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31.
32.
铋的原子吸收光谱分析进展 总被引：4，自引：0，他引：4
文章对１９８５年以来用原子吸收光谱法测定Ｂｉ的情况进行了综述，着重介绍了用氢化物发生法、石墨炉法和火焰法测Ｂｉ时，为了提高灵敏度所采用的各种氢化物发生装置及根据不同试样所使用的各种分离富集手段。主要参考文献１０１篇。 相似文献
33.
南黄海盆地油气资源潜力一直是中国海上油气勘探关心的问题，但仍未取得突破性进展。生烃动力学研究对烃源岩生烃潜力评价至关重要，而该区古近系烃源岩的生烃动力学的研究十分薄弱。为此，在对南黄海盆地南部凹陷烃源岩常规地球化学分析统计基础上，着重选择南二凹低成熟样品开展PY-GC，SRA 和MSSV 等实验分析及动力学模拟。结果表明：南二凹阜四段烃源岩已进入生烃阶段，其产出的石油类型为石蜡-环烷-芳香基低蜡型，活化能分布范围为43~60 kcal/mol，其活化能主峰为51 kcal/mol，占72%，指前因子A=9.66×1012，生烃窗温度为128~158℃。该套烃源岩生烃历程中所生成的烃类在渐新世末期（23~30 Ma）以气液两相共存的形式存在，其余时期均以单一液相存在于该地层，至今转化率仍处于50%~60%。研究获得的南黄海盆地南二凹古近系泥岩的生烃动力学特征对于估算该盆地油气资源潜力极为重要，可为该区下一步油气勘探开发决策提供参考依据。 相似文献
34.
A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores. 相似文献
35.
36.
塔里木盆地三叠系烃源岩有机岩石学特征与生烃评价 总被引：5，自引：1，他引：5
应用现代有机岩石学方法，配合有机地球化学方法，通过对塔里木盆地三叠系烃源岩的研究，认识了一种较特殊的烃源岩类型，其生烃母质以菌解无定形体为主，不仅其实测镜质组反射率Ｒ°具有明显抑制作用，而且其生烃早，“液态窗”范围介于镜质组Ｒ°为０．４０％－０．９５％之间。这类烃源岩生烃潜力较强（相当于ⅡＢ型干酪根），实际上已进入成熟－成烃峰期阶段，并广泛分布于塔北轮南及其以南地区，预测展布面积达１．０－１．５万 相似文献
37.
The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks 总被引：1，自引：0，他引：1
The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence
of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation
of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment
of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different
existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic
matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation
process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic
bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the
mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion
pressure during the high evolution stage.
Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”. 相似文献
38.
Evolution model and formation mechanism of bio-thermocatalytic transitional zone gas 总被引：1，自引：0，他引：1
As a new genetic type of natural gas exploration area, the bio-thermocatalytic transitional zone gas (BTTZG) has been highly
stressed by geologists both at home and abroad. Systematic study on the generation mechanism of hydrocarbon at the transitional
zone is presented. Based on simulating experiments and geochemistry analysis of the source rock with lower evolution, a hydrocarbon-forming
model at the transitional zone has been established. The mechanism is proposed that under the condition of low temperature
and pressure combining with extremely active structural stress and clay mineral catalysis, BTTZG is formed by de-group of
soluble organic matter and polarized compositions through orthocarbon ion as well as by condensation polymerization of aromatic
ring-rich insoluble organic matter. This mechanism controls the formation of BTTZG, and furthermore, BTTZG is the product
of superimposition and interaction of all the factors mentioned above. 相似文献
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