环境植物样品中铜铅锌铁锰的测定     

马欣  丛玉梅  邵文君 《国土资源》1995,(1)

将环境植物样品在４００─５００℃灰化，用硝酸、氢氟酸和高氯酸分解，用盐酸（１＋１）提取，控制２％─３％的盐酸介质，用火焰原子吸收分光光度法测定环境植物样品中的微量铜、铅、锌、铁、锰。该方法简单、快速、可靠。对环境植物标准样品的测定结果理想。  相似文献   

东北黑土区侵蚀沟遥感影像特征提取与识别   总被引：3，自引：0，他引：3  

于佩鑫  周询  刘素红  王西凯 《遥感学报》2018,22(4):611-620

东北黑土区是中国重要的粮食生产区,而长期的开垦造成了严重的水土流失现象,坡耕地表面出现大量的侵蚀沟。侵蚀沟的识别是土壤侵蚀监测的重要手段之一,目前遥感技术在侵蚀沟的识别中应用广泛,但自动化程度不高。针对特定地物影像的识别,如何选取最能够有效描述该地物的特征是解决问题的关键。本文构建了耕地和侵蚀沟遥感影像的训练样本集,基于样本集分别提取了由光谱特征和纹理特征组成的浅层特征、SIFT特征经编码后得到的中层特征,以及利用卷积神经网络提取的深层特征;再基于不同层次的特征选用合适的分类器对遥感影像进行分类,识别出含有侵蚀沟的遥感影像,形成了一套针对侵蚀沟的特征提取与识别方法,为东北黑土区的耕地保护提供有力支持。测试结果表明:基于中层特征的识别精度最高,为98.5%,但该特征需要人工设计,自动化程度有限;而利用卷积神经网络可自动提取深层特征,其识别精度达到了95.5%,同时大大提高了自动化程度,满足侵蚀沟影像的识别的需求。  相似文献   

Evaluation of the Residual Mass Fractionation in High-Precision Cr Isotopic Analysis with TIMS     

Tetsuya Yokoyama  Yusuke Ohkuma  Keiji Nishikawa  Koki Sumiya  Ikshu Gautam 《Geostandards and Geoanalytical Research》2023,47(2):415-435

The Cr isotope ratios of terrestrial and extra-terrestrial materials are emerging as one of the most important tracers in geosciences. Previous studies on Cr isotopic measurements using TIMS have found that there is residual Cr isotopic fractionation between the mass-fractionation-corrected ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios, which may cause an offset of obtained ratios from the reference values. The residual fractionation was thought to be caused by the evaporation of Cr-oxide species during thermal ionisation, but the mechanism by which this residual fractionation could be reduced remained unclear. Here we revisit the issue of residual fractionation and propose that this problem can be alleviated by utilising W filaments instead of conventionally used Re filaments for Cr ionisation. Using W filaments, the formation of CrO⁺ was suppressed during heating as the filament temperature was ~ 100 °C lower than when Re filaments were used. In repeated measurement of a carbonaceous chondrite, the intermediate precisions of ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios in the W filament runs were two to three times better than those of the Re filament runs. Therefore, the new finding of this study will be of key importance for future studies of Cr isotopes for terrestrial and extra-terrestrial materials.  相似文献   

Rapid screening of Zr-containing particles from Chang’e-5 lunar soil samples for isotope geochronology: Technical roadmap for future study     

