Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Caractérisation des paragenèses et des paléocirculations fluides dans l'indice d'or de Bleı̈da (Anti-Atlas,Maroc)Characterization of the paragenesis and the fluid palaeo-circulations in the gold showings of Bleida (Anti-Atlas,Morocco)     

Ahmed Barakat  Christian Marignac  Marie-Christine Boiron  Mohamed Bouabdelli 《Comptes Rendus Geoscience》2002,334(1):35-41

The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41  相似文献   

氢氧化镁沉淀热力学、动力学及控制   总被引：5，自引：0，他引：5       下载免费PDF全文

许荣辉  李海民 《盐湖研究》2003,11(3):40-42,46

分析了氢氧化镁絮状沉淀生成的热力学、动力学 ,提出了使其结晶的控制措施  相似文献   

遵义市城区及周边地带制砖页(泥)岩地质特征和开发前景     

王祁仑  金华英 《贵州地质》2003,20(1):50-55

文章对遵义市城区及周边地带各地质时代的页（泥）岩已有资料进行了系统收集、归纳和适当的野外调研，认为区内制砖页（泥）岩层位可分为三类，第一、二类利用价值小或仅有部分可以利用，第三类则易于露采，大部分可利用，其层位为下奥陶统湄潭组和下三叠统夜郎组九级滩段，是区内可作制砖页（泥）岩利用最有开发前景的层位。同时对页（泥）岩的形成沉积环境作了简要分析，对其资源量进行了概略估算，经优化筛选，提出了10个供制砖厂企设置布局和矿源地选择之前需进行地质勘查的区块。  相似文献   

由电法勘探资料计算地下水矿化度的软件系统     

强建科  郭建强  朱庆俊  罗延钟 《物探化探计算技术》2003,25(3):226-231

地下水矿化度是划分地下咸淡水的重要参数，过去人们常用手工计算。但由于涉及的参数众多，计算过程烦琐，人工计算不仅速度慢，而且容易出错。一种利用Visual Fortrain和C^ 编制的批量计算地下水矿化度的软件系统，可有效地解决这类烦恼。该系统根据事先由电(磁)测深资料反演出的真电阻率数据，借助水文地质资料划分出不同区块的孔隙度、水质类型及温度等参数，自行判别计算公式，在数秒内可算完一条电(磁)测深剖面下的地下水矿化度。经实际试算，效果令人满意。  相似文献   

Origin and Formational Environment of Noda-Tamagawa Manganese Ore, Northeast Japan: Constraints from Isotopic Studies     

Mohammed El Rhazi  Ken-ichiro Hayashi 《Chemie der Erde / Geochemistry》2003,63(2):149-162

  相似文献   

我国9大气候区降水特性及其物理成因的研究Ⅰ——基本特性分析   总被引：2，自引：2，他引：2  

苗娟  林振山 《热带气象学报》2003,19(4):377-388

首先利用旱涝Z指数对全国9大气候区的旱涝进行了评定，并给出我国9大气候区旱涝Z指数的分布图。分析结果表明，1950年代我国除新疆地区处于偏早期外，其它几个区都处于多雨量期，1960年代由多雨向少雨转变的时期，1970年代——1980年代中期我国大部分地区处于雨量偏少期；1990年之后我国各个区的雨量都有所增加。此外，还应用Morlet小波变化对我国9大气候区降水的旱涝周期变化、旱涝分型及变化趋势进行了分析。研究结果表明：在16年、32年层次变化上，各气候区在不同时间段上，8年层次上降水的变化出现了一定的规律：东北、华北在1980年之后存在1年位相差；而长江中下游、江南及华南三者之间在1951～1970年时段上依次有着2年的位相差；长江中下游、内蒙及新疆之间依次存在着3年位相差。  相似文献   

First-Order Chemistry in the Surface-Flux Layer     

L. Kristensen  C. E. Andersen  H. E. Jørgensen  P. Kirkegaard  K. Pilegaard 《Journal of Atmospheric Chemistry》1997,27(3):249-269

We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O₃ and the radioactive ²²⁰Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of ²²⁰Rn from measured concentration profiles.  相似文献   

ICP—AES法同时测定高纯氧化钇中稀土及非稀土杂质元素方法研究     

吕宝源  裘丽雯 《高校地质学报》1997,3(1):106-110

本文提出了用ＩＣＰ－ＡＥＳ法直接同时测定高纯氧化钇中１４个稀土和１６个非稀土杂质元素的分析方法，对被测元素的 谱线、氧化钇基本及背景影响进行了研究，用标准加入法测出氧化钇基准中的微量杂质元素，消除了由于忽略基准中的杂质元素含量给高纯氧化钇分析测定带来的误差，同时对工作条件进行了优化。方法中各被测元素的检出限为0.003～1.31ug/g，能够满足生产过程中的质量控制及进出口商品检验  相似文献   

三峡库区生物多样性的变化态势及其保护对策   总被引：5，自引：0，他引：5  

章家恩  徐琪 《热带地理》1997,17(4):412-418

三峡库区拥有丰富的生镜多样性，物种多样性与基因多样性，是一个天然生物宝库，然而，由于人类活动长期的强烈干预和破坏，库区生境日趋退化，生物种群发生逆行演替，生物多样性在逐渐减少或丧失。加强对生物多样性保护和研究具有极其重要的现实意义。  相似文献