Lithium Isotope Composition of Marine Biogenic Carbonates and Related Reference Materials          下载免费PDF全文

Luc Bastian  Nathalie Vigier  Stéphanie Reynaud  Marie‐Emmanuelle Kerros  Marie Revel  Germain Bayon 《Geostandards and Geoanalytical Research》2018,42(3):403-415

In this study, the accuracy and the precision corresponding to Li isotopic measurements of low level samples such as marine and coastal carbonates are estimated. To this end, a total of fifty‐four analyses of a Li‐pure reference material (Li7‐N) at concentrations ranging from 1 to 6 ng ml^?1 were first performed. The average δ⁷Li values obtained for solutions with and without chemical purification were 30.3 ± 0.4‰ (2s, n = 19) and 30.2 ± 0.4‰ (2s, n = 36), respectively. These results show that the chosen Li chemical extraction and purification procedure did not induce any significant isotope bias. Two available carbonate reference materials (JCt‐1 and JCp‐1) were analysed, yielding mean δ⁷Li values of 18.0 ± 0.27‰ (2s, n = 6) and 18.8 ± 1.8‰ (2s, n = 9), respectively. Small powder aliquots (< 15 mg) of JCp‐1 displayed significant isotope heterogeneity and we therefore advise favouring JCt‐1 for interlaboratory comparisons. The second part of this study concerns the determination of δ⁷Li value for biogenic carbonate samples. We performed a total of twenty‐nine analyses of seven different tropical coral species grown under controlled and similar conditions (24.0 ± 0.1 °C). Our sample treatment prior to Li extraction involved removal of organic matter before complete dissolution in diluted HCl. Our results show (a) a constant δ⁷Li within each skeleton and between the different species (δ⁷Li = 17.3 ± 0.7‰), and (b) a Li isotope fractionation of ?2‰ compared with inorganic aragonite grown under similar conditions. Comparison with literature data suggests a significant difference between samples living in aquaria and those grown in natural conditions. Finally, we investigate ancient (fossil) carbonate material and foraminifera extracted from marine sedimentary records. Different leaching procedures were tested using various HCl molarities. Results indicate that carbonate preferential dissolution must be carried out at an acid molarity < 0.18 mol l^?1. Possible contamination from silicate minerals can be verified using the Al/Ca ratio, but the threshold value strongly depends on the carbonate δ⁷Li value. When the silicate/carbonate ratio is high in the sediment sample (typically > 2), contamination from silicates cannot be avoided, even at low HCl molarity (? 0.1 mol l^?1). Finally, bulk carbonate and foraminifera extracted from the same core sample exhibited significant discrepancies: δ⁷Li values of foraminifera were more reproducible but were significantly lower. They were also associated with lower Sr/Ca and higher Mn/Ca ratios, suggesting a higher sensitivity to diagenesis, although specific vital effects cannot be fully ruled out.  相似文献   

四川自贡地区地下卤水锂矿化特征及靶区预测     

詹涵钰  马红熳  武文辉  秦宇龙  吴和  易胜利 《中国地质调查》2018,5(4):17-24

锂作为一种新能源、新材料,对国民经济建设及国防安全保障具有重要的战略意义。卤水中液体锂为锂资源的主要来源之一。四川盆地自贡地区地下卤水资源丰富,但开发利用方式较为单一。前人对自流井背斜卤水中的锂资源研究较少,但已有数据均表明局部卤水中Li⁺含量达单独开采工业品位的2~4倍,具有较高的开采价值。近年来,对自贡地区的地下卤水资源分布情况进行了调查,对有利地区采集的样品进行了分析,结果表明: 锂资源已达边界品位的3~4倍、最低工业品位的2倍以上; Li⁺与Na⁺、K⁺、$NH^{+}_{4}$、Cl^-含量呈明显的正相关,卤水中Na⁺、K⁺、$NH^{+}_{4}$、Cl^-的含量可作为Li⁺含量的间接指示; 降低卤水中Mg/Li值能够有效控制提锂成本; 相比于黄卤,黑卤有较低的Mg²⁺和较高的Li⁺、Na⁺、K⁺、$NH^{+}_{4}$及Cl^-。通过综合分析认为,邓井关背斜的轴部黑卤密集分布地区可作为锂资源的找矿靶区。  相似文献   

