中国东部寒武系与奥陶系界线地层的碳氧同位素研究   总被引：12，自引：0，他引：12  

沈渭洲  方一亭 《沉积学报》1997,15(4):38-42

对我国东部不同地层区一些代表性的寒武系-奥陶系界线层位开展了碳?氧同位素研究?结果表明,由于沉积环境差异和成岩蚀变影响,界线层位的δ18O值变化较大,规律性不明显,δ13C值变化虽小,但在界线处均发生不同程度漂移?漂移的层位与寒武纪-奥陶纪主要生物群面貌变化的界线相一致?综合各方面资料分析,笔者认为,碳同位素组成的漂移很可能由晚寒武世到早奥陶世时期内海平面的升降所引起.  相似文献   

地质速率计—矿物氧扩散的应用     

傅斌  郑永飞 《地球科学进展》1997,12(5):428-433

概述了同位素封闭体系内的矿物氧扩散和同位素交换机制及其在地质速率计上的应用。火成岩从高温冷却或变质岩从高峰主质温度冷却过程中，由于冷却速度不同，扩散作用导致的矿物晶体内部及晶粒间氧同位素再平衡也有所不同。通过实测岩石中各组成矿物氧同位素比值，模式含量和颗粒半径，据矿物氧扩散和同位素交换模型，可以估算出岩石的冷却速率。  相似文献   

Multicomponent ionic diffusion in porewaters: Coulombic effects revisited     

Bernard P. Boudreau  Filip J.R. Meysman 《Earth and Planetary Science Letters》2004,222(2):653-666

The diffusion of an ion in porewaters cannot occur independently of the other ions in solution as a result of Coulombic coupling, as well as from other effects not considered here. Unfortunately, a longstanding disagreement exists about the correct form and meaning of the equations that describe Coulombic coupling in porewaters, i.e., Ben-Yaakov [Am. J. Sci. 281 (1981) 974] vs. Lasaga [Am. J. Sci. 281 (1981) 981]. This paper re-examines this controversy by reformulating the problem starting from fundamental concepts of mass and charge conservation. We show that these antagonistic formulations are both valid and, in fact, equivalent, when the different interpretations of charge balance are resolved. Most of the disagreements between Ben-Yaakov and Lasaga are then shown to result from differing methods of solution, not fundamental disparities in their models. We note, however, that the explanation for the concept of “stationary” gradients of nonreacting ions as given Ben-Yaakov is inaccurate, and such gradients do lead to diffusive fluxes that are counterbalanced by electrochemical migrational fluxes to produce no net flux (excluding advective flux). We further find that the bicarbonate diffusive flux will not balance the diffusional charge flux of sulfate during its reduction if advection is present. This latter imbalance generates compensating fluxes in the other nonreacting ions. We have applied our theory to a simplified case of sulfate reduction in a marine sediment. The results show that nonreacting ions do diffuse and that with normally expected values of porewater advection, the ratio of the bicarbonate to the sulfate flux can be far different than the ideal value of −2.  相似文献   

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea     

C.A McCammon  T Stachel 《Earth and Planetary Science Letters》2004,222(2):423-434

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.  相似文献   

用混合和扩散云室对大气冰核浓度的观测分析   总被引：3，自引：0，他引：3  

杨绍忠  王祥国  游来光  皮家雄 《气象》2004,30(12):39-43

继1963年用混合云室对春季冰核浓度观测之后，1994～1996年，在同季节、同地点用混合和静力扩散云室又做了同步观测。对取得的资料进行整理分析，得出了凝华核浓度在不同天气背景下占总冰核浓度的百分比，两种云室测值的对应关系；分析了扩散云室的容积效应及冰核浓度随气压、能见度等气象因子的变化。  相似文献   

煤层气在煤储层中的扩散及其影响因素   总被引：4，自引：0，他引：4  

曹成润  牛伟  张遂安  霍永忠  陈秀艳  孙英男 《世界地质》2004,23(3):266-269

煤层气在煤储层中的扩散是指从煤基质孔隙表面上解吸的煤层气运移到割理系统的主要过程。发生扩散的前提条件是气体浓度差的出现，衡量扩散能力大小的重要参数是扩散系数。前者为由解吸速度、解吸气量和煤层气产量、井孔压力降等因素控制的动态参数，而后者为主要受扩散物质性质、扩散介质特征、扩散系统的温度、压力和孔隙结构形态等因素影响的静态参数。煤层气在煤储层中的扩散量与煤层气浓度差和扩散系数呈正比关系。  相似文献   

