石油中饱合烃类的喇曼特征   总被引：6，自引：0，他引：6  

张鼐  宋孚庆  王汇彤 《矿物岩石地球化学通报》2006,25(1):33-36

本文试通过一些饱合烃类标样的喇曼分析,总结出石油中饱和烷烃组分的最大喇曼特征是在2700~2970 cm-1区域有一系列强烈的喇曼效应,有三种情况:1)直链烷烃类是以—CH3链基对称喇曼效应(约2872 cm-1)最强;2)带异构骨架链烷烃类是以—CH链基喇曼效应(约2911 cm-1)最强;3)环烷烃类是以—CH2链基对称喇曼效应(约2857 cm-1)最强。另外异构骨架在748 cm-1处有一强的喇曼效应,烷烃环基在804 cm-1处有一个强的喇曼效应。并发现不同的烃或烃混合物,若结构基团相同,喇曼谱图也相同;在混合烃组分(或烃类包裹体)的喇曼谱图中2905~2921 cm-1间喇曼峰应是—CH基团,而不能单作甲烷存在的证据。  相似文献   

油气包裹体在油气地质研究中的应用--概念、分类、形成机制及研究意义   总被引：18，自引：1，他引：17  

潘立银  倪培  欧光习  丁俊英 《矿物岩石地球化学通报》2006,25(1):19-28

油气包裹体己成为油气成藏研究的有力工具,在划分油气运移充注期次、确定油气藏的形成时间、反映油气的成熟度及来源等方面均有重要的应用价值。近年来,利用油气包裹体及其共生的盐水溶液包裹体估算油气藏形成时的pVT条件是油气包裹体研究中的一个新热点,它为更准确地计算油气藏形成的温度一压力条件提供了一种独立的、更准确的技术手段。研究表明,包裹体岩相学和流体体系的热力学研究仍将是今后的发展重点。油气包裹体的pVT模拟技术尚处于初始阶段,两种软件（VTFlinc和FIT）的准确性和精确性虽有待进一步提高,但已经成为今后一个重要的发展方向。  相似文献   

塔里木盆地西北缘二叠系礁灰岩的时空分布特征及其油气地质意义   总被引：3，自引：0，他引：3  

罗金海车自成  周新源李勇李建立  张敬艺 《地质论评》2007,53(5):600-607

对塔里木盆地西北缘二叠系礁灰岩的岩石、岩相、沉积演化和油气地质特征的分析表明,生物礁主要发育于中二叠统栖霞阶昆克拉契组和巴立克立克组,以亮晶藻粘结灰岩为主,具有堤礁的特点。二叠系礁灰岩较大的厚度表明,当时礁体生长速率与礁基沉降（或水体加深）的速率匹配较好,具有进积型沉积的特点,这与当时塔里木地块内部的退积型沉积特点是不一致的。礁灰岩的原生孔隙较小,可以作为中等烃源岩,在哈拉峻盆地的东南侧和乌什凹陷北缘的覆盖区之下可能构成与礁灰岩相关的油气远景区。  相似文献   

王家岗断阶带含烃流体的成藏效应分析     

鲍晓欢  郝芳  方勇 《地质科技情报》2007,26(1):77-81

王家岗断阶带及其附近地区地层和地层流体所表现出的能量场和物质两方面的成藏效应,反映其局部地区的油气运移具有瞬态流体流动的特点.在以断层活动为主、以烃源岩超压为辅的双重控制作用下,来自牛庄洼陷内深部烃源岩的超压含烃热流体沿断阶带内的断层向王家岗地区方向快速充注.能量场上,快速的大规模流体流动既引起了地温场的局部扰动,也将深层的超压能量传递到浅层.物质上,溶解有大量矿物质的深部热流体以混相涌流的方式运移到浅层.流体活动强的断层附近区域水-岩相互作用强烈,地层岩石中的碳酸盐质量分数和黏土矿物组成变化较大.同时在深部流体进入浅层活动活跃的层段内,地层水矿化度高的地段聚集的油气也较多.  相似文献   

复垦土地样品中石油类物质加速溶剂萃取-荧光分光光度法分析方法研究     

赵江华  王鹏  黎卫亮  李忠煜 《岩矿测试》2021,(3):375-383

作为土地环境质量的一项重要指标,石油类物质含量决定了土地的用途.对于复垦土地样品,在一定程度上反映了污染土地的复垦、治理效果.土壤样中的石油类物质测定方法主要有气相色谱法、红外分光光度法、紫外光谱法等.气相色谱法主要应用于测定样品中的饱和烷烃;红外分光光度法通过测定不同波数下的特征吸收值来表征样品中石油类物质,但采用四...  相似文献   

