种因素综合作用的结果,必须把各个因素分离开来,从宏观和微观角度逐个作详细的分析研究,然后综合起来,才能对喀斯特发育规律有更深入的了解。  相似文献   

Diagenetic evolution of Aptian evaporites in the Namibe Basin (south‐west Angola)          下载免费PDF全文

Laurent Gindre‐Chanu  John K. Warren  Cai Puigdefabregas  Ian R. Sharp  David C. P. Peacock  Roger Swart  Ragnar Poulsen  Hercinda Ferreira  Lourenco Henrique 《Sedimentology》2015,62(1):204-233

The widespread and dissected nature of the Angolan gypsiferous salt residuals offers a uniquely detailed view of the lateral and vertical relations inherent to secondary evaporite textures, which typify exhumed salt masses worldwide. Such secondary textures are sometimes misinterpreted as primary evaporite textures. Thin, metre‐scale and patchy, dome‐like gypsum accumulations are well‐exposed within strongly incised present‐day river valleys along the eastern margin of the Namibe and Benguela basins (south‐west Angola). These sections are time equivalent to the main basinward subsurface evaporites (Aptian Loeme Formation) which mostly consist of halite. The gypsum (here called the Bambata Formation) is interpreted to represent the final residual product of fractional dissolution and recrystallization of the halite mass that occurred during Late Cretaceous margin uplift and continues today. This halite underwent multiple episodes of diagenetic alteration between its deposition and its final exhumation, leading to the formation of various secondary gypsum fabrics and solution‐related karst and breccia textures that typify the current evaporite outcrop. Four different diagenetic gypsum fabrics are defined: thinly bedded alabastrine, nodular alabastrine, displacive selenite rosettes and fibrous satin‐spar gypsum. Current arid conditions are responsible for a thin weathered crust developed at the top of the outcropping gypsum, but the fabrics in the main core of the current at‐surface evaporite unit mostly formed during the telogenetic stage of uplift prior to complete subaerial exposure. Alteration occurred as various dissolving and rehydrating saline minerals encountered shallow aquifers in the active phreatic and vadose zones. Geomorphological and petrographic analyses, mostly based on the cross‐cutting relations and crystallographic patterns in the outcrop, are used to propose a sequence of formation of these different fabrics.  相似文献   

A Discussion of Concavo-Convex Contacts between Oolites and Quartz Grains in Mixed Siliciclastic-Carbonate Rocks in Huanghua Basin, China     

Ma Yanping  Liu Li 《世界地质(英文版)》2002,5(2)

Concavo-convex contacrs between oolites and quartz grains are observed in mixed siliciclastic-carbonate rocks of the lower part of number 1 of Shahejie Formation, beach area, Dagang. Thin sections observation shows that oolite is convex in quartz grain, and oolite is complete. A possible explanation for it is pressure dissolution under alkaline fluid.  相似文献   

Dissolution kinetics,transit times through subglacial hydrological pathways and diurnal variations of solute content of meltwaters draining from an alpine glacier     

David N. Collins 《水文研究》1995,9(8):897-910

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辽河曙光油田蒸气吞吐开采过程中水岩作用的研究   总被引：1，自引：0，他引：1  

钱会  李云峰 《地球科学与环境学报》2001,23(1):33-37

稠油蒸气吞吐开采过程中，注入储层的高温水蒸气与储层岩石发生了强烈的水岩作用，使注入水的化学成分产生了显著的变化，根据这种变化，结合水岩作用室内模拟实验的研究成果，在确定水岩作用方式的基础上，使用元素质量守衡计算方法对辽河曙光油田的水岩作用量进行了计算，结果表明，注入水在储层运动过程中，溶解了大量的石英和高岭石，同时沉淀出大量的钠蒙脱石，该结果很好地吻合了室内实验成果。  相似文献   

Hydrothermal mixing,carbonate dissolution and sulfide precipitation in Mississippi Valley-type deposits   总被引：1，自引：0，他引：1  

