蓝色翡翠的呈色机制探讨     

王铎  莫祖荣  李雪明  王洪权 《地质科学译丛》2013,(2):14-17

近期广东市场上出现了一种来自缅甸的蓝色翡翠样品,该样品目前未见相关报道。为了确定其定名,通过常规宝石学测试、红外光谱和X射线粉末衍射测试对样品进行分析,表明样品的主要矿物组成为硬玉,质量分数约97．1％,检测鉴定结论为翡翠。为了对蓝色翡翠呈色机制进行研究,通过紫外一可见吸收光谱测试,表明可见光区480nm以后逐渐增强的吸收带是其产生蓝色的原因;采用电子探针进行化学成分测试,表明蓝色的成因与钒离子有关。根据3d过渡金属离子的晶体场理论和翡翠晶体场理论的研究,可以推测：由于翡翠结构中M1位的Al3＋被过渡金属离子钒（V4＋）替代,目l起八面体结构畸变而导致蓝色的产生,因此,蓝色是过渡金属离子钒（v4＋）产生的原生色。  相似文献   

含芘氨基酸衍生物对水中Cd2+、Pb2+的高选择性识别研究     

鲁慧文  王德秋 《吉林地质》2005,24(4):92-94

本文报道了一种新型含芘氨基酸衍生物-L-[4-（1-芘基）]丁酰基苯丙氨酸（缩写为PLT）,通过对PLT与离子结合前后其二聚体/单体荧光发射峰强度比的检测表明该衍生物对水中的重金属离子Cd^2＋和Pb^2＋表现出了极强的识别性能,而对水中所存在的其它离子则具有完全不同的响应特性.  相似文献   

Analytical laboratory comparison of major and minor constituents in an active crater lake     

B. Takano  S. M. Fazlullin  P. Delmelle 《Journal of Volcanology and Geothermal Research》2000,97(1-4)

The crater lake water from Maly Semiachik volcano in Kamchatka was used for the international analytical laboratory comparison of major and minor elements, and hydrogen, sulfur, and oxygen isotope data. Eight institutions participated in this program, giving analytical results of 9 major and 20 minor elements mainly by using ICP-AES for cations and IC for anions. Among the major elements, Na, Mg and Si showed coefficients of variation (CV) of 10% or more, whereas B, Al, Fe, Mn had coefficients less than 7%. The CV% of the minor elements Co, Cu, P, Cr, Pb was much greater (>30%) while the V analyses agreed well (<10%). Ti, Sr, Zn, and F were intermediate (between 10 and 20 CV%). The errors observed for these constituents are inherent to the methods applied: large dilutions and spectrometric interferences. Even the major anions such as Cl (>2000 ppm) and SO₄ (>5000 ppm) gave considerable ranges (5.1 and 8.8 CV%, respectively) as did the obtained pH values (22 CV%). The measured δ¹⁸O of the water samples and δ³⁴S of sulfate are in excellent agreement but the δD values had CV% of 8. Technical recommendations are presented to improve the analytical results for these elements with significant deviations from the mean values.  相似文献   

渤海湾盆地石炭纪-二叠纪煤中基质镜质体飞行时间二次离子质谱研究     

王延斌  韩德馨  姜亮  杨青  王拯 《地球化学》2000,29(2):167-174

利用飞行时间二次离子质谱仪（简称ＴＯＦ－ＳＩＭＳ）对渤海湾地区Ｃ－Ｐ太原组和山西组煤中基质镜质体进行了对比研究,结果表明,在接收到的正二次离子中都含有一定的烯基和烷基碎片,这些脂族碎片离子的出现说明它们具有富氢及较好的生烃性质。同时,该仪器的实际应用结果表明,它对研究煤及源岩中有机显微组分的化学成分和结构具有独特的优势。  相似文献   

Characteristics of paleoproterozoic Subduction System in Western Margin of Yangtze Plate   总被引：1，自引：0，他引：1  

Zhang Hongxiang Liu Congqiang Xu Zhifang Geology  Geophysics Institute  Chinese Academy of Sciences  Beijing Huang Zhilong Geochemistry Institute  Chinese Academy of Sciences  Guiyang 《中国地质大学学报(英文版)》2000,11(1)