Seismic imaging of deep hydrocarbon reservoirs     

J. J. O'Brien  I. Lerche 《Pure and Applied Geophysics》1988,127(1):33-61

This paper examines those aspects of reflection seismology which require special consideration when imaging deeper hydrocarbon reservoirs, including the constraints imposed by vertical resolution, lateral resolution, and velocity analysis. We derive quantitative expressions relating the uncertainties in stacking velocities and in interval velocities derived from stacking velocities to acquisition parameters, as well as expressions for the lateral resolution which can theoretically be achieved for migrated seismic images. This analysis shows that the most significant limitations of seismic imaging at depth involve the finite lateral resolution of the seismic method, and the proper lateral positioning of seismic images. These difficulties are overcome in large measure through the proper migration of a seismic dataset, which becomes more critical as deeper horizons are imaged. If these horizons are suspected of having significant 3-D structure, a strong argument may be made for acquiring a 3-D seismic survey over the prospect. Migration of this dataset will then generate an image of the subsurface with good lateral resolution in both the X and Y directions.  相似文献   

World oil: Hotelling depletion or accelerating use?     

Duane Chapman 《Natural Resources Research》1993,2(4):331-339

In theoretical Hotelling-type models of resource depletion, oil use declines monotonically over time to depletion. However, world oil use has been increasing for several years. Can theory and reality be reconciled? The answer is affirmative, if theory is modified to accommodate outward-shifting demand functions that are rising in response to growth in world population and income. Under this assumption, a Hotelling depletion model projects a 50-year period of increasing world oil use before the decline to exhaustion. This holds for both competitive and monopolistic regimes. Hotelling theory has been criticized by Adelman and others, in part because of the unreality of the theoretical projections. By combining the modified Hotelling theory with U.S. Geological Survey resource estimates, the numerical projections seem congruent with Adelman's near-term expectations. Finally, a backstop technology, such as renewable biomass ethanol, introduces a new dimension. Assuming a $2-per-gallon cost for the ethanol, the modified Hotelling theory projects accelerating use of conventional oil until depletion or substitution. Consequently, it does not seem unreasonable to believe that a finite, limited resource of conventional oil is consistent with growing use for several decades. A projected exhaustion in 100 years is consisten with increasing use for 50 years.  相似文献   

从第55届EAEG年会看勘探地球物理发展方向     

李金铭 《地球物理学进展》1994,9(3):45-50

本文根据笔者在第５５届ＥＡＥＧ会议期间了解到的情况，对勘探地球物理在石油能源、固体矿产、水文地质、工程地质和环境地质等领域的进展作了综述，指出了今后的重点研究课题和发展方向。  相似文献   

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids     

J. Albaigés  J. Borbón  W. Walker 《Organic Geochemistry》1985,8(4):293-297

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.  相似文献   

Organic geochemical studies of a recent Inner Great Barrier Reef sediment—I. Assessment of input sources     

Philip M. Shaw  R.B. Johns 《Organic Geochemistry》1985,8(2):147-156

The concentration of solvent-extractable (SE) and bound hydrocarbons, ketones, alcohols, sterols, monocarboxylic acids, hydroxyacids and α,ω-dicarboxylic acids of a surface sample (0–2.5 cm) from a recent carbonate tropical sediment taken at 60ft (18m) depth north-west of the Low Isles, North Queensland, are reported in detail. n-Alkanes are a minor constituent in the SE and bound hydrocarbon fractions with the major component being unresolved complex hydrocarbon material which is not an anthropogenic input. 6,10,14-Trimethylpentadecan-2-one derived from chlorophyll, as well as phytol, were identified as major components of the ketone and alcohol constituents. No chlorophyll pigments or pigmented degradation products were present, implying degradation before incorporation into the sediment. This conclusion is consistent with evidence for higher-plant input in which all sensitive lipids have been degraded before incorporation. SE and bound fractions have been studied in detail and show considerable differences probably arising from the importance of viable biomass in the SE fraction. Inputs to the sediment are determined as higher plants, algae, bacteria, fungi and meiofauna in descending order of importance.  相似文献