Origin and occurrence of 25-norhopanes: a statistical study   总被引：1，自引：0，他引：1  

Ph. Blanc  J. Connan 《Organic Geochemistry》1992,18(6)

The alkane fraction of more than 200 rocks, biodegraded oils and non-biodegraded oils, have been analysed by means of computerized GC-MS, in order to investigate the effect of natural biodegradation on the occurrence of “demethylated hopanes”, i.e. 17α-25-norhopanes. The results obtained indicate that 25-norhopanes are preexisting biomarkers the concentration of which is enhanced by selective biodegradation of more readily degradable homologs, i.e. regular hopanes, rather than by demethylation of hopanes in reservoirs. However, the use of 25-norhopane enrichment as a palaebiodegradation indicator in apparently non-biodegraded oils is still valuable providing the initial background content in the corresponding source rocks is known. Furthermore, 25-norhopanes appear to be diagnostic of specific environmental conditions (marine and lacustrine source rocks, dysoxic and not very hypersaline). Lastly, one other (novel) bacterially resistant rearranged hopanoic compound, namely a C₂₉ neohopane, is applicable for both biodegradation and maturation evaluation.  相似文献   

Isoprenoid alkanes with irregular “head-to-head” linkages     

Al.A. Petrov  N.S. Vorobyova  Z.K. Zemskova 《Organic Geochemistry》1990,16(4-6)

A lightly biodegraded crude oil from the Tolkinsk field (Upper Jurassic), situated in north-west Siberia, was found to contain a series of C₂₈–C₃₉ isoprenoid alkanes. Most of these components contain a pristane unit linked head-to-head with other isoprenoid units. The structures of these components were elucidated by mass spectral interpretations, comparisons with a synthesised standard and by reference to data published previously in the literature. These results extend the carbon number range, the variety of structural types, and the number of reported occurrences of these compounds in geological samples. These results provide further evidence for a contribution of bacterial cell-wall lipids to crude oils.  相似文献   

夏玉米生长过程曲线重建研究——以鹤壁市为例     

李颖  李耀辉  王金鑫 《气象与环境科学》2016,39(4):7-13

增强型植被指数(EVI)时间序列数据(即植被生长曲线)是整个生育期内植被各种生物学特征的综合反映。由于太阳位置、大气、地表和传感器位置与性能等的影响,根据遥感数据计算的EVI值往往比实际值偏低(存在大量噪声),并不能反映植被生长的真实情况,应用前需进行去噪重建工作。针对目前生长曲线重建研究大多是针对MODIS等国外遥感数据的情况,在综合分析重建方法的基础上,利用风云3号卫星的MERSI中分辨率遥感卫星数据构建鹤壁市夏玉米的EVI生长过程曲线。首先,用最大值合成法(MVC)对原始EVI时间序列数据进行初步的去云处理。接着,利用基于时间域的Savitzky-Golay滤波(简称SG滤波)对该EVI序列进行进一步的平滑去噪处理,结果发现,在噪声点EVI数值提高了,但同时在其他不是噪声点的地方EVI的值降低了。针对这种不合理的情况,利用基于SG迭代滤波取上包络线的改进方法进行处理,很好地克服了上述缺陷,在非噪声点EVI数值适当提高,且曲线平滑,达到了生长曲线重建的目的。然后,采用基于频率域的小波变换方法进行实验对比,结果发现,小波变换存在着与经典SG滤波类似的缺陷,而且在曲线末端存在突变情况。经过比较分析发现,针对研究区的实际情况,改进SG迭代滤波是较优的去噪方法。  相似文献   

改进两步移动搜索法的焦作公共交通可达性     

王磊  程钢  原东方  曾宪锴 《测绘科学》2016,41(12):151-156

针对大部分城市公交发展滞后、公交站点和公交线路供需不平衡等问题,该文采用统计数据与实调数据相结合的方式,利用两步移动搜索法,从供需的角度研究分析城区公交站点服务的空间可达性。以河南省焦作市为例,以城区街道办为基本研究单元,分别采用固定阈值的简单两步移动搜索法和基于实测数据拟合的增强两步移动搜索法,对焦作市公交设施可达性的空间布局和差异性进行研究。实验结果表明:焦作市城区公交站点服务可达性整体上比较差;城区公共交通资源发展不平衡,空间差异比较明显,公交站点供需相对平衡区域主要集中在城区中心城区,低值区主要集中在城区边缘;增强两步移动搜索法考虑了距离衰减对人们公交出行的影响,更能反映焦作市真实的公交状况。  相似文献   

Contaminant transport and biodegradation in saturated porous media: model development and simulation     

Song‐Bae Kim 《水文研究》2005,19(20):4069-4079

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基于知识图谱的增强型混合式学习的教学实践与思考     

史宇坤  许姝艺  董少春 《高校地质学报》2022,28(3):387-393

随着互联网与信息技术的快速发展,线上线下混合式学习逐渐得到普及与应用。混合式学习强调学生的主体作用,注重学生的自主学习、协作学习和个性化学习,是良好的适合高等教育的创造性学习模式。但是在目前的混合式学习模式下,学生对知识的加工、梳理、整合能力不够,构建完整知识体系的自主学习能力稍显薄弱,因此亟需更多引导。文章综合分析了混合式学习模式的优缺点,建议引入人工智能领域的知识图谱概念,作为新的教学元素以引导和加强学生的自主学习过程,由此构建了基于知识图谱的增强型混合式学习模式。该模式在2020年南京大学《古无脊椎动物学》课程中进行了实践,进一步证明其在改善学生自主学习能力方面的潜力。  相似文献   

