Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures     

P. C. Simon  D. Gillotay  N. Vanlaethem-Meuree  J. Wisemberg 《Journal of Atmospheric Chemistry》1988,7(2):107-135

Absorption cross-sections of nine halomethanes (CCl₄, CHCl₃, CH₂Cl₂, CH₃Cl, CFCl₃, CF₂Cl₂, CF₃Cl, CHFCl₂, and CHF₂Cl), measured between 174 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties ranging from 2 to 4% and compared with previous determinations made for comparable temperature ranges.The largest temperature effect which takes place near the absorption threshold, decreases the absorption cross-section up to 50% for highly chlorinated methanes, but is negligible for molecules highly stabilized by hydrogen and/or fluorine. Extrapolated values for temperatures of aeronomical interest are presented, as well as parametrical formulas which give absorption cross-section values for given wavelength and temperature ranges.  相似文献   

用相关系数估计导线点误差椭圆参数     

张兰英 《华东地质学院学报》1988,(3)

用比例误差k和导线边数n所表示的坐标相关系数r,当导线走向α=45°时,误差椭圆大小、形状与相关系数之间存在一个简单的数学关系式,在导线设计时可用作精度估算。  相似文献   

运城市地下水咸化趋势预测——准三维数值模拟方法   总被引：2，自引：0，他引：2       下载免费PDF全文

陈崇希  刘建刚 《地球科学》1993,18(1):48-59

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Infiltration-driven dehydration and anatexis in granulite facies metagabbro, Grenville Province, Ontario, Canada   总被引：2，自引：0，他引：2  

D. R. M. PATTISON 《Journal of Metamorphic Geology》1991,9(3):315-332

Dark hornblende + garnet-rich, quartz-absent metagabbro boudins from the Seguin subdomain, Ontario Grenville Province, are transected by anastomosing light-coloured veins rich in orthopyroxene, clinopyroxene, plagioclase and sometimes quartz. The veins vary in texture from fine-grained diffuse veins and patches that overprint the metagabbro, to coarse tonalitic leucosomes with sharp borders. The diffuse veins and patches are suggestive of channellized subsolidus dehydration of the metagabbro, while the tonalitic leucosomes are suggestive of local internally-derived anatexis. All vein types grade smoothly into each other, with the tonalitic leucosomes being the latest.
Relative to the host metagabbro, the veins have higher Si, Na, Ba & Sr, lower Fe, Mg, Ca & Ti, and similar Al. The coarser veins are enriched in K. Plagioclase becomes steadily enriched in Na in the transition from host metagabbro (An₄₇) to the veins (An₃₅), and in the coarsest veins it is antiperthitic. Differences in composition of the other minerals between host metagabbro and vein are minor. Pressure–temperature estimates are scattered, but indicate a minimum temperature during vein formation of 700°C at about 8 kbar.
Mass balance constraints indicate that the veins formed from the metagabbro in an open system. The transecting veins are interpreted to represent pathways of Si + Na + Ba + Sr ± K ± Al-enriched, low a _H2O fluids that metasomatized the host metagabbro to form the anhydrous veins. An initial period of localized solid-state dehydration of the metagabbro, represented by the diffuse veins, was followed by a transition to localized anatexis, represented by the tonalitic leucosomes. The change to anatexis may have been due to the addition of K to the infiltrating fluid. The source and delivery mechanism of the fluids is unknown.  相似文献   

A SEARCH TECHNIQUE FOR CHOOSING OPTIMUM PARAMETERS IN NUMERICAL WEATHER PREDICTION     

Liu Jin  Yan Hong 《Acta Meteorologica Sinica》1991,5(5):598-607

The steepest descent(or ascent)search is employed for finding optimum diffusion coefficients in T42L9Gmodel,with a view to improving the model's computational stability or prediction accuracy.The method of thesteepest descent search is first described,in which the golden section search is chosen as the fundamental one-dimensional search used in the multi-dimentional steepest descent search,and then the optimization of the dif-fusion coefficients is described.  相似文献   

Fluid flow patterns and infiltration isograds in melilite marbles from the Bufa del Diente contact metamorphic aureole, north-east Mexico   总被引：2，自引：0，他引：2  

