The Meatiq dome (Eastern Desert, Egypt) a Precambrian metamorphic core complex: petrological and geological evidence   总被引：2，自引：0，他引：2  

P. NEUMAYR  G. HOINKES  J. PUHL  A. MOGESSIE  & A. A. KHUDEIR 《Journal of Metamorphic Geology》1998,16(2):259-279

The Meatiq basement, which is exposed beneath late Proterozoic nappes of supracrustal rocks in the Central Eastern Desert of Egypt, was affected by three metamorphic events. The ophiolite cover nappes show only the last metamorphic overprint. The M1 metamorphic event (T ≥750 °C) is restricted to migmatized amphibolite xenoliths within the Um Ba′anib orthogneiss in the structurally lowest parts of the basement. Typical upper amphibolite facies M2 mineral assemblages include Grt–Zn-rich Spl–Qtz±Bt, Grt–Zn-rich Spl–Ms–Kfs–Bt–Sil–Qtz and locally kyanite in metasedimentary rocks. The mineral assemblages Ms–Qtz–Kfs–Sil in the matrix and Sil–Grt in garnet cores indicate that peak M2 P–T conditions exceeded muscovite and staurolite stabilities. Diffusional equilibration at M2 peak temperature conditions caused homogeneous chemical profiles across M2 garnets. Abundant staurolite in garnet rims and the matrix indicates a thorough equilibration during M2 at decreasing temperature conditions. M2 P–T conditions ranged from 610 to 690 °C at 6–8 kbar for the metamorphic peak and 530–600 °C at about 5.8 kbar for the retrograde stage. However, relic kyanite indicates pressures above 8 kbar, preceeding the temperature peak. A clockwise P–T path is indicated by abundant M2 sillimanite after relic kyanite and by andalusite after sillimanite. M2 fluid inclusions, trapped in quartz within garnet and in the quartz matrix show an array of isochores. Steepest isochores (water-rich H₂O-CO₂±CH₄/N₂ inclusions) pass through peak M2 P–T conditions and flatter isochores (CO₂-rich H₂O-CO₂±CH₄/N₂ inclusions) are interpreted to represent retrograde fluids which is consistent with a clockwise P–T path for M2. The M3 assemblage Grt–Chl in the uppermost metasedimentary sequence of the basement limits temperature to 460 to 550 °C. M3 temperature conditions within the ophiolite cover nappes are limited by the assemblage Atg–Trem–Tlc to<540 °C and the absence of crysotile to >350 °C. The polymetamorphic evolution in the basement contrasts with the monometamorphic ophiolite nappes. The M1 metamorphic event in the basement occurred prior to the intrusion of the Um Ba′anib granitoid at about 780 Ma. The prograde phase of the M2 metamorphic event took place during the collision of an island arc with a continent. The break-off of the subducting slab increased the temperature and resulted in the peak M2 mineral assemblages. During the rise of the basement domain retrograde M2 mineral assemblages were formed. The final M3 metamorphic event is associated with the updoming of the basement domain at about 580 Ma along low-angle normal faults.  相似文献   

流体包裹体成分分析研究   总被引：27，自引：4，他引：23  

王莉娟 《地质论评》1998,44(5):496-501

笔者在日本研修期间学习和了解了先进的流体包裹体成分分的方法,其中包括分析群体包裹体液相成分的ＩＣＰ－ＭＳ和ＰＩＸＥ分析方法;分析单个包裹体液相成分的ＬＡ－ＩＣＰ－ＭＳ方法,ＬＲＭ,ＦＴ－ＩＲ单个包裹体气相成分分析方法等。这些方法极大地提高了包裹体成分分析的水平,促进了包裹体研究的发展,本文简要介绍这几种流体包裹体成分分析方法和其它包裹体研究方法及笔者的一些研究成果,以供国内同行借鉴和共同探讨。  相似文献   

Analytical perspective on trace element species of interest in exploration   总被引：1，自引：0，他引：1  

Gwendy E. M. Hall 《Journal of Geochemical Exploration》1998,61(1-3)

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   

微细浸染型金矿床的稳定同位素特征与成因探讨   总被引：22，自引：1，他引：21  

刘建明  刘家军 《地球化学》1998,27(6):585-591

对我国众多沉积岩系中的微细当染型金矿床开展了较为系统的稳定同位素地球化学研究,非常分散复杂的氢氧同位素组成被认为是沉积盆地流体的一个典型特征,这是因为盆地流体中水的两个主要来源－海水和大气降水,经不同程度的水－岩反应同位素交换后又以不同比例相互混合,再加上有机物和粘土矿物的相变水在不同阶段以不同比例加入。  相似文献   