察尔汗盐湖别勒滩区段固态锂的赋存状态与分布特征     

张宇萌  胡宇飞  王笛  刘成林  李瑞琴  王罗海  刘万平  沈立建  焦距 《矿床地质》2023,42(1):77-89

察尔汗盐湖别勒滩区段赋存大量具有开发潜力的固态锂资源,但目前对固态锂的赋存状态和分布特征研究较少。文章利用水溶法、稀酸溶法和全岩溶解法3种方法对该区4个钻孔的15件岩芯样品进行主微量元素分析。研究结果显示,水溶法的w(Li)(Li溶出量,余同)为23.37×10^-6～85.98×10^-6,稀酸溶法的w(Li)为47.77×10^-6～139.58×10^-6,全岩溶解法w(Li)为49.47×10^-6～151.64×10^-6。以同一样品全岩溶解所得的w(Li)为100%,水溶法、稀酸溶法的w(Li)平均值分别为56.44%和92.83%。结合矿物薄片鉴定、扫描电镜分析和X射线衍射的鉴定结果,岩芯样品中的矿物主要是石盐、杂卤石、光卤石、石英、绿泥石、钠长石、硬石膏、白云石、伊利石、菱镁矿和方解石等,推测固态锂大部分赋存于易溶盐类矿物,其余赋存于不易溶的碳酸盐、硫酸盐和硅酸盐等矿物中。根据4个钻孔岩芯样品的Li溶出量来看,察尔汗盐湖别勒滩区段固体钾盐层中固态锂的分...  相似文献   

贵州狮溪铝土岩型锂资源的发现及意义          下载免费PDF全文

邓旭升  余文超  杜远生  杜威  熊兴国  曾禹人  龙建喜  张晗彬  符宏斌  何犇  卢树藩  罗香建 《地质论评》2023,69(1):133-147

狮溪锂资源位于贵州省桐梓县狮溪向斜东翼,是首次在黔北务(川)、正(安)、道(真)地区之外的下二叠统大竹园组中发现锂元素的异常富集。狮溪锂富集层位于大竹园组中—上部,具有厚度和品位均较为稳定的特征,含锂岩石类型为致密状和碎屑状铝土岩,主要矿物为伊利石(水白云母)。综合矿物学、岩石学及地球化学特征分析认为,该区域Li的富集与风化淋滤作用密切相关,受古气候、古地貌、地下水位等多因素控制。通过统计黔北地区和狮溪地区含铝岩系数据发现,Li含量与Al₂O₃、Al/Si值呈规律性变化,Li富集程度与大竹园组的岩性相关,大致可分为Li一般富集区(含矿岩石为泥岩或铝土质泥岩、较高品位铝土矿)和Li高度富集区(含矿岩石为铝土岩和低品位铝土矿)。笔者等通过狮溪锂资源的发现及综合分析认为,在黔北务(川)、正(安)、道(真)地区外围的近岸平原环境,特别是在地势低洼处形成的致密状和碎屑状铝土岩中,具有发现较高品位铝土岩型锂资源的巨大潜力。  相似文献   

地质历史时期海洋Li同位素演变     

莫洪成  杨瑞东  高军波  罗朝坤  倪莘然  李鑫正  周登峰  薛忠喜 《地质论评》2023,69(3):929-942

Li是一种碱金属元素,由于它不受氧化还原和生物效应的影响,因此在追踪地球元素循环方面非常有利。并且Li在海洋中的留存时间远大于海水混合时间,因此海洋中的Li具有相对均一的组成,从而能够代表对应地质历史时期整体海洋情况。近年来海洋Li同位素被应用在示踪大陆风化模式领域,并取得了很多成果。笔者等在系统总结全球海洋Li循环作用和表生地质作用的Li同位素分馏机制的基础上,通过收集并整理、估算了不同时期海洋Li同位素组成,对地质历史时期海洋Li同位素组成变化与改变大陆风化模式相关的地质事件进行分析,再结合同时期碳酸盐岩C、Sr同位素数据进行对比分析,探讨Li、C、Sr同位素演化与地质事件之间的关系。最后,讨论了目前海洋Li同位素组成方面研究的不足,为后续利用海洋Li同位素记录示踪大陆风化模式的应用提供了参考。  相似文献   

