中国环境化学研究进展     

高国伟  陈锦凤 《云南地理环境研究》2005,17(5):92-96

通过对近年来中国环境化学学科中的环境分析化学、土壤环境化学、水环境化学、大气环境化学和污染生态化学5个大方面研究现状的详细介绍和评述,分析了中国环境化学基础性研究的进展,归纳总结了中国环境化学中已取得的成果及相关的应用,同时通过对目前一些国际上较热门研究内容及研究方向的讨论,指出了中国环境化学学科发展中存在的问题和不足,并对部分相关前沿领域的研究提出了建议。  相似文献   

兰州市2001年沙尘气溶胶质量浓度的特征分析   总被引：11，自引：14，他引：11  

权建农  奚晓霞  王鑫  李杰  张镭 《中国沙漠》2005,25(1):93-97

 分析了2001年沙尘暴期间兰州与靠近沙尘源区的武威的沙尘浓度和粒径分布特征,并运用对数正态分布规律拟合了沙尘粒径的分布。通过对比武威、皋兰和兰州沙尘暴期间沙尘浓度的变化以及武威与兰州的沙尘粒径分布特征,揭示了河西走廊沙漠对兰州市沙尘暴的影响。  相似文献   

甘肃春季(3～5月)沙尘暴成因分析   总被引：3，自引：7，他引：3  

郭慧  王式功  李栋梁  冯建英  陆登荣  张存杰 《中国沙漠》2005,25(3):412-416

甘肃春季(3～5月)沙尘暴小波变换分析清楚地反映了甘肃春季沙尘暴不同时间尺度周期振荡的交替作用。甘肃中西部自20世纪80年代以来变暖,其变暖与太阳黑子周期长度(SCL)密切相关。甘肃春季沙尘暴与甘肃中西部热力因子和降水研究表明,当冬季冷空气活动频繁,春季气温回升快,气温波动幅度大,降水偏少,甘肃春季容易发生沙尘暴。  相似文献   

松花江上游地区汞污染的化学生态效应   总被引：5，自引：0，他引：5  

王宁  朱颜明  朴明玉  孟丹 《地理科学》2005,25(6):737-741

采样分析了吉林省东部松花江上游金矿开采区及其附近水、土壤、动植物及河流沉积物样品中汞的含量，发现河流沉积物中汞的污染相当严重；受其影响当地的植物和两栖类动物——中国林蛙体内总汞和甲基汞含量也明显高于对照组。实验表明，林蛙内脏对汞的富集能力大于肌肉；秋季对汞的富集大于春季；河流沉积物中甲基汞的含量与林蛙体内甲基汞的含量有较好的正相关。汞污染的来源与区域内个体金矿的滥采滥排有直接关系，表明人类活动所产生的有毒重金属在地表过程中出现了化学生态效应。  相似文献   

中国陆地净初级生产力的季节变化研究   总被引：22，自引：1，他引：22  

崔林丽  史军  唐娉  高志强 《地理科学进展》2005,24(3):8-16

了解不同季节陆地净初级生产力(NPP)的变化及与气候的相互关系以及在不同地类的差异对深刻理解我国陆地生态系统对全球气候变化的响应和陆地碳循环研究具有重要意义。本文使用1981～2000年间GLO-PEM模型模拟的我国陆地NPP数据和同期气温、降水以及土地利用数据, 研究不同季节我国陆地植被NPP的变化。结果表明,在1981～2000年期间,四个季节的NPP都呈显著增加趋势,春季是NPP增加速率最快的季节,夏季是NPP增加量最大的季节。耕地在春、夏和秋季NPP增长和增长率最高,林地冬季NPP增长最多而水域冬季NPP增长率最高。夏季NPP增长最高的区域分布于我国东部的多数地区、内蒙古东部、四川盆地、贵州东部、藏南和新疆西部;夏季NPP降低最多的区域分布于在呼伦贝尔高原、鄂尔多斯高原、黄土高原、青藏高原东部和新疆西北部。  相似文献   

Refined modeling and movement characteristics analyses of irregularly shaped particles          下载免费PDF全文

Y. W. Zeng  L. Jin  X. Du  R. Gao 《国际地质力学数值与分析法杂志》2015,39(4):388-408

Irregularly shaped (IRS) particles widely exist in many engineering and industrial fields. The macro physical and mechanical properties of the particle system are governed by the interaction between the particles in the system. The interaction between IRS particles is more complicated because of their complex geometric shape with extremely irregular and co‐existed concave and convex surfaces. These particles may interlock each other, making the sliding and friction of IRS particles more complex than that of particles with regular shape. In order to study the interaction of IRS particles more efficiently, a refined method of constructing discrete element model based on computed tomography scanning of IRS particles is proposed. Three parameters were introduced to control the accuracy and the number of packing spheres. Subsequently, the inertia tensor of the IRS particle model was optimized. Finally, laboratory and numerical open bottom cylinder tests were carried out to verify the refined modeling method. The influence of particle shape, particle position, and mesoscopic friction coefficient on the interaction of particles was also simulated. It is noteworthy that with the increase of mesoscopic friction coefficient, the fluidity of IRS particle assembly decreases, and intermittent limit equilibrium state may appear. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada          下载免费PDF全文