时域瞬变场电磁场有限差分法   总被引：1，自引：2，他引：1  

徐凯军  李桐林 《世界地质》2004,23(3):301-305

模拟电磁场在地下介质中的传播规律是理解地下介质响应的重要手段，直接应用有限差分法在时间域对二维、三维瞬变场进行数值分析是一种有效方法。应用反映电磁场基本规律的麦克斯韦方程组，导出时域场量的齐次扩散方程，对所研究的空间区域作差分离散，源作为初始条件加入，采用合适的边界条件，利用差分方程进行计算，从而得到场量的数值结果，展现瞬变场在地下随时间扩散的全过程，对电磁场的瞬态响应有更加直观的了解。  相似文献   

吉林市第二松花江江段污染物-NH4+分布特征研究     

肖长来  兰盈盈  梁秀娟  盛洪勋  刘耀莹  王德成 《世界地质》2004,23(4):382-385,396

针对吉林市铁合金厂排污口下游江水的污染情况，设计研究江段，分段、分层取样。通过野外与室内实验，分析研宄了江水污染物的主要成分，并对NH4^ 的纵向、横向、垂向上的分布特征及其影响因素进行了详细研究。结果表明，垂直方向污染物扩散可以瞬时完成，在极短的时间内基本能达到完全混合；在横向和纵向上，岸边排放污染物一般只在近岸扩散，污染范围一般也只在靠近排污口一带；随着离排污口距离增大，污染物浓度降低，横向变化率较纵向大。本研究为排污口的污染物控制与治理、水资源保护提供了科学依据。  相似文献   

水质大涡模拟数学模型研究   总被引：2，自引：0，他引：2       下载免费PDF全文

张昌兵  熊朝坤  桂林  刘华  莫政宇 《水科学进展》2004,15(4):431-435

建立了基于弱可压缩流基础上的水质大涡模拟数学模型及污染物质扩散系数与平均运动的关系。数值计算采用有限体积法和预测校正法,固壁边界条件采用"部分滑移条件"。并应用该模型对重庆嘉陵江、长江两江交汇段的流场,污染物质浓度分布进行了计算,计算结果与实测值比较吻合。研究表明,横向扩散与流动状态有关,当支流流量相对较小时,横向扩散较弱,形成岸边污染带,当支流流量相对较大时,横向扩散较强,污染带向江心移动。  相似文献   

Iron-Titanium Oxide Geothermometry and Petrogenesis of Lava Flows and Dykes from Mandla Lobe of the Eastern Deccan Volcanic Province, India     

Mansoor Ahmad  J.P. Shrivastava   《Gondwana Research》2004,7(2):563

Compositional studies on different forms of magnetite, ulvospinel, ilmenite and hematite mineral phases occurring in 37 lava flows and 6 dykes of the Mandla lobe are presented in this paper. Ilmenite (0001) in equilibrium with titanomanetite show high values of temperature of equilibration, ranging from 1172–974°C, for high alumina quartz normative tholeiitic lava flows of Chemical Type - A; 1129–1229°C for low alumina quartz normative tholeiitic lava flows of Chemical Type - B; 1283–1124°C for tholeiitic lava flows of Chemical Type - F and 1243°C and 99O°C for two diopside olivine normative tholeiite flows of Chemical Type D. High olivine normative flows of Chemical Type - G and H show 1095°C and 1092°C respectively. Whereas, high hypersthene normative tholeiite flow of Chemical me C shows temperature of 1187°C. Data plots disposition over iron-titanium oxide equilibration temperature vs – logfo₂, diagram for Mandla lava flows and other parts of the Deccan (Igatpuri, Mahabaleshwer, Nagpur and Sagar areas) revealed that tholeiitic (evolved) basalt of the eastern Deccan volcanic province formed at high temperatures whereas, picritic (primitive) lavas of Igatpuri and tholeiitic basalt of Mahabaleshwar areas were formed at low temperatures. Mahabaleshwer basalts follow FMQ (fayalite-magnetite-quartz) buffer curve but, plots of the Mandla basalts lie above this curve indicating higher temperatures of crystallisation of ilmenite-titanomagnetite than that of the lava flows from other parts of Deccan 'Raps. The eastern Deccan Traps are most evolved types of lava as characterised by its low Mg-number and Ni content whereas, Igatpuri lava flows are picritic (primitive), having high Mg-number and Ni contents. Temperature vs FeO + Fe₂O₃ / FeO + Fe₂O₃ + MgO ratio data plots for Mandla and other Deccan lava flows and liquidus data for Hawaiian tholeiites, indicated that Igatpuri basalts lie parallel to the liquidus line of Hawaiian tholeiite but at lower temperatures. Large data plots of Mandla lava flows lie along the liquidus line of the Hawaiian lava. The highly vesicular nature of compound lava flows having large amount of volatile is responsible for low temperature values whereas, lava flows represented by high temperatures show high modal values of glass and opaque minerals.  相似文献