多金属结核的沉积物地球化学场     

杨慧宁  陈永志  沈桂梅 《岩石矿物学杂志》1996,15(4):307-315

远洋沉积物是多金属结核赖以生长的场所，本文系统地研究了沉积物中主要成矿元素水成组分在不同地球化学场和不同沉积阶段的地球化学特征，以及水成组分的含量比与成矿作用的相互关系。研究表明，Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ都是一些比较活泼的元素，它们共处于多金属结核、沉积物和大洋水的统一体系中，当结核形成时，Ｍｎ、Ｆｅ、Ｎｉ、Ｃｕ在结核与沉积物中的含量呈负相关，而Ｃｏ含量呈正相关。研究区东部结核以富含Ｍｎ、Ｎｉ、Ｃｕ贫Ｆｅ、Ｃｏ为特征，其伴生沉积物相对贫Ｍｎ、Ｎｉ、Ｃｕ、Ｃｏ，而富Ｆｅ，可称之为贫化的地球化学场。研究区西部结核富含Ｆｅ、Ｃｏ而贫Ｍｎ、Ｎｉ、Ｃｕ，其伴生沉积物则相应贫Ｆｅ，而富Ｍｎ、Ｎｉ、Ｃｕ、和Ｃｏ，可称之为富化的地球化学场。可以看出，贫化的沉积物地球化学场，恰恰是寻找富矿结核的最佳场所。早中新世以来的沉积物，根据水成组分的含量或含量比，也可相应于结核的形成分为三大沉积阶段，其中的第Ⅱ阶段具有贫化的地球化学特征，是多金属结核形成的最有利时期  相似文献   

中国海洋地球物理进展   总被引：2，自引：2，他引：2       下载免费PDF全文

刘光鼎 《地球物理学报》1997,40(Z1):46-49

在中国地球物理学会50周年之际，总结海洋地球物理工作是十分重要的文章从中国海油气普查、近海工程地质调查。大洋多金属结核调查和中国海基础调查四个方面简要地阐述它们的进展。  相似文献   

碳酸锰氧化实验和热力学分析     

郝瑞霞  关广岳 《地质论评》1997,43(2):167-172

通过对碳酸锰氧化实验的结果分析和讨论，建立了一种适合于锰氧化过程的非平衡热力学模型，并利用此模型对硫酸锰氧化过程作了热力学可行性分析，研究结果表明，碳酸锰氧化过程是矿物组合的变化过程，也是锰自身价态的转为过程，整个过程既存在平衡状态，又存在非平衡状态，是一个不可逆的，多相的复杂反应。  相似文献   

催化褪色光度法测定痕量锰的研究及应用   总被引：2，自引：0，他引：2  

康文  周发连 《华东地质学院学报》1997,20(2):141-146

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。  相似文献   

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)     

M. Roy-Barman  C. Jeandel  M. Souhaut  M. Rutgers van der Loeff  I. Voege  N. Leblond  R. Freydier 《Earth and Planetary Science Letters》2005,240(3-4):681-693

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

湖南省沉积型锰矿地质环境及成矿作用   总被引：2，自引：0，他引：2  

石少华 《地质与勘探》2016,52(2):209-219

湖南省沉积型锰成矿时代跨度大,最早由早元古代板溪群马底驿期至早二叠世孤峰期。其中,早南华纪大塘坡期、中奥陶世烟溪期及中二叠世孤峰期为三个最主要成锰集中期,并且大体呈现出朝东南方向成矿时代变新的趋势。成锰沉积盆地是锰矿床就位的重要场所,相应的岩相古地理环境为锰成矿创造了有利条件,即相对缺氧的、滞流的安静环境。这种环境在诸多古地理环境中都可以形成,导致了锰成矿岩相古地理环境的多样性,如浅海陆棚相、次深海棚缘盆地相、次深海台缘斜坡相及陆表次深海海盆相。三个主要成锰期锰成矿作用具有统一性,成矿作用与地壳拉张、海侵事件、缺氧事件等区域性重大地质事件关联密切。  相似文献   

四川观音梁子锰矿床地质特征及找矿意义          下载免费PDF全文

郑辉 《地质找矿论丛》2016,31(3):317-324

观音梁子锰矿赋存于寒武系邱家河组中,是龙门山中段在邱家河组中新发现的工业锰矿床。通过矿区勘探工作及室内观察、测试等手段,对矿区成矿地质背景、含锰岩系、矿体及矿石矿物特征、矿床成因、找矿前景等方面进行了初步总结分析。研究发现,观音梁子锰矿为典型的沉积型锰矿床,矿体呈层状产于邱家河组三段硅质白云岩中,延伸较稳定,严格受层位的控制;矿石类型为菱锰矿型,主要由菱锰矿、硫锰矿、水锰矿等组成。早寒武世,龙门山地区由于地壳拉张裂陷形成深海盆地,在还原环境下,锰元素与碳酸根直接结合形成碳酸锰矿物,稳定的物源、深海还原环境为锰矿富集提供了有利的成矿环境。观音梁子锰矿的发现,证实了龙门山北段邱家河组含锰层位的存在,为龙门山中段的锰矿找矿提供了契机,同时显示了寒武系邱家河组具有良好的找锰远景。  相似文献   

湖南湘潭锰矿的地球化学特征及成矿机制     

史富强  朱祥坤  闫斌  刘燕群  张飞飞  赵妮娜  褚明恺 《岩石矿物学杂志》2016,35(3):443-456

湘潭锰矿床的锰矿层赋存于新元古代南华系(成冰系)大塘坡组底部含锰黑色页岩中,含锰矿物主要为菱锰矿。湘潭锰矿的Fe/Mn值低,Th/U、V/(V+Ni)和V/Cr值等地球化学指标显示其发育在氧化-次氧化的沉积环境中,暗示菱锰矿并不是由Mn~(2+)和CO_3~(2-)直接沉淀形成的。湘潭锰矿稀土元素含量高,稀土元素配分模式存在轻微的中稀土元素富集,具有明显的Ce正异常,这些特征指示湘潭锰矿含锰矿物是以锰氧化物或氢氧化物的形式沉淀的。同时,锰矿的碳同位素富集碳的轻同位素,说明有机物参与了菱锰矿的形成过程。综合分析表明,湘潭锰矿成矿过程可以分为沉淀和转化两个阶段:在氧化性的水体中,Mn以氧化物或氢氧化物的形式沉淀;在缺氧且富含有机物质的成岩环境中,Mn氧化物或氢氧化物被有机物还原而转化生成菱锰矿。这与华南地区其他几个典型的大塘坡式锰矿的成矿机制一致。  相似文献