Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga     

Yasuhiro KATO  Takashi KANO  Keitaro KUNUGIZA 《Resource Geology》2002,52(2):101-110

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.  相似文献   

Recycling in the Puerto Rican mantle wedge, Greater Antilles Island Arc     

Wayne T. Jolly  Edward G. Lidiak  Alan P. Dickin  Tsai-Way Wu 《Island Arc》2002,11(1):10-24

Abstract The initial volcanic phase of Cretaceous island arc strata in central Puerto Rico, at the eastern end of the extinct Greater Antilles Arc, comprises a 6‐km thick pile of lava and volcanic breccia (Río Majada Group). Preserved within the sequence is a conspicuous shift in absolute abundances of the more incompatible elements, including Th, Nb, and the light rare earth elements (LREE: La, Ce, Pr and Nd). The compositional shift is marked by a decrease in La/Sm from averages of 2.11 in the lowest third of the pile (Formation A) to 1.48 at the top (Formation C), and by a distinctive flattening of LREE segments of chondrite‐normalized REE patterns. i⁸⁷Sr/⁸⁶Sr and ?_Nd average about 0.7035 and 8.2, respectively, in early Formation A basalts. These ranges normally overlap samples from later Formations B and C. Isotope compositions of the latter group are more variable, however, and several samples are considerably more radiogenic than Formation A basalts, such that i⁸⁷Sr/⁸⁶Sr averages almost 0.7042 while ?_Nd‐values decrease to 7.5 in Formation B and C basalts. Theoretical models of non‐modal melting processes in both amphibole peridotite and spinel lherzolite sources provide insight into the origin of depleted Th, Nb, and LREE abundances in Puerto Rican basalts. Low Nb concentrations less than normal mid‐oceanic ridge basalts in Formation A basalts indicate the wedge was slightly depleted by low‐volume decompression fusion due to induced convection in the back‐arc region prior to entry of the source into the arc melting zone. However, depleted patterns in Formation C basalts cannot be generated by relatively greater degrees of decompression fusion in the back‐arc, because addition of the La‐enriched slab‐derived component to more depleted source material invariably produces elevated rather than decreased La/Sm. Refluxing of Formation A harzburgitic residua is similarly precluded. In contrast, the observed patterns are readily reproduced by multistage melting models involving hybridized sources containing normal Formation A lherzolite source material blended with recycled, unrefluxed harzburgite residua. Successful models require hybrid sources containing large volumes of recycled harzburgite (up to 50%) during generation of Formation C basalts. Slightly elevated radiometric Sr and Nd isotopes in a few flows from Formation C are attributed to partial refluxing of the hybrid sources within the wedge.  相似文献   

Effective stress analyses of liquefaction-induced deformation in river dikes   总被引：3，自引：0，他引：3  

O. Ozutsumi  S. Sawada  S. Iai  Y. Takeshima  W. Sugiyama  T. Shimazu 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1075-1082

A series of effective stress analyses is carried out on the seismic performance of river dikes based on the case histories during the 1993 Hokkaido-Nansei-oki and 1995 Hyogoken-Nambu earthquakes in Japan. Seven case histories selected for the analyses involve a crest settlement ranging from none to 2.7 m in the dikes 3–6 m high with evidence of liquefaction at foundation soil. The effective stress model used is based on a multiple shear mechanism and was developed by one of the authors. The soil parameters are evaluated based on the site investigation and laboratory test results. The results of the analyses are basically consistent with the observed performance of the river dikes. In particular, the effective stress model shows a reasonable capability to reproduce the varying degree of settlements depending on the geotechnical conditions of foundation soils beneath the dikes. The analyses also indicate that the effect of a cohesive soil layer mixed with the liquefiable sand layers beneath the dikes can be a primary factor for reducing the liquefaction-induced deformation of dikes.  相似文献   

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique     

Moon Kyum Kim  Yun Mook Lim  Seong Yong Cho  Kyung Hwan Cho  Kang Won Lee 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1151-1158

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.  相似文献   

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析     

李慧峰  张玉蓉 《地震研究》2002,25(1)

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架  相似文献   

Models of passive margin inversion: implications for the Rhenohercynian fold-and-thrust belt, Belgium and Germany     

Y Vanbrabant  J Braun 《Earth and Planetary Science Letters》2002,202(1):15-29

Positive tectonic inversion is related to the transmission of compressional stresses along a décollement into the foreland of an orogenic zone. This stress and strain concentration in regions remote from the main orogenic front is commonly related to the presence of pre-existing rheological heterogeneities such as normal syn-depositional faults. During inversion, these pre-existing normal faults are reactivated as reverse faults. Tectonic inversion in the Rhenohercynian fold-and-thrust belt during the Variscan Orogeny shows that inversion is likely synchronous with the onset of collision in the hinterland. Here, we present the results of a simplified thermo-mechanical model (STM) which allows one to study strain partitioning between two orogenic zones. We show that, if the two orogenic zones have the same mechanical properties, the viscosity of the décollement, which links them, controls the initial strain partitioning. During subsequent finite shortening, erosional processes determine the partitioning of strain rate. The presence of a weak structure in the inverted zone and of a low-viscosity décollement leads to initial strain concentration in the inverted track rather than in the collision zone and a progressive decrease in strain partitioning between the two orogenic zones. The STM results are in good agreement with results of a 2D finite-element model. We conclude that, in the western part of the Rhenohercynian Massif, simultaneous uplift and deformation within the Mid-German Crystalline Rise (the main collision zone) and the Ardenne Anticlinorium (the inverted zone) lead to interpreting this orogenic event as a case of vice tectonic rather than the propagation of a ‘wave of folding’ towards the Variscan front, as suggested by previous authors.  相似文献   

A finite‐element algorithm for electromagnetic induction in two‐dimensional anisotropic conductivity structures     

Yuguo Li 《Geophysical Journal International》2002,148(3):389-401

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The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3     

R. W. White  Roger Powell  G. L. Clarke 《Journal of Metamorphic Geology》2002,20(1):41-55

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.  相似文献   

A 3-D finite-element algorithm for DC resistivity modelling using the shifted incomplete Cholesky conjugate gradient method     

Xiaoping Wu 《Geophysical Journal International》2003,154(3):947-956

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层控夕卡岩型矿床成矿系统的元素活动性及质量迁移--以铜陵冬瓜山铜矿床为例   总被引：7，自引：0，他引：7  

凌其聪  刘丛强 《矿物学报》2003,23(1):37-44

应用改善了的质量平衡方程研究冬瓜山层控夕卡岩型铜矿床成矿系统的元素活动性及质量迁移，结果表明：系统中Zr,Hf,Y和Nb为不活动元素，其余均为活动元素。主量元素中仅CaO为迁出组分，其质量迁移量为84％，其余均为带入组分，带入量最大的SiO2的质量迁移量高达2384％；稀土元素均为带入组分，其中，中稀土较轻稀土和重稀土的活动性更强；其它微量元素中，带入序列由强到弱为：Cr→Ta→Sn→Th，迁出序列由强至弱依次为：U→Sb→Ni—Sr→Ba→Bb→Co→W；成矿元素Cu和Ag为带入组分，其中Cu的带入量最大，质量迁移量高达1200％。本文还得出两点具普适性认识：①稀土元素较其它微量元素对体系条件的变化更为敏感，且往往表现出明显的规律性变化，能更好地示踪地质地球化学过程。②不同元素在不同体系中的行为特征差异极大，仅凭经验判定某一元素为不活动元素往往不可靠。因此，在开展质量平衡研究时，首先采用适当方法确认体系的不活动元素是一项不可或缺的前提工作。  相似文献