华北平原夜间对流性天气对地面O₃混合比的抬升效应          下载免费PDF全文

贾诗卉  徐晓斌  林伟立  王瑛  何心河  张华龙 《应用气象学报》2015,26(3):280-290

2013年6—9月在河北省固城站观测到多次夜间对流性天气伴随地面O₃混合比快速抬升的过程,并引起次日清晨到中午O₃混合比升高。大多数对流过程中,O₃混合比在半小时内升高至60×10-9～80×10-9,同时NO_x等反应性气体混合比下降,θ_se值降低,说明下沉气流将高空气团带到地面,造成了O₃混合比的升高。通过再分析资料得到下沉气团基本来源于对流层中下层,这一结论与当地进行的一次飞机观测结果吻合。多数对流过程中固城站和北京城区地面O₃混合比和θ_se值有相同的变化趋势和程度。根据观测结果,推测华北地区在夏季和初秋时,对流层中下层存在O₃高值区,混合比约为60×10-9～80×10-9。对流性天气对地面O₃抬升的影响区域与对流系统的影响范围有关,可达到中尺度范围。华北地区光化学污染严重,对流性天气引起的地面O₃混合比抬升程度比较强,对环境的影响值得关注。  相似文献   

基于MODIS资料的宁夏LST反演方法新探索   总被引：1，自引：0，他引：1  

张学艺  张晓煜  卫建国  李剑萍  韩颖娟 《气象》2009,35(5):61-65

为快速、宏观、全面地获取陆面生态重要参数陆面温度(LST),避免分裂窗算法中诸多参数的估计和参数的适用范围限制,加快计算速度,更好地利用中国气象局"三站四网"的建设成果,利用宁夏2005-2007年13个时次过境晴空地表MODIS资料及对应过境时17个自动气象站观测数据,筛选、优化引入对LST影响较大的水汽通道、NDVI和EVI参数,建立基于MODIS遥感和地面自动气象站观测数据反演陆面温度(LST)的统计模式.研究结果表明:引入相关参数后,宁夏各季及全年模式的相关性和精度有较大提高,且水汽通道和EVI的参数组合最优.与分裂窗算法相比,省去了对大气透过率的估算以及对地表比辐射率估计的繁琐计算,与地面自动站观测真实值误差70.1%能够控制在4.0℃以内,计算速度快,能够满足一般业务的需求,易于推广使用.  相似文献   

以醋酸为共代谢基质时四氯乙烯的生物降解初步研究     

李烨  刘菲  史敬华  刘石 《水文地质工程地质》2006,33(3):7-10,96

四氯乙烯（PCE）是一种广泛用于干洗和脱脂的有机溶剂,是地下水中常见的污染物.在本实验中,将某肉联厂厌氧污泥接种到土壤中,进行微生物培养.当系统中的微生物活性较高时,以醋酸为共代谢基质,进行驯化实验,当系统中的微生物适应浓度为120μg/L的PCE之后,对PCE在厌氧条件下的降解情况进行研究.研究结果表明,将厌氧污泥接种到土壤中培养的微生物,在以醋酸为共代谢基质的条件下,可以使PCE很快转化为三氯乙烯（TCE）,并可以进一步转化为二氯乙烯（DCEs）.PCE在天然地下水中的半衰期为108d,本实验PCE降解的半衰期为2.95d,反应速率常数为0.2342d^-1.  相似文献   

Acclimatization and screening of a chloramphenicol-degrading strain     

Xuanwen LU Xueqin TAO Zhi DANG 《中国地球化学学报》2006,25(B08):115-116

Chloramphenicol （CAP） is an antibiotic commonly used in aquaculture as a prophylactic or disinfectant to prevent diseases, or as a chemotherapeutic agent to control diseases. This antibiotic is either spread directly in the aquatic environment or administered through medicated feeds. It may be directly exposed to or enter the environment by leaching from uneaten feeds or from the aquatic animals＇ excrements. The antibiotic also directly enters the environment through pharmaceutical wastewater. Toxicity of CAP to human bone marrow has been linked to fatal aplastic anemia. Antimicrobial residues enter the environment, which may also establish a selective pressure in favour of antimicrobial-resistant bacteria. The residues of antibiotics may pose potential risk to public health or increase the occurrence of antibiotic-resistant bacteria in the aquatic environment. Due to these perceived risk, treatment of CAP in farm animals intended for human consumption has been restricted. However, residue of CAP in the environment is still a concern. There have been some reports on the residual effects of CAP on aquaculture and on microbial resistance to CAP in certain environments. The biotransformation of CAP in aquaculture pond sediments has been reported, which indicated that salinity is one of the many environmental factors that affect the degradation of CAP. However, acclimatization and screening of dominant bacteria for biodegrading CAP have been rarely studied. This paper studied the microbial degradation of CAP. In order to screen the dominant bacteria for degrading, the source of bacteria was sampled from the aquaculture pond sediments of Baiyun Borough, Guangzhou, China. 60 mg/L CAP was used as a sole carbon source to screen CAP-degrading bacteria and the dominant bacteria were acclimated after 2 months.  相似文献