塔里木盆地中高氮天然气的成因及其与天然气聚集的关系   总被引：2，自引：0，他引：2  

《沉积学报》2000,18(4)

塔里木盆地塔北和塔中地区的海相腐泥型天然气,N2含量较高,尤其是湿气,N2含量分布在10.1％～36.2％,而干气的N2含量则低于10％,即湿气的N2含量高于干气的N2含量。同是下古生界寒武－奥陶系来源的海相腐泥型天然气,为什么湿气和干气的氮气含量相差如此之大?根据与氮气相伴生的烃类气体、非烃气体及稀有气体的组份及同位素特征,认为塔里木盆地的中高氮天然气属于有机成因,来源于下古生界海相烃源岩。文章还提出塔北和塔中地区湿气和干气N2含量差异与源岩的演化程度和圈闭的捕获条件有关。  相似文献   

中国能源领域温室气体排放现状及减排对策研究   总被引：23，自引：5，他引：18  

齐玉春  董云社 《地理科学》2004,24(5):528-534

自工业革命以来,随着化石燃料的广泛应用,能源领域的温室气体排放逐渐成为其主要的人为排放源,能源、环境和经济发展之间的矛盾也日益成为各国政府共同关注的焦点。如何有效地进行能源活动中温室气体的减排已经成为涉及环境、经济、政治、外交等多方面的全球性科学问题。文章对中国能源开发利用现状和主要温室气体二氧化碳(CO₂)、甲烷(CH₄)、氧化亚氮(N₂O)能源排放源进行了简要分析,并对适合中国国情的温室气体减排与能源可持续开发与利用"双赢",实现"发展型减排"的有效途径进行了初步的探讨。  相似文献   

Does I = PAT Work in Local Places?     

Jennifer L. DeHart  Peter T. Soul 《The Professional geographer》2000,52(1):1-10

An aspect of global change currently not well understood is how processes operating on spatial scales finer than those used in recent global circulation models (GCMs) contribute to changes in atmospheric composition and the subsequent changes in climate. We use the ‘IPAT’ formulation as a framework to test relationships among social driving forces and user group greenhouse gas (GHG) emissions in northwestern North Carolina. Using regression, correlation, and bivariate mapping to examine relationships between a suite of socioeconomic variables and GHG emissions for the residential, commercial/industrial, and agricultural end‐user categories, we find that various measures of population and affluence serve equally well as explanatory variables.  相似文献   

温室气体的卫星遥感—进展与趋势     

刘毅  王婧  车轲  蔡兆男  杨东旭  吴林 《遥感学报》2021,25(1):53-64

二氧化碳和甲烷减排是控制全球增温最核心的手段,传统的人为碳排放计算主要依赖于在线监测和清单算法,2019年第49届1PCC全会明确了利用大气观测通过"自上而下"通量计算对排放清单进行支撑和验证,因此了解大气遥感碳监测发展趋势以及同化反演技术方法成为了中国应对国际气候变化事务亟待探明的重要问题.根据卫星遥感技术发展进程和...  相似文献   

复合体系有机气体氧化生成二次有机气溶胶研究进展          下载免费PDF全文

陈晓文  李坤  李建龙  杜林 《大气科学学报》2023,46(5):641-654

生物源与人为源有机气体氧化形成的二次有机气溶胶(SOA)对气候变化和人类健康具有重要影响。SOA的产生与其前体物研究已取得了一些进展,但由于有机气体之间存在复合相互作用以及SOA形成机制复杂,目前对不同有机气体混合体系中SOA的形成认知还比较匮乏。因此,深入了解有机气体多源、复杂的相互作用,摸清有机气体的大气氧化机制、SOA的形成及影响等对深入理解真实大气有机气体化学演变具有指导意义。本文旨在了解复合体系有机气体氧化生成SOA的相关研究进展。一方面总结了复合体系有机气体产生SOA质量浓度、产率、成分、挥发性、光学性质等的变化,侧重于实验室复合体系有机气体氧化对SOA形成的多重影响以及SOA组成元素、分子构成的变化特征,并总结了目前实验室基于模型对复合体系SOA生成的模拟研究和拟合情况;另一方面探究了环境因素,如相对湿度(RH)、温度(T)以及无机气体,如氮氧化物(NO_x)、二氧化硫(SO₂)、氨气(NH₃)等对复合体系有机气体形成SOA的影响。  相似文献   