INTRODUCTIONDebate centered on Proterozoic tectonic style and crustalevolution has existed for a long time.The customary viewbelieved that the Proterozoic undeveloped solid plate could notput into effect on the subduction because of the high heat flowin the earth,and the continental crustal growth was dominatedby mafic magm a vertical underplating (Wyborn,1988;Etheridge etal.,1987) .However,many observations recentlyobtained from Proterozoic mobile zones in the world suggeststhat Proter…  相似文献   

Darcys Law Expressed by Chemical Index   总被引：3，自引：0，他引：3  

Hu Kuanrong Cao Yuqing Zhang Wenbing Hu Zhongyi Department of Hydrogeology  Engineering Geology  Changchun University of Science  Technology  Changchun 《中国地质大学学报(英文版)》2000,11(4)

Ｉｎ 18 5 6 ,ＨｅｎｒｙＤａｒｃｙｐｕｂｌｉｓｈｅｄｈｉｓｌａｗ ,ｔｈｅＤａｒｃｙ’ｓｌａｗ ,ｅｘｐｒｅｓｓｅｄｂｙｈｙｄｒａｕｌｉｃｉｎｄｅｘｔｈｒｏｕｇｈａｌｏｎｇ ｔｅｒｍｅｘｐｅｒｉｍｅｎｔｏｆｗａｔｅｒｐｅｒｍｅａｔｉｏｎｉｎｍｕｌｔｉ ｍｉｎｅｒａｌｍｅｄｉｕｍ (Ｘｕ ,1986 ) ,ｗｈｉｃｈｎｏｔｏｎｌｙｍｅｔｔｈｅｕｒｇｅｎｔｎｅｅｄｏｆｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｓｏｃｉａｌｅｃｏｎｏ ｍｙａｎｄｐｒａｃｔｉｃｅｆｏｒｃａｌｃｕｌａｔｉｏｎｏｆｗｅｌｌｗａｔｅｒｑｕａｎｔｉｔｙａｔｔ…  相似文献   

EARLY PALEOZOIC SUBDUCTION-RELATED ACCRETIONARY COMPLEX IN WESTERN KUNLUN     

Zhou Hui 《地学前缘》2000,(Z1)

EARLY PALEOZOIC SUBDUCTION-RELATED ACCRETIONARY COMPLEX IN WESTERN KUNLUN  相似文献   

红外掩星观测的首批结果     

杨少荣  钱忠钰 《中国天文和天体物理学报》1992,(3)

自从1991年9月28日我们首次成功地进行了SAO076523的红外月掩星观测以来,又接连进行了一些成功的观测。本文将简要地介绍观测的设备、数据处理方法和初步的处理结果。  相似文献   

青海盐湖锂资源开发现状及对提锂产业发展建议   总被引：4，自引：4，他引：0  

邓小川  朱朝梁  史一飞  樊洁  樊发英  卿彬菊  张毅  张文丁  杨佳亓  李阳阳 《盐湖研究》2018,26(4):11-18

中国正处在环境污染治理和产业结构调整的关键时期,发展新能源产业是应对能源和环境危机的必然选择;同时,锂资源储备和提锂技术直接影响到国家能源战略安全。中国科学院青海盐湖所经过二十年开发,目前已形成一套成熟的选择性离子迁移分离提锂技术,并经过了产业化和工业应用验证,核心技术达到国际领先水平。该产业化具有绿色、高效、低能耗、低物耗、低产品成本、高纯度等特点,技术通用性好,可推广应用到青海、西藏高海拔生态脆弱地区以及南美玻利维亚、阿根廷、智利等高镁锂比盐湖中锂的分离提取,在高钙镁地热水、油(气)田水提锂方面也有一定的应用潜力。  相似文献   

Rare Earth Magnets: Conservation of Energy and the Environment     

Takehisa Minowa 《Resource Geology》2008,58(4):414-422

Rare earth sintered magnets (Nd magnet) have been used in many applications such as computer and industrial equipment, automobile manufacturing and many others. They are highly efficient and reduce energy consumption because of their superior magnetic properties. The element dysprosium (Dy) contained in the Nd magnet is important and indispensable. It improves the stability of the Nd magnet by enhancing the coercive force of its magnetic properties at high temperature. Dy is not so abundant. The rapid growth of the Nd magnet may result in Dy shortage. Exploration for new deposits of Dy is desired.  相似文献