Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico     

Sergio Martínez-Trinidad  Gilberto Hernández Silva  Juventino Martínez Reyes  Gregorio Solorio Munguía  Sara Solís Valdez  Martha Elena Ramírez Islas  Rocío García Martínez 《Geofísica Internacional》2013,52(1):43-58

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.  相似文献   

天然水体中汞形态分析   总被引：1，自引：1，他引：0  

陈娟  余晓平  郭亚飞  邓天龙 《岩矿测试》2012,31(6):939-944

简要归纳了天然水体中汞形态分析的分离(萃取、吸附、电化学分离、色谱)及检测技术(分光光度法、原子光谱法、质谱法、电化学分析法),指出了未来针对痕量超痕量汞形态分析新技术主要集中在样品前处理和便携式在线现场分析,着重推荐高效、经济并具有广阔应用前景的液相色谱-氢化物发生原子荧光光谱( LC - HG - AFS)用于痕量超痕量汞形态分析.  相似文献   

湘黔汞矿带旋扭构造动力作用与成矿规律   总被引：1，自引：0，他引：1  

雷义均  戴平云  段其发  王国强  赵武强 《大地构造与成矿学》2012,36(4)

湘西黔东地区,在古生代沉积盖层中,北北东向保靖-铜仁断裂带的东侧,发育一系列北东向平移逆冲压扭性断裂构造带,它们均具有相似的变形特征和动力学机制,构成一个大型压扭性旋扭构造系统。旋扭构造控制了湘黔汞矿带的分布,其中北东向断裂带控制了汞矿带内各矿田的展布,而由北东向断裂带所派生的次级张扭性断裂裂隙带,则控制了单个矿体或矿床的产出和定位,特大型和大型汞矿床均产于旋扭构造的应力强区内。  相似文献   

金矿焙烧工艺生产处理液中汞测量不确定度的评定     

胡明  赵东阳  王忠伟 《吉林地质》2012,(3):98-100

本文针对原子荧光对金矿焙烧工艺生产中汞处理液的测定,找出了影响其测量不确定度的因素,建立了数学模型,计算出各不确定度的分量,求出合成标准不确定度及扩展不确定度。  相似文献   

原子荧光法测量痕量汞的预处理实验     

丁美婷 《吉林地质》2012,31(2):97-99

用原子荧光法测量地质样品中痕量汞,对两种不同的预处理方案进行了试验。通过国家一级地球化学标准物质中汞的测定,试验证实预处理时加入高锰酸钾的样品测量值更接近于标准值。  相似文献   

水汞观测资料对比分析     

陈其锋  赵杰锋  魏汝庆  李月强  冯恩国  连凯旋  崔娜  刘保华 《地震地磁观测与研究》2011,32(4):111-114

通过聊古一井井水中汞量的测定及对比观测试验,找到了影响数据内在质量的干扰因素,提出了浓硫酸、蒸馏水是干扰因素的主要来源,进行空白样的测定是排除干扰,提高观测资料内在质量的重要方法.  相似文献   

水浴消解-顺序注射-氢化物发生原子荧光光谱法测定铁矿石中砷和汞   总被引：2，自引：2，他引：0  

苏明跃  陈广志  王晶  姚传刚 《岩矿测试》2011,30(2):210-213

采用水浴加热低温消解浸取铁矿石样品,顺序注射-氢化物发生原子荧光光谱法测定铁矿石样品中砷和汞的含量.选择了消解试剂,研究了硼氢化钾浓度、载气流量、屏蔽气流量、溶液酸介质、载流、溶液酸碱比例、样品中的主要基体元素等因素对砷和汞测定的干扰,并确立了适宜的测定条件.砷浓度在0～100 μg/L与荧光强度呈良好的线性关系,砷的...  相似文献   

恒速压汞技术定量评价低渗透砂岩孔喉结构差异性   总被引：1，自引：0，他引：1  

高永利  张志国 《地质科技情报》2011,30(4):73-76

针对常规压汞不能准确确定储层孔隙与喉道的弊端,利用恒速压汞技术对鄂尔多斯盆地低渗透砂岩样品孔喉结构的差异性进行了定量评价.结果表明,渗透率越小的岩心,喉道分布越集中,随着渗透率的增大,大喉道分布逐渐增多,喉道分布范围也更加宽泛,主喉道半径随之增大,但较大喉道对低渗透砂岩储层的开采效果具有双重影响;渗透率小于0.5×10...  相似文献   

Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy     

Seunghee Han  Joris Gieskes  Anna Obraztsova  Dimitri D. Deheyn  Bradley M. Tebo 《Estuarine, Coastal and Shelf Science》2011

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.  相似文献   

膨胀土干湿循环过程孔径分布试验研究及其应用   总被引：5，自引：0，他引：5  

曾召田  吕海波  赵艳林  王志兵 《岩土力学》2013,34(2):322-328

采用压汞法对膨胀土干湿循环过程孔隙大小分布的演化规律进行了试验研究,结果表明,随着循环次数的增加,膨胀土的总孔隙体积、孔隙率和平均孔径等微结构参数均递增;分析了试验结果产生偏差的原因,其一是干湿循环过程中膨胀土试样的体积收缩,其二是孔隙形状和测试压力有限的影响,在此基础上对试验数据进行了合理修正。结合毛细管模型,利用修正的孔径分布曲线推算了膨胀土干湿循环过程中的土-水特征曲线,并分析了干湿循环过程中基质吸力的变化规律：以含水率28%为分界点,含水率大于该值时基质吸力随循环次数N的增加而线性递增,含水率小于该值时基质吸力随循环次数N的增加而线性递减;在此基础上,建立了基质吸力与循环次数之间的关系,为解释膨胀土力学特性的干湿循环效应开辟了一条新途径。  相似文献