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61.
气相色谱法测定地下水中六六六结果的不确定度评定 总被引:7,自引:4,他引:3
依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。 相似文献
62.
Chang-Guk Sun Sung-Ho Chun Tae-Gyun Ha Choong-Ki Chung Dong-Soo Kim 《Computers and Geotechnics》2008,35(3):436-449
An integrated GIS-based tool (GTIS) was constructed to estimate site effects related to the earthquake hazards in the Gyeongju area of Korea. To build the GTIS for the study area, intensive site investigations and geotechnical data collections were performed and a walk-over site survey was additionally carried out to acquire surface geo-knowledge data in accordance with the procedure developed to build the GTIS. For practical applications of the GTIS used to estimate the site effects associated with the amplification of ground motion, seismic microzoning maps of the characteristic site period and the mean shear wave velocity to a depth of 30 m were created and presented as a regional synthetic strategy addressing earthquake-induced hazards. Additionally, based on one-dimensional site response analyses, various seismic microzoning maps for short- and mid-period amplification potentials were created for the study area. Case studies of seismic microzonations in the Gyeongju area verified the usefulness of the GTIS for predicting seismic hazards in the region. 相似文献
63.
江西省德兴铜矿矿区重金属元素的环境效应 总被引:6,自引:0,他引:6
本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质(水土植物)中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。 相似文献
64.
Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The 176Hf/177Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic 176Hf/177Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system. 相似文献
65.
Zhou Haiyan Zhou Xun Chai Rui Yu Lan Liu Chunhui Li Liangping 《Environmental Geology》2008,53(7):1483-1489
Thermal groundwater occurs in bedrock aquifers consisting of the dolomite of the Wumishan Group of the Jixianin System and
the Cambrian carbonate in the Xiaotangshan geothermal field near the northern margin of the North China Plain, China. The
hot water in the geothermal field of basin-type discharges partly in the form of the Xiaotangshan hot spring under natural
conditions. The hot water has TDS of less than 600 mg/L and is of Na·Ca-HCO3 type. The geothermal water receives recharge from precipitation in the mountain area with elevation of about 500 m above
sea level to the north of the spring. Thermal groundwater flows slowly south and southeast through a deep circulation with
a residence time of 224 years estimated with the Ra–Rn method. The Xiaotangshan hot spring dried up in the middle of the 1980s
owing to the increasing withdrawal of the hot water in the geothermal field in the past decades. The water level of the geothermal
system still falls continually at an annual average rate of about 2 m, although water temperature changes very little, indicating
that the recharge of such a geothermal system of basin-type is limited. Over-exploitation has a dramatic impact on the geothermal
system, and reduction in exploitation and reinjection are required for the sustainable usage of the hot water. 相似文献
66.
Phosphorus transport in shallow groundwater in peri-urban Kampala, Uganda: results from field and laboratory measurements 总被引:1,自引:0,他引:1
To understand Phosphorus (P) sources and transport processes in the subsurface in Bwaise III Parish, Kampala, P attenuation
and adsorption capacities of soils were studied in situ and from laboratory measurements. Relationships between sorption parameters
and soil matrix properties, rates and mechanism of the adsorption process and soil P fractions were also investigated. P was
generally higher in the wet than the dry season, but for both seasons, the maximum was 5 mgP/l. P transport mechanisms appeared
to be a combination of adsorption, precipitation, leaching from the soil media and by colloids with the latter two playing
an important role in the wet season. The sorption process comprised two phases with the first stage rate constants being about
fourfold those of the second stage. The Langmuir isotherm described the sorption data well (R
2 ≥ 0.95) with the second soil layer exhibiting the highest sorption maximum (C
max) (average value 0.6 ± 0.17 mgP/gDW). The best prediction of C
max had organic carbon, Ca, available P and soil pH. Residual P consisting mostly of organics was the main fraction in all the
layers followed by inorganic HCl-P and NaOH-P in the top and middle layers, respectively. Loosely bound P (NH4Cl-P) was the least fraction (<0.4% of total P) in all layers indicating the high binding capacity of P by the soils. The
study results suggest that P dynamics is related to Ca, Fe and organic carbon content of the soils. 相似文献
67.
Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China 总被引:2,自引:0,他引:2
Yongjin Chen Kefa Zhou Yaning Chen Weihong Li Jiazhen Liu Tao Wang 《Environmental Geology》2008,53(6):1365-1373
In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River
during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that
the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after
the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth.
The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e.,
from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising
groundwater level, the concentrations of major anions Cl−, SO42− and cations Ca2+, Mg2+, Na+, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater
chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther
from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that
farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably
when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end
of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage
and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships
between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum
groundwater depth in the lower reaches of the Tarim River should be −5 m. 相似文献
68.
A Triassic carbonate unit has been intensively drained by zinc and lead ore mines and numerous borehole fields since the nineteenth
century. Its groundwater recharge has increased due to: pumping of water from boreholes, mining activity, and urbanization.
An approach to determine the amounts of the recharge at a variety of spatial scales is presented in the paper. Different methods
were used to identify and quantify recharge components on a regional and local scale: mathematical modelling was performed
for four aquifers included in an aquifer system, an analytical estimation based on the assumption that an average recharge
is equal to the average discharge of the hydrogeological system—for six man-made drainage centres, and the method of water
level fluctuation (WLF) was applied in one observation borehole. Results of modelling have been supplemented by observation
of environmental tracers (δ18O, δ2H, 3H), noble gases temperatures, and 4Heexc in groundwater. The regional aquifer’s current recharge according to estimations performed by means of modelling varies from
39 to 101 mm/year on average. Depending on the aquifer site the average precipitation ranges from 779 to 864 mm/year. In the
confined part of the aquifer average recharge ranges from 26 to 61 mm/year. Within outcrops average recharge varies from 96
to 370 mm/year. Current recharge estimated by the analytical method for man-made drainage centres varies from 158 up to 440 mm/year.
High values are caused by different recharge sources like precipitation, induced leakage from shallow aquifers, and water
losses from streams, water mains and sewer systems. Pumping of water, mining and municipal activities constitute additional
factors accounting for the intensified recharge. 相似文献
69.
70.
Greening as strategic development in industrial change - Why companies participate in eco-networks 总被引:1,自引:0,他引:1
Eckhard Störmer 《Geoforum》2008,39(1):32-47
Networking between companies and other regional key actors has grown into a widespread instrument for economic development since the 1990s. Participatory networks have formed the concept for many activities of Local Agenda 21. Simultaneously, economic geography has focused on network theories to explain innovation in and the economic success of regions.This article focuses on the reasons why individual actors participate in environmentally oriented information networks. The questions approached are: Does the concept of learning within networks influence a firm’s development? How do the participants interact with each other? What effects do the networks have on their environment (arenas)?The changing arenas of a firm are analysed with regard to environmental concerns. These changes need to be anticipated for reliable strategies. To gain information and knowledge about current behaviour and activities, the functions of networks as learning platforms are discussed. Drawing upon arguments from different network theories, the motivations of participating in a network are threefold: actor and firm oriented, network internal (inter-firm), and network external. From these, a generic target cube of network motivations and actions is set up.The concept is reviewed by examining 12 ‘regional environmental information-oriented corporation networks’ (RUN) in the Greater Munich Area. The empirical material reveals that this type of network does not provide a guarantee for significant improvements in a firm’s environmental behaviour. However, participants learn about best practices while pursuing explicit or implicit aims as to influence their arenas. 相似文献