东川汤丹铜矿床石英真空击碎及其粉末阶段加热^40Ar—^39Ar年龄谱的含义   总被引：17，自引：5，他引：12  

邱华宁  孙大中 《地球化学》1998,27(4):335-343

采用真空击碎技术提取东川汤丹铜矿床石英流体包裹体进行40Ar-39Ar法年龄测定,获得了逐渐下降的阶梯形年龄谱,表明流体包裹体含有过剩氩;数据点在40Ar／36Ar-39Ar／36Ar图解上构成等时线,等时线年龄为（712±33）Ma,代表了矿床的形成年龄。随后对其粉末进行40Ar-39Ar阶段加热（100—800℃）分析,形成相对比较平坦的年龄谱,坪年龄为（317±6）Ma（39Ar占45％,含真空击碎分析在内）,粉末加热分析全部数据点构成的等时线年龄为（321±13）Ma。电子探针分析和显微镜观察证实了该石英样品中含有粒径大于100μm,K2O含量为8％-10％,形成时间明显晚于石英的白云母类富钾矿物,粉末阶段加热分析结果表明～320Ma应为后期白云母类矿物的年龄。  相似文献   

中国东部新生代碱性玄武岩中的流体组成及其碳,氧同位素地球化学特征   总被引：16，自引：2，他引：14  

张铭杰  王先彬 《地球化学》1998,27(5):452-457

利用热分解质谱法测定了中国东部新生代碱性玄武岩中流体挥发分的组成,并对不同温度段释放出的ＣＯ２气体测定了Ｃ,Ｏ同位素值,流体组成和ＣＯ２的Ｃ,Ｏ同位素值表明中国东部上地幔源区的不均一性,与其中所含幔源岩捕体相比,碱性玄武岩浆发育在相对氧化的环境中,并有外来流体组分的加入。  相似文献   

南秦岭勉县─略阳结合带蛇绿岩与岛弧火山岩地球化学及其大地构造意义   总被引：31，自引：1，他引：30  

赖绍聪  张国伟  杨永成  陈家义 《地球化学》1998,(3)

南秦岭勉县-略阳结合带中超基性岩类主要为方辉橄榄岩和纯橄榄岩,稀土特征为轻稀土亏损,铕富集型;辉绿岩均为轻稀土富集型。变质火山岩可区分为两种组合：一为轻稀土亏损的洋脊拉斑玄武岩,其Ti／V．Th／Ta、Th／Yb、Ta／Yb表明其为MORB型玄武岩,代表本区消失了的洋壳岩石,指示本区晚古生代一早中生代期间的一个古洋盆。另一类为岛弧火山岩组合,除岛弧拉斑玄武岩外,甚至还有大量中、酸性岛弧火山岩,它们并非洋壳的物质组成,而是大陆弧岩浆活动的产物。这表明勉略洋盆在晚古生代-早中生代期间曾经经历过一个较完整的有限洋盆的发生、发展与消亡过程,这期间秦岭已成为一独立的岩石圈微板块,其南缘具有活动大陆边缘的构造属性,秦岭并非华北与扬子陆块之间的简单碰撞产物。  相似文献   

江西省小龙钨矿深部地球化学找矿远景预测   总被引：2，自引：0，他引：2  

张艳宜  吴泳生 《地质与勘探》1998,34(3):34-37

运用岩石地球化学找矿方法预测了小龙钨矿区深部Ｃｕ、Ａｇ、Ｗ矿化富集规律及其找矿远景。认为矿区南涪７、１１勘探线八中段以下存在Ｃｕ、Ａｇ、Ｗ矿体可能;北部０勘探线六中段Ｃｕ、Ａｇ晕已收敛,深部存在Ｃｕ、Ａｇ矿体可能性不大,而Ｗ的强度和规模在八中段以下呈显著增大趋势,深部可能存在Ｗ矿体,为矿区深部部署坑道工程提供了准确的地球化学依据。  相似文献   

氢氧化物族矿物的氧同位素分馏   总被引：2，自引：0，他引：2  

郑永飞  徐宝龙 《地球化学》1998,27(2):141-152

应用增量方法计算了氢氧化物族矿物的氧同位素分馏,得到常见氢氧化物的18O富集顺序为：褐铁矿＞三水铝石＞针铁矿＞水镁石＞硬水铝石。氢氧化物与其对应的氧化物相比显著地富集18O。三价阳离子的氢氧化物和氧化物的18O富集顺序为：M（OH）3＞MO（OH）＞M2O3。Al（OH）3同质多象变体之间也存在一定的分馏。对于石英-氢氧化物、方解石-氢氧化物和氢氧化物-水体系,本文计算提供了在0-1200℃温度范围内三组内部一致的分馏系数方程。这些理论校准与合成实验结果和／或地表温度下的天然样品相吻合,特别针铁矿、勃姆石和硬水铝石与水之间的氧同位素分馏关系能够满足地质测温的要求。因此,对氢氧化物-水体系的氧同位素分析可望提供表生环境下可靠的地质温度计。  相似文献   

贵州天柱磨山—油麻坳金矿化带岩石矿物地球化学研究   总被引：3，自引：0，他引：3  

张杰  余大龙  张先煜  杨勇俊 《地质与勘探》1998,(2)

研究了贵州天柱磨山—油麻坳金矿化带的成矿条件、控矿规律及地球化学特征。认为：金元素来源于地层;成矿流体具变质水和大气降水混合特征;褶皱翼部与断裂交汇带及层间破碎带等控制着矿体产出。成矿作用过程具沉积变质改造作用特点,多期次的构造变质作用对金元素的迁移聚集有着重要控制作用。  相似文献