J. Gordon  W. Quinton  B. A. Branfireun  D. Olefeldt 《水文研究》2016,30(20):3627-3638

In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

A multi‐proxy record of changing environments from ca. 30 000 to 9000 cal. a BP: Onepoto maar palaeolake,Auckland, New Zealand     

Paul Augustinus  Donna D'costa  Yanbin Deng  Joseph Hagg  Phil Shane 《第四纪科学杂志》2011,26(4):389-401

We present a high‐resolution record of lacustrine sedimentation spanning ca. 30 000 to 9000 cal. a BP from Onepoto maar, northern North Island, New Zealand. The multi‐proxy record of environmental change is constrained by tephrochronology and accelerator mass spectrometric ¹⁴C ages and provides evidence for episodes of rapid environmental change during the Last Glacial Coldest Period (LGCP) and Last Glacial–Interglacial Transition (LGIT) from northern New Zealand. The multi‐proxy palaeoenvironmental record from Onepoto indicates that the LGCP was cold, dry and windy in the Auckland region, with vegetation dominated by herb and grass in a beech forest mosaic between ca. 28 500 and 18 000 cal. a BP. The LGCP was accompanied by more frequent fires and influx of clastic sediment indicating increased erosion during the LGCP, with a mid‐LGCP interstadial identified between ca. 25 000 and 23 000 cal. a BP. Rapid climate amelioration at ca. 18 000 cal. a BP was accompanied by increased terrestrial biomass exemplified by the expansion of lowland podocarp forest, especially Dacrydium cupressinum. Increasing biomass production is reversed briefly by LGIT perturbations which are apparent in many of the proxies that span ca. 14 000–10 500 cal. a BP, suggesting generally increased wetness and higher in situ aquatic plant productivity with reduced terrestrial organic matter and terrigenous detrital influx. Furthermore, conditions at that time were probably warmer and frosts rare based on the increasing importance of Ascarina. The subsequent early Holocene is characterised by podocarp conifer forest and moist mild conditions. Postglacial sea‐level rise breached the crater rim and deposited 36 m of estuarine mud after ca. 9000 cal. a BP. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Fracture mechanics analysis of multiple cracks in anisotropic media     

Chia‐Huei Tu  C.‐S. Chen  T.‐T. Yu 《国际地质力学数值与分析法杂志》2011,35(11):1226-1242

This paper presents a single‐domain boundary element method (BEM) for linear elastic fracture mechanics analysis in the two‐dimensional anisotropic material. In this formulation, the displacement integral equation is collocated on the un‐cracked boundary only, and the traction integral equation is collocated on one side of the crack surface only. A special crack‐tip element was introduced to capture exactly the crack‐tip behavior. A computer program with the FORTRAN language has been developed to effectively calculate the stress intensity factors of an anisotropic material. This BEM program has been verified having a good accuracy with the previous researches. Furthermore, by analyzing the different anisotropic degree cracks in a finite plate, we found that the stress intensity factors of crack tips had apparent influence by the geometry forms of cracks and media with different anisotropic degrees. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Semi‐analytical solution to one‐dimensional consolidation for unsaturated soils with semi‐permeable drainage boundary under time‐dependent loading          下载免费PDF全文

L. Wang  D. A. Sun  A. F. Qin  Y. F. Xu 《国际地质力学数值与分析法杂志》2017,41(16):1636-1655

This paper presents semi‐analytical solutions to Fredlund and Hasan's one‐dimensional consolidation of unsaturated soils with semi‐permeable drainage boundary under time‐dependent loadings. Two variables are introduced to transform two coupled governing equations of pore‐water and pore‐air pressures into an equivalent set of partial differential equations, which are easily solved by the Laplace transform. The pore‐water pressure, pore‐air pressure and settlement are obtained in the Laplace domain. Crump's method is adopted to perform the inverse Laplace transform in order to obtain semi‐analytical solutions in time domain. It is shown that the present solutions are more general and have a good agreement with the existing solutions from literatures. Furthermore, the current solutions can also be degenerated into conventional solutions to one‐dimensional consolidation of unsaturated soils with homogeneous boundaries. Finally, several numerical examples are provided to illustrate consolidation behavior of unsaturated soils under four types of time‐dependent loadings, including instantaneous loading, ramp loading, exponential loading and sinusoidal loading. Parametric studies are illustrated by variations of pore‐air pressure, pore‐water pressure and settlement at different values of the ratio of air–water permeability coefficient, depth and loading parameters. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献