An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides (LDHs) are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China. 相似文献
We studied the temporal behavior of the background shallow seismicity rate in 700 circular areas across inland Japan. To search for and test the significance of the possible rate changes in background seismicity, we developed an efficient computational method that applies the space–time ETAS model proposed by Ogata in 1998 to the areas. Also, we conducted Monte Carlo tests using a simulated catalog to validate the model we applied. Our first finding was that the activation anomalies were found so frequently that the constant background seismicity hypothesis may not be appropriate and/or the triggered event model with constraints on the parameters may not adequately describe the observed seismicity. However, quiescence occasionally occurs merely by chance. Another outcome of our study was that we could automatically find several anomalous background seismicity rate changes associated with the occurrence of large earthquakes. Very significant seismic activation was found before the M6.1 Mt. Iwate earthquake of 1998. Also, possible seismic quiescence was found in an area 150 km southwest of the focal region of the M7.3 Western Tottori earthquake of 2000. The seismicity rate in the area recovered after the mainshock. 相似文献
Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition. 相似文献
The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.
Abundant H2O–CO2, H2O- or CO2-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H2O- and/or CO2-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation. 相似文献
In ground improvement projects with prefabricated vertical drains, the duration of the preloading period is set in advance
based on the predetermined time rate of consolidation of the compressible layer. If prediction is accurately done, the required
degree of consolidation is met at the pre-determined preloading time. As such, there is a requirement for in-situ tests to be carried out just prior to the removal of surcharge to assess the degree of consolidation of the improved ground.
In-situ tests were carried out after 23 months of surcharge loading at the In-Situ Test Site within the Changi East Reclamation Project in the Republic of Singapore. In-situ testing works in this research study comprises the use of field vane shear, piezocone, flat dilatometer and self-boring pressuremeter.
The in-situ tests were carried out to determine the shear strength and degree of consolidation of the Singapore marine clay at Changi
after 23 months of surcharge loading. The In-Situ Test Site consisted of a Vertical Drain Area as well as an untreated Control Area. Both areas were located adjacent to each
other and were surcharged simultaneously to the same level and surcharge left in place for a period of 23 months. Comparison
was made between the in-situ test results of the Vertical Drain Area and the untreated Control Area. 相似文献
The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt.
It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial
multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed
pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the
test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been
put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation
energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the
rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters
assumed constant in the basic law. 相似文献
Risk and uncertainty assessments for waste containment systems employing clay barriers often include spatial variability in
the hydraulic conductivity as part of the analysis. The two-parameter log-normal distribution is often used to describe the
spatial variability, but for compacted clays the three-parameter form can be more appropriate. A statistical hypothesis test
was developed that can be used to determine if the two- or three-parameter form of the log-normal distribution is more appropriate.
The test is based on a likelihood ratio, comparing likelihood functions for the two- and three-parameter forms at their maximums.
Likelihood functions are used assuming that a data set can be segregated into a set of distinct groups of hydraulic conductivities.
A step-by-step calculation procedure is described and the test is applied to data collected from 45 sites. 相似文献