厦门海域水体中有机锡的存在形态与含量分布   总被引：1，自引：0，他引：1  

赵冬梅  王新红  马建强  洪华生 《热带海洋学报》2007,26(4):76-81

利用固相萃取-气相色谱-火焰光度检测(SPE-GC-FPD)对厦门海域表、底层海水中的有机锡化合物进行了分析检测。其中表层海水中检出的有机锡化合物以二丁基锡(DBT)为主,底层海水中以三丁基锡(TBT)为主,且TBT的浓度显著高于表层水。表层海水中总有机锡浓度在129.1—4 826.8 ng(Sn).L-1之间,底层海水则分布在321.6—1 954.5ng(Sn).L-1之间。结果显示,厦门港内及同安湾附近海域水体中的有机锡浓度远高于九龙江口及厦门西南海域,这与厦门海域船舶活动和网箱养殖密切相关。通过对鼓浪屿站点表层海水中有机锡化合物15 h的连续监测,推测光照对水体中有机锡的降解影响显著。  相似文献   

南海表层沉积物中钙质超微化石分布特征   总被引：9，自引：0，他引：9  

王勇军  陈木宏  陆钧  向荣  张兰兰  张丽丽 《热带海洋学报》2007,26(5):26-34

为系统描述钙质超微化石在南海表层沉积中的分布特征,对遍布南海的175个样品进行了实验分析。发现不同地区钙质超微化石绝对丰度相差很大,从0—3.8×1010个.g-1不等。平面上将钙质超微化石丰度分为3个区。共鉴定出钙质超微化石21属28种,以Emiliania huxleyi、Florisphaera profunda和Gephyrocapsa oceanica为优势种,其中Florisphaera profunda占据绝对优势。南海钙质超微化石分布具有两个明显特征:一是14°N线南北两边钙质超微化石的分布存在差异;二是南海钙质超微化石丰度以南沙群岛和西沙群岛两片海域为最高,并有东北-西南走向的分布趋势。对影响钙质超微化石分布的水深、上升流与营养盐、陆源物质稀释作用、碳酸盐溶解作用等因素作了讨论,并根据钙质超微化石随水深的变化推测南海碳酸盐补偿深度应在4 000m左右。  相似文献   

In situ and satellite observations of the eastward migration of the Western Alboran Sea Gyre     

M.M. Flexas  D. Gomis  S. Ruiz  A. Pascual  P. Len 《Progress in Oceanography》2006,70(2-4):486

During October 2003 an intensive oceanographic survey (BIOMEGA) was carried out in the Alboran Sea, coinciding with a migration event of the Western Alboran Sea Gyre (WAG). The observations gathered during that cruise constitute the first field evidence of a migrated stage of the WAG. In this work we present the main differences between the 3D hydrodynamic fields observed during BIOMEGA and those corresponding to a WAG located at its usual position. The migration of the gyre was followed by satellite (altimetry and sea surface temperature) imagery. The causes of the gyre migration are explored in terms of the quasi-geostrophic tendency equation, in particular of the dynamics governing scales larger than the Rossby radius of deformation. It is shown that the steady state gyre must be almost equivalent barotropic and that the key process to break down the stationarity would be a density advection at gyre scale. The mechanisms to explain the migration of the WAG proposed by previous authors are discussed in light of the explanation proposed in this work.  相似文献   

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX     

王修林  张正斌  刘莲生 《中国海洋湖沼学报》1992,(1)

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

蒸发皿中水面蒸发氢氧同位素分馏的实验研究   总被引：3，自引：0，他引：3       下载免费PDF全文

包为民  胡海英  王涛  瞿思敏 《水科学进展》2008,19(6):780-785

气象要素与蒸发密切相关,通过室内外不同气象条件下的器皿水蒸发实验,获得了水面蒸发氢氧稳定同位素分馏因子与气象要素的关系。实验结果表明,随着蒸发的进行,剩余水体中逐渐富集重同位素;自由水体蒸发同位素分馏在垂线上有分层现象,表层水体同位素值比垂线平均的同位素值略富集;不同温度条件下的室内蒸发实验中,温度越高,液-气间分馏系数越小,相应于同一剩余水体体积比,剩余水体稳定同位素值则越低。室外器皿水自由蒸发实验中得出的蒸发线方程斜率较大地偏离了当地降水线,表明实验期间水体蒸发分馏作用较明显。该研究为进一步揭示水体蒸发分馏规律提供了可靠的实验依据。  相似文献   