Leachate Lithium Characteristics of Loess-paleosol Sequences on the Chinese Loess Plateau and their Paleoclimatic Significance     

JIA Peng  FU Chaofeng  HE Maoyong  LIU Junfeng  LIU N  LI Yulong  YANG Kaiyuan 《《地质学报》英文版》2023,97(6):1814-1824

The geochemical components of the leachate from loess-paleosol deposits can provide information about climate-related post-depositional processes. For example, leachate lithium ([Li]leachate) is a potential paleoclimate proxy because lithium is a typical lithophile element that is readily adsorbed by clay minerals during weathering and pedogenesis, and thus stratigraphic variations in [Li]leachate can reflect these processes. We investigated the [Li]leachate values of two loess-paleosols profiles (the Luochuan and Weinan sections), on a north–south climatic gradient on the Chinese Loess Plateau. Independent paleoclimate information was provided by measurements of magnetic susceptibility, grain size, Rb/Sr ratios, and clay mineral content. During the last glacial-interglacial period, [Li]leachate increased from 0.39 to 1.97 μg/g at Luochuan and from 0.67 to 2.45 μg/g at Weinan, mainly due to increasing pedogenesis. Based on these results we developed a conceptual model to explain the variations in [Li]leachate. Li+ within loess layers is mainly derived from dust input and the decomposition of primary minerals, influenced by the East Asian winter monsoon, while in paleosol layers Li+ is mainly derived from clay mineral adsorption during pedogenic processes, influenced by the East Asian summer monsoon.  相似文献   

赣南石雷钨锡矿云英岩型锂矿找矿新发现及其区域成矿潜力分析          下载免费PDF全文

王成辉  王登红  刘善宝  许建祥  秦锦华  秦燕  刘金宇  赵正  冯文杰  刘战庆  赵如意  郭春丽 《中国地质》2022,49(6):1834-1844

近年来,随着赣西北云母型锂矿的大规模开发利用,华南云英岩型、蚀变花岗岩型等岩体型锂矿逐渐受到关注。赣南是世界著名石英脉型黑钨矿集区和生产基地,以往勘查研究工作多集中在钨锡矿。【研究目的】为进一步了解石英脉型钨锡矿中是否存在锂矿化及其地质特征。【研究方法】本次研究通过系统的岩矿鉴定和激光剥蚀电感耦合等离子体质谱仪（LA-ICP-MS）分析,查明了在赣南崇余犹矿集区章源钨业石雷钨锡矿深部存在云英岩型锂矿。【研究结果】研究表明,锂矿体产于石雷矿区深部隐伏花岗岩体的顶部,分布于含钨锡石英脉和长石石英脉的两侧,锂元素主要赋存在白云母—多硅白云母之中。产于角岩化砂岩中的云英岩的Li₂O含量平均为0.25%,二云母花岗岩中石英（长石）脉—云英岩Li₂O含量平均为0.21%,二云母花岗岩中发育的含云母脉云英岩Li₂O平均为0.22%,具有潜在的综合利用价值。【结论】本次研究查明了石雷石英脉型钨锡矿中存在工业意义的云英岩型锂矿化,进一步丰富了赣南石英脉型钨锡矿的成矿理论,拓宽了崇余犹地区云英岩型锂矿的找矿勘查思路,并为进一步拓展华南地区岩体型锂矿的找矿空间提供了依据。  相似文献   