《地学前缘(英文版)》2022,13(3):101367

New samples returned by China Chang’e-5 (CE-5) mission offer an opportunity for studying the lunar geologic longevity, space weathering, and regolith evolution. The age determination of the CE-5 samples was among the first scientific questions to be answered. However, the precious samples, most in the micrometer size range, challenge many traditional analyses on large single crystals of zircon developed for massive bulk samples. Here, we developed a non-destructive rapid screening of individual zirconium-containing particle for isotope geochronology based on a Micro X-ray fluorescence analysis (µXRF). The selected particles were verified via scanning electron microscopy (SEM), 3D X-ray microscopy (XRM), and focused ion beam scanning electron microscopy (FIB-SEM) techniques, which showed that zirconium-bearing minerals with several microns were precisely positioned and readily suitable for site-specific isotopic dating by second ion mass spectrometry (SIMS). Such protocol could be also applicable in non-destructively screening other types of particles for different scientific purposes. We therefore proposed a correlative workflow for comprehensively studying the CE-5 lunar samples from single particles on nanometer to atomic scales. Linking various microscopic and spectromicroscopic instruments together, this workflow consists of six steps: (1) single-particle selection with non-destructive µXRF technique, (2) 2D/3D morphological and structural characterization with a correlative submicron 3D XRM and nanoscale resolution FIB-SEM imaging methods, (3) SEM analysis of the surface morphology and chemistry of the selected particle, (4) a series of microscopic and microbeam analyses (e.g., SEM, electron probe microanalysis, and SIMS) on the cross-section of the selected particle to obtain structural, mineralogical, chemical, and isotopic features from the micron to nanometer scale, (5) advanced 2D/3D characterization and site-specific sample preparation of thin foil/tip specimens on a microregion of interest in the selected particle with FIB-SEM technique, and (6) comprehensive analyses on the FIB-milled specimens at nanometer to atomic scale with synchrotron-based scanning transmission X-ray microscopy, analytic transmission electron microscopy, and atom probe tomography. Following this technical roadmap, one can integrate multiple modalities into a uniform frame of multimodal and multiscale correlated datasets to acquire high-throughput information on the limited or precious terrestrial and extraterrestrial samples.  相似文献   

真三轴单面临空下煤岩组合体冲击破坏特征试验研究     

杨科  刘文杰  马衍坤  许日杰  池小楼 《岩土力学》2022,(1):15-27

煤岩复合承载结构所处的应力边界条件不同,冲击地压在巷道中的显现特征和前兆规律亦不相同。采用高频振动采集及孔内成像三轴动静载试验系统,开展了高静载和动静载耦合作用下煤岩组合体真三轴单面临空试验,分析了煤岩组合体界面处力学特征和强度条件,探究了不同应力边界下煤岩组合体的破坏形态、动力显现特征和声发射信号的演变规律。研究结果表明:(1)受煤岩变形相互制约的影响,交界面处砂岩强度被"弱化"。当界面处煤体裂隙尖端的应力大于"弱化"后砂岩强度时,裂隙将穿过煤岩界面发育至砂岩中,砂岩呈现出屈曲层裂、劈裂成板的破坏形态。(2)高静载作用下,煤岩组合体变形破坏特征和声发射信号具有明显的前兆规律,组合体发生承载失效前煤体局部颗粒弹射动能增大、弹射颗粒块度降低,声发射信号由"高频低能"向"高频高能"转变,组合体的破坏形态以剪切-张拉复合破坏为主。(3)受冲击动载影响,顶底板砂岩夹持作用减弱,煤体裂纹尖端应力得不到有效积聚,裂纹扩展到煤岩交界面时被阻隔,组合体以煤样的张拉破坏为主,声发射信号呈现出"高频高能"的特点,但大多集中在冲击破坏之后,导致组合体动力破坏难以预测。(4)与纯静载作用相比,虽然动静载耦合作...  相似文献   

电感耦合等离子体质谱法测定灌木枝叶中微量元素的样品预处理方法研究   总被引：1，自引：1，他引：0  

林伟龙  王正海  王娟  蒋丽怡  范朝焰 《岩矿测试》2015,34(4):430-435

利用电感耦合等离子体质谱法(ICP-MS)测定植物样品中微量元素的关键技术是消除植物样品的有机基体效应,本文通过预处理方法中的酸消解体系、称样量和消解方式消除其影响。以国家标准物质灌木枝叶组合样(GBW07603)为材料进行研究,对比分析了硝酸-过氧化氢、硝酸-氢氟酸、硝酸-氢氟酸-过氧化氢3种酸溶体系的消解效果,以确定最佳酸溶体系,进而定量研究2种称样量(50 mg和100 mg)和3种消解方式(密封高压二次消解、密封高压一次消解、微波消解)的消解效果,并以In作为内标采用ICP-MS测定微量元素含量。结果表明:硝酸-氢氟酸-过氧化氢酸溶体系的消解效果最好;50 mg的测定值更接近于参考值;微波消解法的测定值明显偏低,而密封高压二次消解法是灌木枝叶样品预处理的有效方法。  相似文献   

