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41.
Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland 总被引:5,自引:0,他引:5
Major and trace elements as well as strontium isotopic composition have been analyzed on the acid-insoluble (AI) phase of
the loess-paleosol sequence from Luochuan, Shaanxi Province, China. Results show that the chemical composition of AI phase
of loess and paleosols is distinctive to the average composition of upper continental crust (UCC), characterized by depletion
of mobile elements Na, Ca and Sr. The distribution pattern of elements in AI phase reveals that initial dust, derived from
a vast area of Asian inland, has suffered from Na- and Ca-removed chemical weathering compared to UCC. Some geochemical parameters
(such as CIA values, Na/K, Rb/Sr and87Sr/86Sr ratios) display a regular variation and evolution, reflecting that the chemical weathering in the source region of loess
deposits has decreased gradually since 2.5 Ma with the general increase of global ice volume. This coincidence reflects that
the aridity of Asian inland since the Quaternary is a possible regional response to the global climate change. 相似文献
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43.
在陆相古火山角砾岩筒中由火山热液蚀变产生的含黄铁矿次生石英岩中的硫化物,在特别干旱的条件下生成了以毛矾石及黄钾铁钒为主的13种钒类矿物组成的硫化矿床氧化带,并在其中聚集了毛矾石矿体。毛钒石矿是由反复进行的氧化-渗透淋滤作用而富集形成的。 相似文献
44.
Mineral extraction and processing, especially metal mining, produces crushed and milled waste; such material, exposed to weathering, poses the potential threat of environmental contamination. In this study, mill tailings from inactive Pb-Zn mines in New Mexico, southwest USA, have been examined for their potential environmental impacts by means of detailed mineralogical and geochemical characterization. The principal ore minerals remaining in the tailings material are sphalerite, chalcopyrite, and very minor galena, smithsonite, and cerrusite, accompanied by the gangue minerals pyrite, pyrrhotite, magnetite, hematite, garnet, pyroxene, quartz, and calcite. White precipitate occurring on tailings surfaces is composed of gypsum and hydrated magnesium sulfates. Pyrite is mostly unaltered or shows only micron-scale rims of oxidation (goethite/hematite) in some surface samples. This iron oxide rim on pyrite is the only indication of weathering-derived minerals found by microscopy. There are variations in element concentrations with depth that reflect primary variations through time as the tailings ponds were filled. Cadmium and Zn concentrations increase with depth and Ag and Pb are low for the uppermost core samples, while Cu, Ni, and Co concentrations are generally high for the uppermost core samples. These elemental distributions indicate that little or no leaching has taken place since emplacement of the tailings because no accumulation or enrichment of these metals is observed in Hanover tailings, even in reducing portions of tailings piles. Element concentrations of surface samples surrounding the tailings reflect underlying mineralized zones rather than tailings-derived soil contamination. We observed no successive decreasing metal concentrations in prevalent wind directions away from the tailings. Stream sediment samples from Hanover Creek have somewhat elevated Zn, Cd, and Pb concentrations in areas that receive sediments from erosion of the tailings. However, input from tributaries downstream of the ponds appears to be principal source of heavy metals in Hanover Creek. The results of this study indicate that there is low risk for groundwater heavy-metal contamination from Hanover tailings. Tailings material do not show significant geochemical oxidation/alteration or metal leaching with depth. Our studies indicate that neutralizing minerals present in the tailings are sufficient to keep the tailings material chemically stable. Geochemically, however, tailings materials are being eroded and may pose a threat to Hanover Creek via siltation. 相似文献
45.
论当前我国北西部铀矿勘查关键技术 总被引:1,自引:1,他引:1
本文提出当前我国北西部铀矿勘查两项关键技术──中国北西部寻找大型超大型可地浸砂岩铀矿勘查技术和找矿勘探过程中地浸可行性评价技术,并论述了技术内容和技术开发目标。两项关键技术的开发研究和落实对扩大我国铀矿资源有现实意义。 相似文献
46.