W. HEINRICH  M. GOTTSCHALK 《Journal of Metamorphic Geology》1994,12(4):345-359

In the inner aureole of the Bufa del Diente alkali syenite (north-east Mexico), thin calcareous argillite bands horizontally embedded in impure marbles acted as contact-metamorphic aquifers for hypersaline brines of magmatic origin. Thick-bedded marbles were largely impervious. From 180 m up to the intrusion contact, argillites were completely decarbonated, resulting in melilite + wollastonite + phlogopite + perovskite-bearing parageneses. In marbles, this assemblage is confined to a narrow 7-12-m-wide infiltration zone adjacent to the contact. Up to this distance, calcite + wollastonite + diopside + alkali feldspar + titanite was stable, indicating that the fluid evolution in these marbles was internally buffered. Brine infiltration from the metaargillite aquifer into the marbles occurred perpendicular to the marble-metaargillite boundaries and was confined to a zone 4-6 cm wide above the boundaries. This is documented by the three reactions Cc + Di = Mel + CO₂, (1) Cc + Kfs + Di + H₂O = Phl + Wo + CO₂, (2) Cc + Ttn = Prv + Wo + CO₂, (3) Melilites (Ak_32-45Gh_13-32Sm_32-40 to Ak_52-72Gh_0-1Sm_28-48) occur as rims around diopsides and become continuously thicker towards the metaargillite beds. Fluid inclusion observations suggest that the infiltrating brine was hypersaline (NaCl + KCl_cq～ 65 wt%) and that the reactions took place at the water-rich side of the H₂O-CO₂-salts immiscibility field at about 600d? C (2, 3) and 660 to 680d? C (1) at P～ 1200 bar and X_co2～ 0.02. Mass balance calculations show that the amount of brine infiltrated from the aquifer into the marble was very low and decreased continuously with increasing distance from the boundary. The maximum width of brine infiltration was about 6 cm. This confirms that brine flow was largely parallel to the aquifer, not perpendicular to it. The CO₂ produced by the decarbonation reactions probably escaped as an immiscible low-density H₂O-CO₂ fluid of X_co2≤ 0.5 into overlying marble via grain-edge flow. The metaargillite-marble boundary acted as a semipermeable membrane 6 cm in thickness keeping back the brine in the aquifer and losing the in-situ produced low-density CO₂-rich fluid.  相似文献   

江西德兴斑岩铜矿床某些元素的扩散和渗滤作用     

Tang Yuanjun 《地球科学》1986,(1)

以江西德兴斑岩铜矿床之细矿脉为研究对象,文章介绍了细矿脉剖面采集及研究的工作方法,着重讨论了自矿脉至围岩元素的空间展布特征。成矿元素Cu、Ag、S和控矿元素Fe、Rb、K都属确定性分布型。对照元素的扩散和渗滤理想模式,得到如下认识:在成矿成晕的地球化学过程中,成矿元素Cu、Ag、S以及Fe以扩散作用为主,控矿元素K和Rb以渗滤作用为主。  相似文献   

小流域地下裂隙潜流对降雨入渗补给的响应特性     

曹建生  刘昌明  张万军 《水文地质工程地质》2005,32(5):20-23,26

采用翻斗法自动量水技术和时域反射仪,对“岩土二元结构”小流域降雨过程、流域出口地下裂隙潜流以及坡地岩土水分的变化进行了测定与分析。试验结果表明,小流域坡地特有的岩土二元结构体具有较强的储、透水性能,小流域在前期坡地岩土水分平均为14.48%(埋深100cm范围内)的前提下,发生总降雨量170.25mm,降雨历时31h,平均强度5.5mmh的大暴雨,在小流域出口处未产生地表迳流;地下裂隙潜流对降雨具有明显的响应,起涨和回落过程均较为明显,峰值流量达到810Lh,是降雨前的32.4倍。因此,科学合理地利用“岩土二元结构”的水文地质特性对缓解洪峰的形成,降低洪灾具有重要作用,同时对山区的雨水资源化问题也具有重要的实际意义。  相似文献   

胶东山丘区典型流域径流年内分配特征量化研究     

刘德林  刘贤赵  李嘉竹  宿庆 《山地学报》2007,25(3):295-301

采用M ann-Kendall法和最小方差法,对大沽夹河流域1966~2004年逐月实测径流数据进行均值变点分析。根据分析结果,将径流划分为水文变化特征相似的A(1966~1971年)、B(1972~1981年)、C(1982~1996年)、D(1997~2004年)4个时段。在此基础上借鉴年降水年内分配的向量法,提出了量化径流年内分配的集中度和集中期。结果表明:1.大沽夹河的不同水文年,其径流年内分配的特征不同。时段A集中度最小,时段D最大,4个时段变差系数为0.12。时段A和时段C的集中期比较接近,最大径流出现的时间均在7月下旬,时段B和时段D的集中期比较相似,最大径流出现的时间在8月中下旬。径流年内分配与降水年内分配两者呈显著正相关。2.用月径流量计算的集中度比径流年内不均匀系数具有更高的分辨能力和有效性,用月径流量计算的集中期对应的月份与月径流最大值出现的实际月份完全一致,径流集中度、集中期能够充分定量地表征径流在年内分配的非均匀性。  相似文献   

Parameterisation of the vertical transport in a small thermally stratified lake     

Christoph von Rohden  Karl Wunderle  Johann Ilmberger 《Aquatic Sciences - Research Across Boundaries》2007,69(1):129-137

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