Accurate and Precise Elemental Abundance of Zinc in Reference Materials by an Isotope Dilution Mass Spectrometry TIMS Technique     

Osama Y. Ghidan  Robert D. Loss 《Geostandards and Geoanalytical Research》2010,34(2):185-191

A thermal ionisation mass spectrometric technique enabled the abundance of Zn in geological and biological reference materials and water samples to be measured by double spiking isotope dilution mass spectrometry enriched in the ⁶⁷Zn and ⁷⁰Zn isotopes. In the past, thermal ionisation mass spectrometry proved to be difficult for low-level zinc isotopic measurements. The size of Zn samples used for isotopic determination, in particular the biological RMs, represents an important breakthrough. These results represent the most accurate and precise concentrations measured for Zn in these samples. The maximum fractional uncertainty was that for TILL-3 (2%), while the minimum fractional uncertainty was 0.7% for both BCR-1 and W-2. The inhomogeneity of Zn in HISS-1 was revealed while other reference materials appeared homogeneous at the 95% confidence uncertainty. The certified concentration of Zn in HISS-1 and IMEP-19 by their producers are 28% and 3.8% higher than the values measured in this work. These are the first Zn concentration measurements in these materials by the isotope dilution-TIMS technique, except for BCR-1, NIES N^o 9 and IMEP-19. Reducing the blank enabled accurate measurement in water at the ng g^-1 level demonstrating the applicability of the technique for low-level Zn samples.  相似文献   

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions     

Philippe Besson  Jefferson Degboe  Benjamin Berge  Valérie Chavagnac  Sébastien Fabre  Gilles Berger 《Geostandards and Geoanalytical Research》2014,38(3):355-362

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.  相似文献   

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry     

Monica E. Erdman  Cin‐Ty A. Lee  Wenbo Yang  Lynn Ingram 《Geostandards and Geoanalytical Research》2014,38(1):51-60

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.  相似文献   

胶东半岛乳山地区低角度韧性剪切带几何学、运动学特征:对中国东部岩石圈减薄作用的启示     

郝志宣  金超  田忠华  李同宇  文飞 《地质科学》2022,57(1):43-60

大规模伸展构造是华北克拉通东部岩石圈减薄的重要表现形式。部分低角度韧性剪切带是地壳伸展变形后所展现的构造形式。本文研究了王格庄韧性剪切带的岩石学、几何学、运动学等特征显示:韧性剪切带走向近南北向,剪切带断层面倾向多变(倾向西、西南、西北方向)。大部分区域面理低角度倾向西,矿物拉伸线理近东西向,不对称旋转碎斑及S-C组构指示顶端指向西的剪切特征。结合研究区西侧与伸展构造相匹配的半地堑伸展盆地证据:本研究认为伸展构造的形成可能与西太平洋板块的后撤相关,即大规模伸展构造作用引发了华北克拉通东部的地壳减薄作用。  相似文献   

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS          下载免费PDF全文

Richard M. Gaschnig  Roberta L. Rudnick  William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.  相似文献   

A Review of the IAG GeoPT™ and Certification Programmes,their Protocols,and the Differences between the Original and Potential Modifications to the Certification Protocol          下载免费PDF全文

Jean S. Kane 《Geostandards and Geoanalytical Research》2015,39(4):419-432

The IAG conducts two programmes, the GeoPT ^? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ^? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.  相似文献   

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS          下载免费PDF全文

Zaicong Wang  Harry Becker  Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.  相似文献   

Volcanic and Scientific Activity at Kick ’em Jenny Submarine Volcano 2001–2002: Implications for Volcanic Hazard in the Southern Grenadines,Lesser Antilles     

Jan?M.?LindsayEmail author  John?B.?Shepherd  Doug?Wilson 《Natural Hazards》2005,34(1):1-24

