Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation     

Pasquale Crea  Concetta De Stefano  Demetrio Milea  Silvio Sammartano   《Marine Chemistry》2008,112(3-4):142-148

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).  相似文献   

中国城际公路零担专线网络空间结构特征     

施路  杜国鹏  庞鸿立  王晓婷  郑中阳  李国旗 《热带地理》2022,42(11):1806-1815

基于社会网络分析方法,利用国家交通运输物流公共信息平台2018年全国地级及以上城市的公路零担专线数据,从城市节点、城际联系、子网络3个层面对中国城市网络结构特征进行识别,结果表明：1）上海、天津、郑州、广州、杭州在网络中处于主导性地位,根据货流组织系数,可将城市节点划分为强中心、次强中心、弱中心、从属型4种类型。2）在首位联系总量排名前十的城市中,输出型城市和输入型城市的比例为4∶1,反映货流流向的不均衡性。由公路零担专线数据刻画的网络空间呈现显著的距离衰减规律,集中在500 km的专线数量占比为41.9%。3）公路零担专线网络形成东北―冀鲁蒙社区、中原社区、关中社区、江淮社区、泛珠三角―长三角社区、长株潭社区6个具有显著地域特征的城市社区,社区结构表现出明显的空间集聚和跨行政区特征。最后,提出以下建议：增强成渝城市群公路零担专线服务能力,发挥核心城市产业集聚和带动作用;优化边缘城市产业结构,加强交通与产业融合;积极引导无车承运人平台发挥网络规模化效应,提高公路货运组织效率。  相似文献   

地形数据对象存储组织方式及其分布策略研究   总被引：2，自引：0，他引：2  

李忠民  喻占武 《测绘学报》2008,37(4):0-520

结合基于对象存储技术,将地形数据按平面格网划分成若干个瓦片,每个瓦片映射为一个对象存储在基于对象存储系统中。根据地形瓦片之间的位置相关性,提出一种地形数据矢量基对分布策略,将多个瓦片对象分布在多个基于对象存储设备中,充分发挥基于对象存储系统的并行性。并采用分布模板的思想来实现矢量基对分布策略,减小运算的复杂度。该策略保证查询窗口在一定范围内每台基于对象存储设备最多只被访问一次,且响应时间恒定。  相似文献   

前兆地电阻率资料处理的剥皮法   总被引：2，自引：1，他引：2       下载免费PDF全文

毛先进  钱家栋 《地震学报》2001,24(6):645-650

在台址下电阻率分层均匀的前提下，针对我国绝大多数前兆地电台单极距观测的事实与现状，提出一种试图从这种观测所获得的视电阻率时间序列中识别电阻率表层变化和深部变化的等效模型方法．分析表明，在保持布极方式和观测结果不变的前提下，任意多层的地电结构都可以视为一个二层地电结构——等效模型．本文中，等效模型上层的地电参数（电阻率和厚度）与实际模型第一层相同，下层的地电参数（电阻率）则根据等效要求，由实际模型第二层及其以下各层的地电参数经计算得到，因此，等效模型的下层包含了实际模型第二层及其以下各层的综合影响．初步研究表明，这种方法是可行的．   相似文献   

地质勘查中的数字图像处理技术     

杨文久  刘心季 《遥感学报》1992,(4)

本文介绍用于地质勘查的数字图像处理技术。所处理的数据涉及遥感、地质、地球物理、地球化学和地理等学科的多源地学信息。针对地学信息的特殊性,研究和开发了各种数字图像处理方法,以增强和提取用于地质勘查的重要信息,辅助地质构造分析,并在矿产预测中取得初步效果,显示出数字图像处理技术在地质勘查中的应用潜力。  相似文献   

Spatial distribution of earthquakes in aftershock zones of the Garm region, Soviet Central Asia   总被引：1，自引：0，他引：1  

Mariana Eneva  Michael W. Hamburger  Georgi A. Popandopulo 《Geophysical Journal International》1992,109(1):38-53

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Destructive gear use in a tropical fishery: Institutional factors influencing the willingness-and capacity to change     

《Marine Policy》2016

The aim of this study was to empirically assess institutional aspects shaping fishers’ behavior leading to unsustainable resource use, by using the example of destructive drag-net fishing in Zanzibar, Tanzania. A broad institutional approach was used to specifically assess institutional factors influencing the fishers’ reasons for the current use of destructive drag-nets as well as their willingness- and economic capacity to change to less destructive gears. Different regulative, normative, cultural-cognitive and economic factors (tradition, group-belonging, social acceptance, common practice, identity of drag-net users and weak economic capacity) were identified as critical elements influencing the current use of destructive gears, as well as obstructing changes to other gears. Hence, the importance of addressing all of these factors, matching to the different contexts, rather than focusing on fast-moving regulative measures, is emphasized to increase chances of management success. More promising approaches would be resource allocations to more sustainable fishing gears, well-managed gear exchange programs, as well as alterations of slow-moving normative and cultural factors, e.g. awareness raising on the advantages of more sustainable fishing gears, their traditional and cultural values, information on the actual income they generate, as well as education and an exchange of traditional knowledge on how to use them.  相似文献   

青岛地区坛张网生产情况的调查研究     

齐建军  高清廉 《海洋湖沼通报》2001,(1):56-59

本文对青岛地区坛张网生产情况进行深入广泛调查的基础上，结合国内外捕捞技术的研究新成果、新趋势，以及作者在渔船改造方面的研究，提出了青岛地区坛张网提高效率、保护资源的一些建议。  相似文献   

Structure of a pair of anticyclonic vortices in northern part of the South China Sea in autumn of 1994     

Fu Gang  Toshio Yamagata 《海洋学报(英文版)》2002,21(2):203-216

A pair of remarkable meso-scale anticyclonic vortices, one formed closely to another, inthe northern part of the South China Sea during the period from the later August to early September of 1994 were documented by the in situ observation data. Their spatial structures were examined in detail from the horizontal and two nearly perpendicular/vertical angles of view. It was shown that the horizontal scales of these two vortices were around 100, 50 km, and their vertical scales were about 500, 1000 m, respectively. Two "warm core" structures associated with these two vortices were found in their horizontal and vertical analyses. The closer spacing of these two vortices (namely, 60 km), which was smaller than the Rossby radius of deformation, suggested that they might merge with each other during their next evolution stages and form into a larger vortex eventually.  相似文献   

Potential bioeconomic impact of reduced mortality of codend escapees of the shrimp fishery in the Davis Strait     

Christensen  Steen 《ICES Journal of Marine Science》1995,52(5):843-851

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