Mercè?CorbellaEmail author  Carlos?Ayora  Esteve?Cardellach 《Mineralium Deposita》2004,39(3):344-357

A large number of Mississippi Valley-Type (MVT) deposits are located within dissolution zones in carbonate host rocks. Some genetic models propose the existence of cavities generated by an earlier event such as a shallow karstification, that were subsequently filled with hydrothermal minerals. Alternative models propose carbonate dissolution caused by the simultaneous precipitation of sulfides. These models fail to explain either the deep geological setting of the cavities, or the observational features which suggest that the dissolution of carbonates and the precipitation of minerals filling the cavities are not strictly coeval. We present a genetic model inspired by the textural characteristics of MVT deposits that accounts for both the dissolution of carbonate and precipitation of sulfides and later carbonates in variable volumes. The model is based on the mixing of two hydrothermal fluids with a different chemistry. Depending on the proportion of the end members, the mixture dissolves and precipitates carbonates even though the two mixing solutions are both independently saturated in carbonates. We perform reactive transport simulations of mixing of a regional groundwater and brine ascending through a fracture, both saturated in calcite, but with different overall chemistries (Ca and carbonate concentrations, pH, etc). As a result of the intrinsic effects of chemical mixing, a carbonate dissolution zone, which is enhanced by acid brines, appears above the fracture, and another zone of calcite precipitation builds up between the cavity and the surrounding rock. Sulfide forms near the fracture and occupies a volume smaller than the cavity. A decline of the fluid flux in the fracture would cause the precipitation of calcite within the previously formed cavities. Therefore, dissolution of carbonate host rock, sulfide precipitation within the forming cavity, and later filling by carbonates may be part of the same overall process of mixing of fluids in the carbonate host rock.Editorial handling: C. Everett  相似文献   

低温条件下长石溶解模拟实验研究   总被引：3，自引：0，他引：3  

张永旺  曾溅辉  郭建宇 《地质论评》2009,55(1):134-142

为了研究有机酸和无机酸对长石的溶解能力以及不同有机酸对长石溶解能力的差异,笔者等在80℃条件下,在不同pH值（4、6和8）的分别含有盐酸、乙酸和草酸的溶液中,对碱性长石和斜长石进行了溶解模拟实验研究。实验结果表明：酸性(pH=4)和弱酸性(pH=6)条件下,乙酸对两种长石的溶解能力大于草酸,碱性条件(pH=8)下草酸的溶解能力最大,无论在酸性或碱性条件下,有机酸对长石的溶解能力均高于无机酸,酸性(pH=4)条件下,斜长石与碱性长石溶解量差别不大,在弱酸性(pH=6)和碱性(pH=8) 条件下,斜长石的溶解量高于碱性长石。  相似文献   

不同温度、羧酸溶液中长石溶解模拟实验   总被引：24，自引：2，他引：22  

向廷生  蔡春芳  付华娥 《沉积学报》2004,22(4):597-602

报道了在100℃、140℃下微斜长石在不同羧酸溶液中的溶解实验数据。通过实验表明1)反应温度增高,可增强溶液中阳离子的活性和迁移性,加快长石溶解的反应速率,促进长石的溶解。2)在强酸性条件下,pH值的变化可影响长石的溶解。但在中等酸性条件下,pH值对长石的溶解影响很小。3)羧酸(乙二酸)可不同程度地促进长石溶解,可通过形成乙二酸络合物的形式,增加离子在溶液中的溶解度。但乙酸络合物的作用不明显。长石溶蚀导致岩石孔隙度变大,并且改善孔喉性质。同时,由于乙二酸络合物的存在,增加了Si在溶液中的溶解度,阻止了石英加大和其它成因SiO₂的生成,有利于次生孔隙和原生孔隙的保存。4)长石溶解使溶液中Al的浓度较高,但由于铝-羧酸络合物的亲油性比亲水性强,故有一部分Al被分配到油相中,这也是目前大多数油田水中Al浓度偏低的主要原因。  相似文献