巯基棉富集-分光光度法测定地球化学样品中铂钯的野外快速分析方法研究   总被引：1，自引：1，他引：0  

王烨  孙爱琴  李志伟 《岩矿测试》2015,34(4):459-463

对于地球化学样品中铂钯的测定,传统和现代分析方法均是建立在试金或树脂及活性炭富集后用分光光度法或电感耦合等离子体质谱法测定,而在野外满足不了这些条件。本文基于样品的性质及分光光度法的适应性强等特点,开发了一种适合于野外简单条件下快速测定地质样品中铂和钯的分析方法。样品用盐酸-氯酸钾-氯化钠-氟化氢铵常温常压密闭分解,巯基棉分别富集铂和钯,灰化处理后采用三氯甲烷-石油醚(1∶3)为萃取剂,DDO为显色剂萃取比色测定铂、钯的含量。巯基棉对钯的吸附率可达98%;加入氯化亚锡-水合肼(还原剂)使铂的吸附率提高到99%。方法检出限为Pt 0.05μg/g,Pd 0.02μg/g,标准物质的测定值与推荐值基本一致,野外地质样品的测定值与实验室分析结果吻合。  相似文献   

From pollen percentage to vegetation cover: evaluation of the Landscape Reconstruction Algorithm in western Norway   总被引：1，自引：0，他引：1       下载免费PDF全文

KARI LOE HJELLE  INGVILD KRISTINE MEHL  SHINYA SUGITA  GIDSKE LEKNÆS ANDERSEN 《第四纪科学杂志》2015,30(4):312-324

The Landscape Reconstruction Algorithm (LRA) with the two models REVEALS and LOVE is developed to transform pollen percentage data to vegetation cover. This paper presents the first study to evaluate LRA in a region with large topographic variations within a short distances. The REVEALS model estimates regional vegetation abundance based on pollen assemblages from large lakes (100–500 ha). Pollen surface samples from one large and 28 small lakes are used together with a combination of regionally derived pollen productivity estimates and available estimates from other regions of Europe. The results show a good relationship between REVEALS‐estimated forest cover and vegetation abundance based on the CORINE land‐cover data. The REVEALS results using various sets of pollen assemblages from small lakes were comparable to those using one large lake. Local vegetation abundance using the LOVE model was estimated around 26 lakes. For common taxa, such as Pinus and Poaceae, the LOVE‐based estimates of plant abundance match well with the distance‐weighted plant abundances based on vegetation maps. Our results indicate that the LRA approach is effective for reconstruction of long‐term vegetation changes in western Norway and other regions with high topographic relief when no major gradients exist in the pollen data.  相似文献   

化探样品中部分元素测定溶矿方法的改进     

周雄菊 《南方国土资源》2002,15(4):80-82

文章研究了用 1∶1王水分解化探样品中Cu、Pb、Zn、Co、Ni、Fe、Mn等元素新的样品溶解测定方法 ,即王水分解测定法 ,该法的检出限、准确度、精密度均达到 1∶5万化探样品分析要求。此法已用于化探及区域地质普查样品分析 ,并取得了较好效果  相似文献   

热解—动力学光度法测定岩石和化探样品中痕量溴     

杨秀清 《国土资源》1989,(1)

以五氧化二钒为熔剂,用热解分离富集痕量溴,吸收于0.036mol/l 氢氧化钾中,在1.34mol/l 硫酸和硝酸混合溶液中,溴离子催化高锰酸钾对碘的氧化,用苯萃取未反应碘,然后用硫氢酸汞—硫酸高铁铵比色法测定溴。本方法灵敏度高,远择性好,操作简便、快速,方法检出限为0.35ppm 溴,标准偏差为11.63％。  相似文献