川西坳陷南段天然气来源与碳同位素地球化学研究   总被引：8，自引：0，他引：8       下载免费PDF全文

樊然学  周洪忠  蔡开平 《地球学报》2005,26(2):157-162

川西坳陷南段是四川盆地主要的天然气产区之一。前人对该区天然气的来源有多种见解。为了更清楚地认识此地区天然气的来源与运移，本文分析了平落坝、大兴西和白马庙气田16件天然气样品的C1-C4烃及CO2组份的碳同位素组成。所获得的同位素数据结合化学成份和地质资料表明，3个气田的烃类完全是热解成因的，都来源于气田下面的上三叠统烃源岩。这些气田的甲、乙烷碳同位素组成随深度呈不同规律的变化，这些变化归因于烃源岩生烃的热解过程和烃类运移的动力学过程。平落坝气田中侏罗统气藏的烃类大部份形成于烃源岩低成熟和成熟的早期阶段并受到晚期成熟气体的不断补给。平落坝和大兴西气田多数气藏的烃类被认为是从源区垂直向上运移通过上伏地层而进入气藏的，白马庙气田的烃类被认为是沿断裂通道向上侏罗统气藏聚集的。平落坝和大兴西气田的δ^13Cco2值有很宽的分布范围(-10.7‰～-0.7‰)，这表明气田的CO2由来自基底的海洋碳酸盐岩无机碳成份和沉积地层的有机碳成份混合而成。这些气田的[He／CH4]-[N2／CH4]值之间和δ^13Cco2-δ^13Cc1值之间的相关性表明，非烃气体在进入气藏前已同烃类很好地混合，并被CH4为主流相的气流携带着向气藏运移。  相似文献   

Seep mounds on the Southern Vøring Plateau (offshore Norway)     

Michael Ivanov  Adriano Mazzini  Valentina Blinova  Elena Kozlova  Jan-Sverre Laberg  Tatiana Matveeva  Marco Taviani  Nikita Kaskov 《Marine and Petroleum Geology》2010

Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ¹³C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ¹⁸O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ¹⁸O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ¹³C (−31.6‰ to −59.2‰) and δ¹⁸O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time.  相似文献   

The importance of sewage effluent discharge in the export of dissolved organic carbon from U.K. rivers     

Fred Worrall  Nicholas J.K. Howden  Tim P. Burt  Rebecca Bartlett 《水文研究》2019,33(13):1851-1864

The flux of fluvial carbon from the terrestrial biosphere to the world's oceans is known to be an important component of the global carbon cycle, but within this pathway, the flux and return of carbon to the river network via sewage effluent has not been quantified. In this study, monitoring data from 2000 to 2016 for the dissolved organic carbon (DOC) concentration, biochemical oxygen demand, and chemical oxygen demand of the final effluent of sewage treatment works from across England were examined to assess the amount of DOC contributing to national‐scale fluvial fluxes of carbon. The study shows that the median concentration of DOC in final effluent was 9.4 compared with 4.8 mg C/L for all surface waters for the United Kingdom over the study period and that the DOC in final effluent significantly declined over the study period from 11.0 to 6.4 mg C/L. Rivers receiving sewage effluent showed a significant, on average 19%, increase in DOC concentration downstream of sewage discharges. At the scale of the United Kingdom, the flux of DOC in final effluent was 31 ktonnes C/year with a per capita export of 0.55 kg C/year and compared with an average annual flux of DOC from the United Kingdom of 859 ktonnes C/year, that is, only 3.6% of national‐scale flux. The lability of this DOC was limited, with only 7.4% loss of final effluent DOC concentration over in‐stream residence times of up to 5 days. The direct decline in DOC concentration from sewage treatment works was not large enough on its own to explain the declines observed in DOC concentration in U.K. rivers at their tidal limit.  相似文献   

