Controls on metamorphic equilibration: the importance of intergranular solubilities mediated by fluid composition          下载免费PDF全文

W. D. Carlson  J. D. Hixon  J. M. Garber  R. J. Bodnar 《Journal of Metamorphic Geology》2015,33(2):123-146

A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO₂‐rich to H₂O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO₂‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H₂O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.  相似文献   

地表覆盖遥感产品更新完善的研究动向     

陈军  张俊  张委伟  彭舒 《遥感学报》2016,20(5):991-1001

近年来,多尺度地表覆盖遥感产品的不断涌现,为环境变化研究、地球系统模拟、地理国(世)情监测和可持续发展规划等提供了重要科学数据。为更好地满足广大用户日益增长的应用需求,应对地表覆盖遥感产品进行持续更新完善,保持其时效性、增强时序性、丰富多样性。针对大面积地表覆盖遥感产品更新完善所面临的主要问题,介绍和评述了国内外有关研究动向,包括影像与众源信息相结合的更新、数据类型细化与完善、地表覆盖真实性验证,并作了简要展望。  相似文献   

不确定度评定及在产品符合性判定中的应用金属铟中锡的 ICP-AES 测定方法     

向德磊 《矿产与地质》2016,(3):508-511

建立了金属铟中锡的 ICP-AES 测定方法过程的数学模型,通过分析得到了对测定结果正确度影响的不确定度来源,评定了各个不确定度度分量、合成标准不确定度和扩展不确定度。并通过对标准方法的重复性、再现性等概念的讨论,说明了不确定度值在产品等级判定上的使用。  相似文献   

动力学模型预测深海鲣鱼(Katsuwonus pelamis)调理食品常温下的货架期     

白冬  王欢  谢超  林琳  黄菊  梁佳  王婷 《海洋与湖沼》2016,47(1):221-226

为了预测鲣鱼(Katsuwonus pelamis)调理食品的货架期,将鲣鱼调理食品贮藏在25°C、30°C、35°C温度条件下,通过测定在贮藏期间菌落总数、挥发性盐基氮、过氧化值三个指标的变化,分别对这三个指标与贮藏时间、温度建立一级动力学模型,来预测鲣鱼调理食品的货架期。经计算得出,菌落总数预测模型中的活化能(Ea)及指前因子(k0)分别为30.96 k J/mol和2.06×103,挥发性盐基氮预测模型中的的活化能及指前因子分别为24.35 k J/mol和75.1,过氧化值预测模型中的活化能及指前因子分别为48.75 k J/mol和2.92×106。在32°C和37°C条件下验证动力学模型,结果表明相对误差分别为–5.52%和–6.45%,准确性较好。进一步推算得出,在18°C和23°C常温下贮藏鲣鱼调理食品,产品的货架期为209d和172d。  相似文献   

中国近海以及邻近海域海洋再分析产品(CORA)中季节内变化的评估   总被引：5，自引：2，他引：3  

张敏  周磊  付红丽  姜良红  章向明 《海洋学报(英文版)》2016,35(3):90-101

A regional reanalysis product—China Ocean Reanalysis(CORA)—has been developed for the China's seas and the adjacent areas. In this study, the intraseasonal variabilities(ISVs) in CORA are assessed by comparing with observations and two other reanalysis products(ECCO2 and SODA). CORA shows a better performance in capturing the intraseasonal sea surface temperatures(SSTs) and the intraseasonal sea surface heights(SSHs) than ECCO2 and SODA do, probably due to its high resolution, stronger response to the intraseasonal forcing in the atmosphere(especially the Madden-Julian Oscillation), and more available regional data for assimilation. But at the subsurface, the ISVs in CORA are likely to be weaker than reality, which is probably attributed to rare observational data for assimilation and weak diapycnal eddy diffusivity in the CORA model. According to the comparison results, CORA is a good choice for the study related to variabilities at the surface, but cares have to be taken for the study focusing on the subsurface processes.  相似文献   

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions     

WU Yingzhong  DUAN Yi  ZHAO Yang  CAO Xixi  MA Lanhu  QIAN Yaorong  LI Zhongping  XING Lantian 《《地质学报》英文版》2018,92(5):1879-1887

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.  相似文献   

Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials          下载免费PDF全文

W. Q. Shen  J.‐F. Shao  D. Kondo 《国际地质力学数值与分析法杂志》2017,41(13):1453-1473

Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

北京西山宏观藻类化石的发现   总被引：3，自引：0，他引：3       下载免费PDF全文

萧宗正 《地质科学》1990,(4):403-407

1980年,作者于北京西山青白口系的命名地点——青白口村西,发现了宏观藻类化石。这些化石呈椭圆形、卵形、肾形及鞋底形等多种形态,有的带有拟茎构造。它们与广泛出现在我国东部前寒武系相当地层中的宏观藻类可以对比。  相似文献   

黑铜矿、蓝铜矿、孔雀石溶解度图的绘制     

Li Shenghua 《吉林大学学报(地球科学版)》1990,(2)

本文阐述了如何用热力学方法绘制 Cu(Ⅱ)的氧化物、氢氧化物、碳酸盐矿物的溶解度图。  相似文献   

金在表生条件下溶解,迁移和沉淀的探讨   总被引：2，自引：0，他引：2  

周学粹 《矿物岩石》1990,10(3):6-14

金矿物在表生条件下溶解为离子金.离子金与表生络合剂结合成金络离子团迁移.在物化条件改变时,由于有机炭、粘土矿物及带异性电荷胶体吸附,使金络离子团分解成原子金沉淀.  相似文献