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961.
962.
人地关系调控与生态环境 --以长江洪灾为例 总被引:5,自引:0,他引:5
以长江洪灾为例,分析了人地相互作用的内容与方式,人地关系系统调控的任务与措施。认为洪灾频发的重要原因是人类对地质资源的不合理开发利用而导致生态系统的严重破坏。并认为要培植生态系统的抗干扰能力,应及时调整人地关系,改善农村的经济方式与经济条件,把生态建设作为国家长治久安的根本大事长期坚持下去。 相似文献
963.
有横缝拱坝的非线性动力模型试验和计算分析研究 总被引:12,自引:0,他引:12
本文通过在大型三向地震模拟振动台上进行的设置伸缩横缝的某拱坝非线性动力模型试验,应用非线性有限元动力分析程序同时进行计算分析,全面系统地研究了拱坝横缝对坝体动力特性和地震反应的影响,并对计算程序进行了改进。试验与计算结果相互印证,验证了试验成果的可靠性和计算分析模型、计算程序与计算结果的合理性。 相似文献
964.
965.
Generation of three dimensional flow fields for statistically anisotropic heterogeneous porous media
M. A. Cushy A. Bellin Y. Rubin 《Stochastic Environmental Research and Risk Assessment (SERRA)》1995,9(1):89-104
A methodology for generating three dimensional (3D) flow fields for statistically anisotropic heterogeneous porous media is presented and demonstrated. The simulated flow fields are shown to exhibit the input spatial correlation structure and observe mass continuity. Sample flow fields are presented in the form of cross sectional slices of the 3D formation. These cross sections demonstrate visually the characteristics of subsurface flow. The method was found to be faster than traditional techniques in terms of its computational requirements. Given this method, it is possible to generate the large number of realizations of a velocity field necessary to compute high order statistics in transport problems. 相似文献
966.
A chemistry module has been incorporated into a Lagrangian type model that computes the dynamics and microphysics of an orographical cloud formed in moist air flowing over the summit of Great Dun Fell (GDF) in England. The cloud droplets grow on a maritime aerosol which is assumed to be an external mixture of sea-salt particles and ammonium-sulfate particles. The dry particle radii are in the range 10 nm<r<1 µm. The gas-phase chemical reaction scheme considers reactions of nitrogen compounds that are important at night. The treatment of scavenging of gases into the aqueous phase in the model takes into account the different solubilities and accommodation coefficients. The chemistry in the aqueous phase focusses on the oxidation of S(IV) via different pathways.Sensitivity analyses have been performed to investigate deviations from gas-liquid equilibria according to Henry's law and also to study the influence of iron and of nitrogen compounds on the aqueous-phase oxidation of dissolved SO2. When addressing these questions, special attention has been given to the dependence on the droplet size distribution and on the chemical composition of the cloud condensation nuclei on which the droplets have formed. It was found that the oxidation of S(IV) via a chain reaction of sulfur radicals can be important under conditions where H2O2 is low. However, major uncertainties remain with respect to the interaction of iron with the radical chain. It was shown that mixing of individual cloud droplets, which are not in equilibrium according to Henry's law, can result in a bulk sample in equilibrium with the ambient air. The dependence of the aqueous-phase concentrations on the size of the cloud droplets is discussed for iron, chloride and NO3. 相似文献
967.
AN ATMOSPHERIC MOTION EQUATION BUILT ON THE CONSERVATIVE RELATIONSHIP OF THE ANGULAR MOMENTUM EXCHANGE BETWEEN THE SOLID EARTH AND THE ATMOSPHERE ON SEASONAL-ANNUAL TIMESCALE 下载免费PDF全文
Within the seasonal-annual timeseale,there exists an angular momentum conservative exchange relationship be-tween the solid earth and the atmosphere,and their angular momentum exchange not only can cause variations inlength-of-day(LOD)but also can express anomalies in atmospheric general circulation.Therefore,their angular mo-mentum exchange mechanism should be introduced into the general circulation model.Considering the angular momentum anomalous exchange caused by the air-earth interface friction effect,awhole-layer atmospheric motion equation is derived in this paper including the earth spin anomalous friction forceparameterized by using the change in the earth rotation rate.Through analysing the equation,it shows that the magni-tude of the earth spin anomalous friction force is the same as that of Coriolis force on seasonal-annual timescale. 相似文献
968.