高灵敏度机载L波段微波辐射计探测海表盐度     

赵凯  史久新  张汉德 《遥感学报》2008,12(2):277-283

海水盐度是研究大洋环流和全球气候变化的重要参数,L波段(1400-1427MHz)微波辐射计是进行海水盐度遥感的最有效工具.在该频段内,微波辐射亮度温度对海水盐度变化的灵敏度为0.5K/psu,而用于海洋研究的盐度分辨率为0.1-0.2psu,要求微波辐射计的灵敏度优于0.1K.高灵敏度机载L波段微波辐射计,应用数字增益波动自动补偿和温度补偿技术,保证了系统的稳定性,并采用高效的滤波技术有效地抑制了全球定位信号(GPS)对接收机的干扰,灵敏度达到0.08K.进行了多次航空和海上对比遥感试验,获得了分辨率优于0.2psu、误差精度0.42psu的测量结果.  相似文献   

黄河内蒙古段上覆水、悬浮物和底泥重金属特征及生态风险研究   总被引：24，自引：12，他引：12  

赵锁志  刘丽萍  王喜宽  李世宝  朱锁  郑萍  张青  张宝  蒙奎文 《现代地质》2008,22(2):304-312

系统地采集黄河内蒙古段上覆水、悬浮物和底泥样品,分析其中重金属元素的含量。采用地质累积指数法和潜在生态危害系数法,研究了黄河干流内蒙古段的上覆水、悬浮物和底泥的重金属沿程分布特征、污染程度和生态风险。分析结果显示:除了As元素,悬浮物中重金属元素含量总体上高于底泥中的含量。地质累积指数法评价结果表明:悬浮物和底泥属于无污染—中度污染,悬浮物总体上比底泥污染严重;潜在生态危害系数法评价结果表明:底泥和悬浮物中重金属的生态危害总体上属轻微状态;因此,生态风险指数法和地质累积指数评价结果基本一致。  相似文献   

浅层SH反射波法和多道瞬态面波法 进行联合工程勘察的讨论   总被引：2，自引：1，他引：1  

仇恒永  王治华  王书增  夏学礼 《物探与化探》2008,32(4):451-454

针对目前单一工程物探方法调查浅部地质结构的局限性,提出采用弹性波法勘察中研究浅部地质结构的SH波反射勘察和多道瞬态面波法勘察这2种有效手段进行联合勘探,提高其可靠性和精度,并给出了3个实例,指出了在数据采集和处理时应注意的问题。  相似文献   

基于传统吸附烃概念的烃类检测新技术   总被引：5，自引：1，他引：4  

程同锦 《物探与化探》2008,32(5):456-460

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.  相似文献   

A sub-pixel analysis of urbanization effect on land surface temperature and its interplay with impervious surface and vegetation coverage in Indianapolis,United States     

Qihao Weng  Dengsheng Lu 《International Journal of Applied Earth Observation and Geoinformation》2008

This study developed an analytical procedure based upon a spectral unmixing model for characterizing and quantifying urban landscape changes in Indianapolis, Indiana, the United States, and for examining the environmental impact of such changes on land surface temperatures (LST). Three dates of Landsat TM/ETM+ images, acquired in 1991, 1995, and 2000, respectively, were utilized to document the historical morphological changes in impervious surface and vegetation coverage and to analyze the relationship between these changes and those occurred in LST. Three fraction endmembers, i.e., impervious surface, green vegetation, and shade, were derived with an unconstrained least-squares solution. A hybrid classification procedure, which combined maximum-likelihood and decision-tree algorithms, was developed to classify the fraction images into land use and land cover classes. Correlation analyses were conducted to investigate the changing relationships of LST with impervious surface and vegetation coverage. Results indicate that multi-temporal fraction images were effective for quantifying the dynamics of urban morphology and for deriving a reliable measurement of environmental variables such as vegetation abundance and impervious surface coverage. Urbanization created an evolved inverse relationship between impervious and vegetation coverage, and brought about new LST patterns because of LST's correlations with both impervious and vegetation coverage. Further researches should be directed to refine spectral mixture modeling by stratification, and by the use of multiple endmembers and hyperspectral imagery.  相似文献