顾及起始数据误差影响时单位权中误差的估值   总被引：1，自引：0，他引：1  

黄加纳 《武汉大学学报(信息科学版)》1986,(4)

本文推导了在附有条件的间接平差和附有未知数的条件平差两种方法中,顾及起始数据误差影响时,计算单位权中误差估值(?)的公式,并以两个实例说明,平差时应该考虑起始数据误差对(?)的影响。  相似文献   

New aromatic biomarkers and possible maturity indicators found in New Albany Shale extracts     

Mei-In M. Chou  Karl V. Wood 《Organic Geochemistry》1986,9(6)

Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C₄₀H₆₆) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C₄₀H₄₈) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation.  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

莺－琼盆地YA13－1气田热流体活动与有机／无机成岩响应   总被引：7，自引：0，他引：7       下载免费PDF全文

孙永传  陈红汉  李蕙生  陆永潮  张启明  张国华  朱河清 《地球科学》1995,(3)

根据钻井中途测试（ＤＳＴ）、重复地层测试（ＲＦＴ）、镜质体反射率（Ｒ０）、流体包裹体分析和粘土矿物Ｘ射线衍射全定量分析等综合研究发现，莺－琼盆地ＹＡ１３－１气田存在４期热流体活动；南侧的崖南地区和西侧的莺歌海盆地是其两个重要的热流体物质源和动力源；多期热流体活动在ＹＡ１３－１地区不仅造成热异常和物质迁移，而且还引起了不同的有机／无机成岩响应，如骨架颗粒的多期溶蚀作用、至少两期的次生加大作用、粘土矿物转化和有机质热成熟作用异常。第二、第三期热流体因出溶作用形成ＹＡ１３－１气田大规模的天然气聚集。  相似文献   

加卸载响应比理论在中强地震（7〉M≥6）预测中的应用   总被引：6，自引：2，他引：6  

陈学忠  尹祥础 《中国地震》1995,11(1):33-37

本文运用加卸载响应比理论对中强地震前的加卸载响应比的变化进行了研究。结果表明，中强地震前加卸载响应比明显上升，表现为三种不同的形态，持续时间为半年到两年。  相似文献   

区域震相强度比—岩石层热状态的有效指示     

高世玉  张廉强 《中国地震》1995,11(3):204-211

本文根据白家疃台６０年代以来的短周期地震记录图，分析了区域震相的强度比。研究表明：Ｓｎ／Ｌｇ波的强度比波传播路径上岩石层热结构、热状态及强地震活动等均有相关性，并就这种相关性对于强地震成因及其预测研究的直接意义进行了讨论。  相似文献   

层序界面和界线层型相结合而产生的地层划分的一个新概念：最优自然界线   总被引：21，自引：0，他引：21       下载免费PDF全文

梅仕龙 《地质学报》1995,69(3):277-284

通过对层序界面的详细剖析，指明了层序地层系统是独立存在于地方性的岩石地层系统和全球性的年代地层系统之间的区域性、过渡性地层系统，并因此提出了一个新的三重地层分类方案；通过将层序界面概念和界线层型概念有机地结合起来，提出了应该将全球层型剖面和点选在层序界面的整合部位从而建立最佳自然界线的观点，为建阶工作指出了工程层位和地区；以二叠纪Ｇｕａｄａｌｕｐｉａｎ统和乐平统的分界研究为实例，对最佳自然界线的概  相似文献   

地球油气资源潜力是自然科学的基本问题   总被引：13，自引：2，他引：13  

徐怀大 《地学前缘》1995,2(3):0-0

层序地层学自１９８７年问世以来，在国外如火如荼地发展起来，石油地质界对它的发展尤为关注。然而，在我国却显得举步维艰，进展缓慢。本文讨论了出现这种状况的起因：①不认识地震反射界面基本上是等时面；②认为地震／层序地层学是研究被动大陆边缘海相地层产生的，不适于非海相地层；③常规剖面中的地震反射频率和分辨率太低，不足以进行层序地层学研究；④层序地层学属纯理论科学，脱离油气勘探实际，采纳它的概念可能打气生产秩序。最后文章从正面阐述了开展层序地层学研究的必要性。  相似文献   

主应变比异常理论在青海祁连地震预报中的应用     

李步云  陈志泰 《高原地震》1995,(1)

本文利用主应变比异常理论分析了祁连建站以来地应变观测资料，认为肃南──祁连断裂段上及附近发生的地震是由于构造应力场的变化，在引张应力状态下，正断层或走滑断层易于活动而导致的。  相似文献   

日侧极隙纬度低频波及其与地磁扰动的关系          下载免费PDF全文

廖怀哲 Egela.  A 《地球物理学报》1995,38(3):293-304

利用挪威斯瓦尔巴德地区的ＥＬＦ／ＶＬＦ观测资料和世界数据中心公布的Ｋｐ指数，分析了日侧极隙纬度低频波不同季节里的周日变化和１９８４年５月－１９８６年４月的年度变化及这些波与地磁扰动的某些关系．主要结果有：１．夏季ＥＬＦ波出现率极大值最大，而冬季的最小，前者约为后者的３倍，而且此极大值无论哪个季节都出现在磁正午时段．２．ＶＬＦ波出现率在夏季较小冬季较大；其极大值出现在磁午后至磁子夜前的２－４ｈ时段里．３．夏季ＥＬＦ波指数∑Ａ与地磁指数∑ＫＰ日变化较相吻合，在太阳自转周内两者相关系数约为０．６．４．冬季ＶＬＦ波指数∑Ａ与∑Ｋｐ日变化相吻合，在太阳自转周内两者相关系数可达０．８．这些结果表明日侧极隙纬度ＥＬＦ波和ＶＬＦ波各有不同的产生机制和源区．  相似文献