Kick em Jenny submarine volcano, ~8 km north of Grenada, has erupted at least 12 times since it was first discovered in 1939, making it the most frequently active volcano in the Lesser Antilles arc. The volcano lies in shallow water close to significant population centres and directly beneath a major shipping route, and as a consequence an understanding of the eruptive behaviour and potential hazards at the volcano is critical. The most recent eruption at Kick em Jenny occurred on December 4 2001, and differed significantly from past eruptions in that it was preceded by an intensive volcanic earthquake swarm. In March 2002 a multi-beam bathymetric survey of the volcano and its surroundings was carried out by the NOAA ship Ronald H Brown. This survey provided detailed three-dimensional images of the volcano, revealing the detailed morphology of the summit area. The volcano is capped by a summit crater which is breached to the northeast and which varies in diameter from 300 to 370 m. The depth to the summit (highest point on the crater rim) is 185 m and the depth to the lowest point inside the crater is 264 m. No dome is present within the crater. The crater and summit region of Kick em Jenny are located at the top of an asymmetrical cone which is about 1300 m from top to bottom on its western side. It lies within what appear to be the remnants of a much larger arcuate collapse structure. An evaluation of the morphology, bathymetry and eruptive history of the volcano indicates that the threat of eruption-generated tsunamis is considerably lower than previously thought, mainly because the volcano is no longer thought to be growing towards the surface. Of more major and immediate concern are the direct hazards associated with the volcano, such as ballistic ejecta, water disturbances and lowered water density due to degassing.  相似文献   

Theory of Basin Scale Dynamics of a Stratified Rotating Fluid     

Leo R. M. Maas 《Surveys in Geophysics》2004,25(3-4):249-279

The dynamics of a stratified fluid contained in a rotating rectangular box is described in terms of the evolution of the lowest moments of its density and momentum fields. The first moment of the density field also gives the position of the fluids centre-of-mass. The resulting low-order model allows for fast assessment both of adopted parameterisations, as well as of particular values of parameters. In the ideal fluid limit (neglect of viscous and diffusive effects), in the absence of wind, the equations have a Hamiltonian structure that is integrable (non-integrable) in the absence (presence) of differential heating. In a non-rotating convective regime, dynamically rich behaviour and strong dependence on the single (lumped) parameter are established. For small values of this parameter, in a self-similar regime, further reduction to an explicit map is discussed in an Appendix. Introducing rotation in a nearly geostrophic regime leads through a Hopf bifurcation to a limit cycle, and under the influence of wind and salt to multiple equilibria and chaos, respectively.  相似文献   

A technique for modeling the Earth’s gravity field on the basis of satellite accelerations   总被引：3，自引：2，他引：1  

P. Ditmar  A. A. van Eck van der Sluijs 《Journal of Geodesy》2004,78(1-2):12-33

A technique is proposed for Earths gravity field modeling on the basis of satellite accelerations that are derived from precise orbit data. The functional model rests on Newtons second law. The computational procedure is based on the pre-conditioned conjugate-gradient (PCCG) method. The data are treated as weighted average accelerations rather than as point-wise ones. As a result, a simple three-point numerical differentiation scheme can be used to derive them. Noise in the orbit-derived accelerations is strongly dependent on frequency. Therefore, the key element of the proposed technique is frequency-dependent data weighting. Fast convergence of the PCCG procedure is ensured by a block-diagonal pre-conditioner (approximation of the normal matrix), which is derived under the so-called Colombo assumptions. Both uninterrupted data sets and data with gaps can be handled. The developed technique is compared with other approaches: (1) the energy balance approach (based on the energy conservation law) and (2) the traditional approach (based on the integration of variational equations). Theoretical considerations, supported by a numerical study, show that the proposed technique is more accurate than the energy balance approach and leads to approximately the same results as the traditional one. The former finding is explained by the fact that the energy balance approach is only sensitive to the along-track force component. Information about the cross-track and the radial component of the gravitational potential gradient is lost because the corresponding force components do no work and do not contribute to the energy balance. Furthermore, it is shown that the proposed technique is much (possibly, orders of magnitude) faster than the traditional one because it does not require the computation of the normal matrix. Hints are given on how the proposed technique can be adapted to the explicit assembling of the normal matrix if the latter is needed for the computation of the model covariance matrix.Acknowledgments. Professor R. Klees is thanked for support of the project and for numerous fruitful discussions. The authors are also thankful to Dr. J. Kusche for useful remarks and to Dr. E. Schrama, his solid background in satellite geodesy proved to be very helpful. A large number of valuable comments were made by Dr. S.-C. Han, Dr. P. Schwintzer, and an anonymous reviewer; their contribution is greatly acknowledged. The satellite orbits used in the numerical study were kindly provided by Dr. P. Visser (Aerospace Department, Delft University of Technology). Access to the SGI Origin 3800 computer was provided by Stichting Nationale Computerfaciliteiten (NCF), grant SG-027.  相似文献