大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究   总被引：1，自引：3，他引：1  

冯旭文  钱江初  张培志 《矿物学报》2003,23(2):109-114

多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。  相似文献   

铅锌矿山开发导致的重金属在环境介质中的积累   总被引：35，自引：4，他引：35  

杨元根  刘丛强  张国平  吴攀  朱维晃 《矿物岩石地球化学通报》2003,22(4):305-309

以连续提取法和相关性分析研究了土法冶炼锌、铅锌和矿山开采导致的重金属在废渣及环境介质土壤、溪流沉积物中的积累，并分析了其环境危害性。结果显示，贵州赫章土法炼锌导致的重金属Pb、Zn、Cd在环境介质中的积累相当高。水城杉树林铅锌矿山开采引起的重金属积累则相对较低，但也明显高于背景值；土壤和沉积物中的铁矿物对重金属有强烈的固定作用。除残渣态外，Pb、Zn在土壤、炼锌废渣中主要呈铁锰氧化物结合态，沉积物中则为碳酸盐结合态。可交换态Pb、Zn含量变异较大，但在炼锌废渣、土壤中含量明显高于河流沉积物，暗示铅锌矿开发对土壤环境的潜在危害更大。  相似文献   

夏塞地区银、锡多金属矿成矿规律新认识     

李建兵  杨更  江元生 《四川地质学报》2003,23(3):146-149

夏塞地区是西南三江(金沙江、澜仓江、怒江)地区东缘的一个重要成矿带，带内银、锡矿产责源十分丰富。本文认为其成矿物质来源于花岗岩体和地层，构造和岩体是区内的主要控矿因素，地壳演化与成矿作用关系十分密切，矿床类型为分布于岩体内接触带的矽卡岩型矿床和分布于岩体外接触带的热液型矿床。  相似文献   

云南白秧坪银多金属矿床微量元素地球化学特征   总被引：1，自引：0，他引：1       下载免费PDF全文

王峰  何明友 《沉积与特提斯地质》2003,23(4):103-107

云南白秧坪银多金属矿床是滇西兰坪盆地内新发现的矿床，属东特提斯—喜马拉雅成矿域的一部分。矿床主要产于下白垩统景星组石英砂岩、粉砂岩中。本文从微量元素地球化学研究入手，与滇西喜马拉雅期富碱岩体相比较，它们具有相同的物质来源区，这种源区被认为是壳—幔物质混合的一种“EMⅡ型”富集地幔源。  相似文献   

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland     

孙玉壮  WILHELM PüTTMANN 《中国地球化学学报》2003,22(1):1-10

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.  相似文献   

大洋多金属结核研究概况   总被引：3，自引：0，他引：3  

杜灵通  吕新彪 《地质与资源》2003,12(3):185-187

从多金属结核的分布及富集规律、物质成分、内部结构、形成机制等方面论述了目前国内外的一些研究动态,对目前在这一研究领域提出的一些新概念、新方法作了一定的介绍.在分析和总结前人研究成果的基础上,指出了在这一研究领域还存在的一些问题及今后研究的方向.  相似文献   

乙醇增强—电感耦合等离子体质谱法直接测定地质样品中碲   总被引：9，自引：3，他引：9       下载免费PDF全文

韩丽荣李冰  马新荣 《岩矿测试》2003,22(2):98-102

建立了HF—HN03密封酸溶以及Na2O2熔融处理样品，乙醇增强灵敏度，电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ＝4％)，在0．85L/min的载气流速下，碲信号可增强2．5倍以上。碲的方法检出限(100，DF＝1000)为0．02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度，标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲，结果与其他方法相符，精密度试验RSD(n＝3)＜10％。  相似文献   

江西银山多金属矿床高盐度包裹体及其成因意义   总被引：13，自引：1，他引：13  

张德会  张文淮等 《岩石学报》2003,19(1):173-180

流体包裹体岩相学和显微测温学研究表明，银山矿床石英斑岩和金金属矿床中都发现须含石盐的高盐度流体包裹体，表明至少在成矿作用的早期成矿流体为高盐度流体，高盐度流体不是由热水溶液的不混溶作用或沸腾作用形成的，而是直接从饱和水的结晶岩浆熔体中出溶的，银山矿床的成矿流体与斑岩铜矿的成矿流体具有相似性，证实矿床深部可能有隐伏斑岩铜矿。  相似文献   

200 years of mining activities at La Paz/San Luis Potosí/Mexico - Consequences for environment and geochemical exploration     

Javier Castro-Larragoitia  Utz Kramar  Harald Puchelt 《Journal of Geochemical Exploration》1997,58(1):81-91

The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km² of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm.  相似文献   

Mobility of heavy metals as a function of pH of samples from an overbank sediment profile contaminated by mining activities     

Hans-Eike Gbler 《Journal of Geochemical Exploration》1997,58(2-3)

Parts of the flood plains north of the Harz Mountains are contaminated with heavy metals, such as Pb, Cu, Zn and Cd derived from mining, which has been carried out in the Harz Mts. since the Middle Ages. It is important to know the mobility of the heavy metals in these overbank sediments in order to estimate the danger to the environment arising from this source. This paper deals with the effect of pH on heavy-metal mobility, using a constant-pH method. The investigations were carried out on an overbank sediment profile near Salzgitter Bad, north of the Harz Mts. The mobility of the heavy metals in the overbank sediment profile is described as a function of pH and depth. Besides the mobile heavy-metal fraction at a certain pH, the buffering capacity of the sediment at this pH must be taken into consideration. The different layers of the overbank sediment profile show distinct differences in buffering capacity and a natural pH harrier could be identified in the upper part of the profile. Therefore, to avoid increasing heavy-metal mobility the natural layering of the overbank sediment profile should not be disturbed. Two different kinds of desorption experiments at constant pH are also discussed, as well as the conversion of the heavy-metal species in the ore minerals into the species in the sediment.  相似文献