How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?     

Thomas Striebel  Wolfgang Schäfer  Stefan Peiffer 《Aquatic Sciences - Research Across Boundaries》1991,53(4):346-366

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.  相似文献   

容量法测定水样中硫酸根     

刘汉初  倪桃英 《岩矿测试》1991,10(2):123-124

本文对EDTA滴定过量Pb间接测定SO_4~(2-)的方法作了改进。加入乙醇抑制PbSO_4沉淀的溶解,使滴定不需分离沉淀而直接进行。用六次甲基四胺调节控制pH为5.2—5.4,可避免大量共存Ca~(2+)、Mg~(2+)的干扰。改进后的方法简单、快速,准确度和精密度均好,可适用SO_4~(2-)含量高于1mg/L的天然水分析。  相似文献   

The effect of gas-phase chemistry on aqueous-phase sulfur dioxide oxidation rates     

William R. Stockwell 《Journal of Atmospheric Chemistry》1994,19(3):317-329

The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO _x termination mechanism for the HO—SO₂ reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO₂ radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO₂ production from the HO—SO₂ reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates.  相似文献   

三元体系KCl－K＿2B＿4O＿7－H＿2O25℃时相平衡研究     

《矿物岩石》1994,(1)

  相似文献   

无机增强纤维Ⅰ.钛酸钾纤维   总被引：9，自引：0，他引：9  

黄继芬 《盐湖研究》1994,2(3):69-75

结晶质的钛酸钾纤维因其性质特殊而备受青睐，本文介绍了二钛酸钾、四钛酸钾、六钛酸钾和八钛酸钾纤维的结构、性质、用途，及国内外的研究现状．  相似文献   

赤砂沸石对氮磷钾吸附与释放的研究     

胡预生  马友华  周自默 《安徽地质》1995,(4)

本文以安徽省繁昌县赤砂沸石为试验材料，以黄红壤为参照，研究了丝光沸石为主的天然沸石对ＮＨ、Ｈ＿２ＰＯ及Ｋ￣＋的吸附与释放，结果表明：赤砂沸石的吸铵量和吸磷量为黄红壤的３倍；其中易释放铵和可释放铵占总吸铵量８０％以上；易释放磷和可释放磷占７０％以上；赤砂沸石的速效钾含量为黄红壤的７倍左右，而钾位缓冲容量（ＰＢＣ￣Ｋ）则为黄红壤的３５倍左右。赤砂沸石用做肥料调理剂和土壤改良剂，将能够减少土壤中氮、磷、钾的流失，并提高肥料中养分的利用率。  相似文献   

区域航空γ能谱场地球化学解释及预测方法的探讨     

孙念义 《铀矿地质》1987,(5)

本文以“铀矿区域评价准则”为依据,试用因子分析主成分比值法,铀对钍(钾)的区域相对场法和铀成矿有利指数法,对我国YW-10和YW-10B两个测区的区域航空γ能谱场进行了地球化学解释及预测方法的研究,与已知矿区660测区从宏观上做了对比分析,并研究了γ能谱参数在走向长270km,宽50—70km空间上的分布变化规律。研究结果表明,这些方法对了解成岩时原始铀的分布及后期铀的地球化学活动规律,估计成岩、成矿阶段铀源岩可能提供的生铀量,识别铀成矿有利地区是有用的。  相似文献   

腾格里地区盐湖的盐类沉积特征     

刘振敏  李博昀  刘国庆  徐少康 《化工矿产地质》2007,29(4):193-201

腾格里沙漠122个盐湖分为石盐、石盐-芒硝、石盐-白钠镁矾及芒硝(石膏)4种类型。盐湖含盐系厚度一般4～9m,总体呈现下部为含盐碎屑沉积,上部以盐类沉积为主,构成储卤层,卤水赋存其中,由湖岸至湖心储卤层厚度增长。含卤层理渐小,卤水含KCl渐高。盐湖中矿物主要为碳酸盐矿物,以芒硝、石膏为主的硫酸盐矿物、石盐以及粘土矿物。盐湖卤水以晶间卤水为主。许多卤水含K+大于2g/L。K+含量最高的红盐池,平均含量达19.14g/L。对钾矿而言,在盐湖分布相对集中地区,有一定的综合开发利用前景。  相似文献   

温度对复分解法制硝酸钾生产过程的影响          下载免费PDF全文

赵启文 《盐湖研究》2001,9(3):43-45

探讨以硝酸铵和氯化钾为原料、复分解法制硝酸钾工艺中 ,配料、硝酸钾结晶、氯化铵结晶等处操作温度对产量、质量、操作时间等的影响  相似文献   

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia   总被引：2，自引：1，他引：2  

M. Preda  M. E. Cox 《Environmental Geology》2001,40(6):755-768

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999  相似文献