熔融制样X射线荧光光谱法测定珍珠岩矿中主量元素     

李鹏程  王梅英  李艳华  张明炜  刘春霞  王冀艳  刘勉  陈冲科  鲁鲲  李振 《岩矿测试》2015,34(1):104-110

珍珠岩矿的化学成分对其膨胀特性有重要影响,是珍珠岩矿的重要质量指标,目前大多采用容量法、重量法、分光光度法、原子吸收光谱法等传统方法对各化学成分进行测定,操作复杂,而且不能满足主量元素同时测定的要求。本文采用熔融法制样,建立了X射线荧光光谱同时测定珍珠岩矿中主量元素(Si、Al、Fe、Ca、Mg、Ti、K、Na)的分析方法。样品制备试验结果表明,试样与四硼酸锂-偏硼酸锂(质量比67∶33)混合熔剂稀释比为1∶10,熔融温度为1050℃时,样品熔融完全,制备的熔片满足分析方法的要求,且克服了珍珠岩矿高温熔矿时由于膨胀不均匀而导致硅元素测量结果偏低的问题。通过仪器测量条件的优化,以国家标准物质和自制校准样品拟合校准曲线,并进行基体效应校正,实际矿区样品测量结果与化学分析法的测定值基本吻合。方法检出限小于0.05%,精密度(RSD,n=12)小于1.5%。本方法与经典分析方法相比,简便高效、绿色环保、精密度高、准确度好,一次熔矿能够同时测定珍珠岩矿中全部主量元素,满足了珍珠岩矿快速分析测试的需要。  相似文献   

Potential Orthopyroxene,Clinopyroxene and Olivine Reference Materials for In Situ Lithium Isotope Determination   总被引：1，自引：0，他引：1       下载免费PDF全文

Ben‐Xun Su  Xiao‐Yan Gu  Etienne Deloule  Hong‐Fu Zhang  Qiu‐Li Li  Xian‐Hua Li  Nathalie Vigier  Yan‐Jie Tang  Guo‐Qiang Tang  Yu Liu  Kwan‐Nang Pang  Aaron Brewer  Qian Mao  Yu‐Guang Ma 《Geostandards and Geoanalytical Research》2015,39(3):357-369

Over 1400 electron probe and 700 ion probe microanalyses were performed on eleven mineral separates to evaluate their potential as reference materials for in situ Li isotopic determination. Our results suggest the homogenous distributions of major elements, Li and its isotopes for each sample. Hence, these samples are suitable to be used as reference materials for in situ measurements of Li abundance and Li isotopes by secondary ion mass spectrometry (SIMS) or laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS). These samples have the advantage of mitigating probable matrix effects during calibration owing to the wide range of compositions. The effect of composition on the δ⁷Li of olivine measured by SIMS is a linear function of composition, with δ⁷Li increasing by 1.0‰ for each mole per cent decrease in forsterite component.  相似文献   

基于LightGBM的盐湖锂浓度遥感反演研究——以西藏扎布耶盐湖北湖为例     

刘婷玥  代晶晶  赵元艺  田淑芳  叶传永 《地质学报》2021,95(7):2249-2256

青藏高原盐湖中的锂、硼等矿产资源具有极高的经济价值.锂、硼等矿产资源的含量及其空间分布是盐湖观测的重点,对于盐湖资源的开发利用具有重要的指导意义.利用遥感技术开展盐湖观测可以克服传统观测站观测空间上数据不连续、费时费力等缺点,而机器学习等人工智能算法可以快速高效地挖掘遥感数据信息,因此本文基于Landsat-8遥感影像数据,利用LightGBM算法开展西藏扎布耶盐湖北湖锂浓度遥感反演.经过采样点波谱数据的获取、锂浓度LightGBM回归模型的构建、盐湖锂浓度反演一系列的实验步骤,最终的模型评价结果显示平均相对误差为0.053530925,均方根误差为10.2869,卡方为0.867,模型与实测数据拟合程度较高.反演结果表明:整个北湖中,锂浓度最高的是东南部的水域,最低的是中西部的水域;河流和秋里南木泉水群的汇入使得附近的水域锂浓度降低;对于本身位于中部锂浓度低值区的钙华岛来说,岛内泉水的汇入使得附近的水域锂浓度有所升高,这一结果与实际情况较为吻合.通过本文的反演研究,证明了LightGBM机器学习算法用于快速反演盐湖锂浓度的可行性和精确性,同时为其它盐湖矿产资源遥感反演提供了技术启示,也为后续的盐湖资源量评估奠定了基础.  相似文献