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151.
锚喷材料经时蠕变损伤本构方程   总被引:1,自引:0,他引:1  
从以应力,湿度,温度和损伤诸函数的时间积分表示和自由能涵函出发,根据非平衡热力学定律,同时考虑了喷射混凝土老化效应及骨料因素,给出了锚喷材料损伤蠕变本构方程和损伤演化方程,养护时间及蠕变有效作用应力的定义,并用实验结果验证了该理论。  相似文献   
152.
Sediment—Hosted Gold Deposits in China_geochemistry and Prospecting   总被引:1,自引:0,他引:1  
Sediment-hosted gold deposits are the major type of gold resources in china,Concen trated mostly in the two“Triangle Regios“,they are generally hosted in fine-clastic turbidite,hydrothermal chet and marl ranging from cambrian to Triassic in age,structurally controlled by domes,anticlines and second-ordered faults.They are similar to the Carlin-type gold deposits in mineral assemblage and geochemical marks,with an element association closely comparable to those of modern springs and submarine hydrothermal sediments.Organic matter may have played an important role in mineralization .The ore solution may be hydrothermally altered meteoric water developed i areas of local geothermal anomaly.  相似文献   
153.
The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository.

As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species.

In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated.

The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model.  相似文献   

154.
广州珠江西航道,流溪河有机污染特征与感潮作用   总被引:6,自引:3,他引:6  
珠江西航道和流溪河在广州市区上游,为广州市主要水源区。由于感潮作用,受市区严重污染的水体因涨潮上溯而上游传输。严重影响上游水质。因此,弄清感潮作用对广州水源区水质的影响程度和范围,对水源保护与利用有重要意义。本研究从下游到上游,对水源区底泥中有机物特征进行了分析,结果表明:(1)从上游到上游,受感潮作用影响逐渐减小,污染程度逐渐减轻;(2)水源区有机物特征呈有规律变化。从靠近城市的下游到远离城市的  相似文献   
155.
临沧超大型锗矿床有机质与锗矿化的地球化学特征   总被引:10,自引:3,他引:10  
庄汉平  刘金钟 《地球化学》1997,26(4):44-52,T002
临沧锗矿床是一产于第三系含煤岩系中的超大型矿床。矿床的最初锗源与盆地西缘的二云母花岗岩有关。主矿体产于下煤组沉积旋回的早期地层中,每一沉积阶段早期形成的褐煤和碳质泥岩中富含锗,最高含量达1470×10^-6。褐煤和碳质泥岩在矿化过程中平均富集了164-169倍。根据锗含量,褐煤和碳质泥岩可分为锗含量小于12×10^-6的低锗煤(泥岩)和大于90×10^-6的高锗煤(泥岩)。高锗煤中有机质富含氧官能  相似文献   
156.
The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.  相似文献   
157.
Organism relics or kerogens in oils are first obsenred by a confocal laser scanning microscope (CLSM) and a transmission electron microscope (TEM). The complexes of kerogens in oils are characterized by the presence of a great variety of microfossils or macerals. These kerogens in oils are mainly the residues of the original organic substances from which oil formed, and minor kerogens from enclosing rocks enter the oils, therefore, the components and types of the kerogens in crude oils can serve as an indirect indicator of oil-source rock correlation. This method was applied to Jurassic oils in the Junggar Basin and the Turpan-Hami Basin, and there are two types of the kerogens in oils: one containing a lot of macerals from terrestrial plants may derive from coals, and the other, characterized by a high content of microscopic algae, fungus spores and Acritarch, may originate from Permian organic matter. In addition, the reflectance of the vitrodetrinites in oils can be used as an indicator of oil-source rock correlation.  相似文献   
158.
民和盆地中侏罗统煤-油页岩层系生油特征   总被引:4,自引:0,他引:4  
本文简要论述了民和盆地中侏罗统含煤及油页岩层系的生油特征,探讨了盆地独特的石油地质和地球化学条件。原油主要地化特征为:Pr/Ph比值偏高(2.65-3.15)、甾烷/藿烷比值极低(0.03)、C27甾烷较丰富、Ts/Tm>1低硫芴/氧芴比值、较高含量的C29降新藿烷及重排藿烷类化合物及相对丰富的长链联苯及烷基四氢萘系列化合物。中侏罗统煤-泥页岩层系含生油潜力明显不同的多类型油页岩,多数油页岩属由藻类和陆生高等植物母质组成的混合型有机质,沉积环境为淡水-微咸水弱氧化条件,其地化特征也表现为高Pr/Ph比值(平均为1。98),低甾烷/藿烷及低硫芴/氧芴比值等特征。某些油页岩富含C29降新藿烷及重排藿烷系列化合物,它们应为主力源岩。油页岩多含再沉积型或沉积改造型有机质。异常地热作用对源岩演化及原油地化特征有重要影响。  相似文献   
159.
大港油田奥陶系碳酸盐岩生物标志化合物地球化学特征   总被引:5,自引:1,他引:5  
在本项研究中,根据Pr/Ph比值,β-胡萝卜烷类化合物丰度,甾/藿比值,单甲基高位取代支链烷烃,OEP值,升藿烷C3122S/(22S+22S)比值等参数,对大港油田奥陶系碳酸盐岩的地球化学特征作了详细的研究,该为该套地层只于弱氧化-弱还原条件下及经历了强烈的细菌改造。  相似文献   
160.
通过单轴抗压试验、剪切试验、变形试验及渗透性试验等方法,对旋喷固结体的物理力学性状和渗透性进行了研究。结果表明:旋喷固结体具有良好的物理力学性质和较低的渗透性,可完全改变天然土的性质。  相似文献   
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