运用相对运动的地球动力学理论,把软流圈以上的岩石圈和软流圈以下的地球内圈,作为两个独立的运动单元来考察它们随地球自转时所发生的变化和各自的运动状态。完整的岩石圈碎裂成岩石块之后,它们各自作为独立的单元,在纬向西漂力、经向离极力和洋底扩张力联合作用下,产生相对运动。 相似文献
969.
The aquatic chemistry of rare earth elements in rivers and estuaries 总被引:17,自引:0,他引:17
Edward R. Sholkovitz 《Aquatic Geochemistry》1995,1(1):1-34
Laboratory experiments were carried out to determine how pH, colloids and salinity control the fractionation of rare earth elements (REEs) in river and estuarine waters. By using natural waters as the reaction media (river water from the Connecticut, Hudson and Mississippi Rivers) geochemical reactions can be studied in isolation from the large temporal and spatial variability inherent in river and estuarine chemistry. Experiments, field studies and chemical models form a consistent picture whereby REE fractionation is controlled by surface/solution reactions. The concentration and fractionation of REEs dissolved in river waters are highly pH dependent. Higher pH results in lower concentrations and more fractionated composition relative to the crustal abundance. With increasing pH the order of REE adsorption onto river particle surfaces is LREEs > MREEs > HREEs. With decreasing pH, REEs are released from surfaces in the same order. Within the dissolved (<0.22 µm) pool of river waters, Fe-organic colloids are major carriers of REEs. Filtration through filters and ultrafilters with progressively finer pore sizes results in filtrates which are lower in absolute concentrations and more fractionated. The order of fractionation with respect to shale, HREEs > MREEs > LREEs, is most pronounced in the solution pool, defined here as <5K and <50K ultrafiltrates. Colloidal particles have shale-like REE compositions and are highly LREE enriched relative to the REE composition of the dissolved and solution pools. The addition of sea water to river water causes the coagulation of colloidal REEs within the dissolved pool. Fractionation accompanies coagulation with the order of sea water-induced removal being LREEs > MREEs > HREEs. While the large scale removal of dissolved river REEs in estuaries is well established, the release of dissolved REEs off river particles is a less studied process. Laboratory experiments show that there is both release and fractionation of REEs when river particles are leached with seawater. The order of sea water-induced release of dissolved REE(III) (LREEs > MREEs > HREEs) from Connecticut River particles is the same as that associated with lowering the pH and the same as that associated with colloidal particles. River waters, stripped of their colloidal particles by coagulation in estuaries, have highly evolved REE composition. That is, the solution pool of REEs in river waters are strongly HREE-enriched and are fractionated to the same extent as that of Atlantic surface seawater. This strengthens the conclusions of previous studies that the evolved REE composition of sea water is coupled to chemical weathering on the continents and reactions in estuaries. Moreover, the release of dissolved Nd from river particles to sea water may help to reconcile the incompatibility between the long oceanic residence times of Nd (7100 yr) and the inter-ocean variations of the Nd isotopic composition of sea water. Using new data on dissolved and particle phases of the Amazon and Mississippi Rivers, a comparison of field and laboratory experiments highlights key features of REE fractionation in major river systems. The dissolved pool of both rivers is highly fractionated (HREE enriched) with respect to the REE composition of their suspended particles. In addition, the dissolved pool of the Mississippi River has a large negative Ce-anomaly suggesting in-situ oxidation of Ce(III). One intriguing feature is the well developed maximum in the middle REE sector of the shale normalized patterns for the dissolved pool of Amazon River water. This feature might reflect competition between surface adsorption and solution complexation with carbonate and phosphate anions. 相似文献
970.
Rolf Sander 《Surveys in Geophysics》1999,20(1):1-31
For detailed modeling of atmospheric chemistry it is necessary to consider aqueous-phase reactions in cloud droplets and deliquesced aerosol particles. Often, the gas-phase concentration is in equilibrium with the aqueous phase. Then Henrys law can be used to describe the distribution between the phases provided that the Henrys law coefficient is known. In some cases, thermodynamic equilibrium will not be reached and it is necessary to use kinetic expressions of the rates involved. These rates depend on diffusion constants, accommodation coefficients, Henrys law coefficients, particle size distributions, and several other parameters. This review describes how these processes can be treated in computer modeling and how the necessary data can be obtained. Even though it is written primarily for use in modeling atmospheric chemistry, some parts will also be useful for waste water and pesticide control and in other areas where the distribution of chemicals between the aqueous and the gas phase is important. 相似文献