中国PGE矿床类型分析 总被引:22,自引:6,他引:16
中国PGE(铂族元素)矿床类型分析,PGE(铂族元素)矿床包括Pt,Pd,Rh,Ru,Os,Ir6种元素,它们有着很强的亲“S”性和亲“Fe”族元素性,同时和Mo,Te,As,Sb,Bi等元素也有亲缘关系。这些相关元素在不同介质中,组成不同的元素组合,叫做元素“序列”,共有7个序列,它们对PGE形成有选择性的萃取和捕获能力,叫“萃捕剂”,再加上PGE自身的地球化学差异性,就可能形成多种不同的PGE矿床类型。列举了6个矿床实例,提出了成矿五要素,分析了中国PGE矿床前景,认为成矿和地幔岩初始岩浆密切相关。 相似文献
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48.
采用生物氧化技术和化学方法,利用堆浸工艺分步提取,对含Au 140~150 g/t、Ag 900~1 000 g/t、B i 9.0%~10.0%、Cu14%~17%的多金属浮选金精矿的综合回收工艺进行了研究。经小型搅拌试验,确定了生物氧化浸铜—氰化浸金、NaC l-FeC l3-HC l体系(氯盐法)浸出铋和银的技术方法。通过柱浸试验,研究了利用该方法分步浸取Au、Ag、Cu和B i在堆浸工艺中的可行性。在10 t精矿的扩大试验验中,验证了柱浸试验所取得的工艺指标和参数。试验中掺入骨架材料,解决了精矿在堆浸中的渗透问题;生物氧化过程中,菌种在含高浓度铜离子浸出液中反复驯化,对铜的耐受力提高到30 g/L;在NaC l-FeC l3-HC l体系浸出B i和Ag时,用H2O2将浸出液中的Fe2+氧化成Fe3+,使浸出液能循环使用,且B i和Ag同时浸出。Au、Ag、Cu和B i的最终浸出率分别为92.98%、65.09%、45.33%和53.49%。 相似文献
49.
20世纪90年代开始,在松辽盆地开展了地浸砂岩型铀矿区域评价工作.盆地的西南部投入数万米钻探工作量开展以第三系和上白垩统嫩江组、姚家组为目的层的找矿工作,取得了较大突破,发现并提交了我国第一个板状砂岩型铀矿床,所建立的双混合叠造铀成矿模式丰富了地浸砂岩型铀成矿理论.在此基础上总结出白垩系砂岩型铀成矿控矿因素和找矿标志.盆地东部构造反转有利于形成砂岩型铀矿床.第三系以潜水氧化为主,还原物质缺乏,而且新构造运动对其改造微弱,总的成矿条件不理想,不宜作为主攻目的层.盆地坳陷阶段沉积的泉头组、青山口组、姚家组为主要找矿目的层,找矿重点在盆地东南部通辽-双辽-德惠地区.下一步科研工作重点为:完善QJD砂岩型铀矿模式、盆地油气与铀成矿关系、白垩纪古水文地质条件的研究. 相似文献
50.
Hematite, as a typical iron oxide slime in sulphide ore slurries, was artificially added into the leaching systems of pure gold and a sulphide ore respectively, in an attempt to investigate the effect of iron oxide slimes on the ammoniacal thiosulphate leaching of gold. The presence of hematite significantly reduced the dissolution of gold and this detrimental effect became more pronounced with increasing hematite concentration. Hematite formed coatings on gold surfaces, which could prevent leach solution from diffusing to the gold surfaces and hence, inhibit gold dissolution. Hematite catalysed the oxidative decomposition of thiosulphate to polythionates with oxygen present. XPS studies indicated a thin layer of iron oxide coating as well as the deposition of some copper and sulphur species on gold surfaces. SEM images revealed a lesser extent of corrosion for gold after leaching in the presence of hematite. The gold extraction from the sulphide ore was reduced with the addition of hematite and this effect became more noticeable with an addition of hematite at a higher concentration. A natural guar type surfactant (Gempolym M47) reduced the detrimental effect of hematite on gold extraction likely due to the prevention of hematite coating on gold and mineral particles and the dispersion of the mineral slurry. Gempolym M47 stabilised thiosulphate by weakening the interaction between cupric ions and thiosulphate and by minimising the catalytic effect of hematite on thiosulphate decomposition. 相似文献