Response of the Tropical Indian Ocean to Greenhouse Gases and Aerosol Forcing in the GFDL CM3 Coupled Climate Model     

Zhi Li 《大气与海洋》2018,56(1):40-54

The response of the tropical Indian Ocean (TIO) to greenhouse gases (GHGs) and aerosols are investigated based on historical single-forcing and all-forcing simulations using the Geophysical Fluid Dynamics Laboratory Climate Model, version 3 (GFDL CM3). Results reveal a positive Indian Ocean Dipole (pIOD)-like pattern in GHG forcing but a negative Indian Ocean Dipole (nIOD)-like pattern in aerosol forcing. The GHG-induced pIOD-like pattern features less (more) sea surface temperature (SST) warming over the southeastern (western) TIO, accompanied by equatorial easterly anomalies, as well as a shallower thermocline off Sumatra. The aerosol-induced nIOD-like pattern displays the reverse features, characterized by less (more) SST cooling over the southeastern (western) TIO, anomalous equatorial westerlies, and a deeper thermocline off Sumatra. Although the aerosol-induced pattern appears to resemble a reversal of the GHG-induced pattern, there is a strong asymmetry in the SST changes over the southeastern TIO, where the cooling responding to aerosol forcing exceeds the warming in response to GHG forcing, and a negative SST residual is thus produced. A mixed-layer heat budget analysis suggests that the negative SST residual results mainly from asymmetric responses of shortwave radiation, zonal advection, and diffusion to GHGs and aerosols. For comparison, the formation processes for the negative SST skewness over the southeastern TIO between the internal pIOD and nIOD are also discussed.  相似文献   

麦哲伦海山富钴结壳的稀有气体丰度及He、Ar同位素组成   总被引：3，自引：0，他引：3  

叶先仁  方念乔  丁林  张铭杰 《岩石学报》2008,24(1):185-192

使用MM5400质谱计对麦哲伦海山富钴结壳和结壳基岩进行稀有气体同位素分析,以此示踪结壳形成期间的海洋环境。富钴结壳的He、Ne、Ar、Kr、Xe稀有气体同位素丰度模式与ASW(air-saturated water,饱和空气的海水)的变化趋势一致,说明结壳是在与海水交换平衡的流体环境中形成的。结壳的分馏因子F_3比饱和空气的海水的F_3高2～3个数量级,表明其相对于海水而言是富集~3He的。其相对于空气亏损~3He、富集Kr和Xe的模式与高度富集~3He、亏损Kr和Xe的星际尘粒的模式完全不同,暗示地球外物质并不是支配富钴结壳稀有气体同位素丰度模式的主要因素。结壳中高的R值甚至超过上地幔代表MORB(大洋中脊玄武岩)的典型值8R_a(R_a为地球大气中~3He/~4He比值,R为样品中~3He/~4He比值),揭示了热点型地幔热液对西太平洋海洋环境的局部贡献。圈层结壳的各结壳层之间的R值差异明显,各结壳层之间的尺值的变化趋势是"较高→最高→较高",结壳中层具有高达15.60R_a的R值,明显有深部地幔流体的加入,这进一步表明滋养结壳生长的热液环境本质上是源于地幔柱型的热点热液。玄武质基岩具有较低的R值,说明该类基岩在形成时严重混染有地壳物质,也说明结壳的物源并非来自玄武质基岩。结壳的~(40)Ar/~(36)Ar比值接近于饱和空气的海水值,也表明结壳的成矿流体与周围海水发生了充分的交换。  相似文献