A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits     

Edwin van der Heijden  Jaap J. Boon 《Organic Geochemistry》1994,22(6)

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.  相似文献   

A preliminary scanning electron microscope study of honeycomb weathering of sandstone in a coastal environment     

J. P. McGreevy 《地球表面变化过程与地形》1985,10(5):509-518

Honeycomb weathering has been observed in a Carboniferous sandstone at a coastal location near Ballycastle on the north coast of Northern Ireland. Specimens of this sandstone have been analysed by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. Results reveal that calcium sulphate (gypsum) is the only salt present and is found only at and immediately below the rock surface. SEM observations suggest that crystallization of salts in pores could easily dislodge quartz grains to promote granular disintegration, whilst etching of quartz grain surfaces attests to chemical weathering activity within the rock However, the reason for the development of the honeycomb pattern is not known.  相似文献   

扫描电镜的定量体视测量法     

冯有纲  汪大成 《矿物学报》1985,(3)

本文提出了一种新的体视学原理及其在扫描电子显微镜中的应用。借助于它的实验技术,可从图象中获得大量信息,而且能测定图片上任何物体的真实尺寸与几何图形,这种方法具有如下的新功能:1.可测定小晶面夹角;2.可测定图片上任意两点之间的真实距离;3.可测定曲线的长度和曲面的面积。文中例举了该法应用于地学的三例.  相似文献   

沉积岩中蒙脱石-伊利石混层矿物的SEM/EDAX分析   总被引：1，自引：1，他引：1  

奚可棠 《矿物学报》1986,(3)

本文利用扫描电子显微镜与X射线能量色散分析联合法,对沉积岩中蒙脱石-伊利石混层矿物进行系统微区成分分析,求出混合层中伊利石的百分含量。  相似文献   

Limestone weathering in Eastern Australia. Part 2: Surface micromorphology study     

C. Moses  A. P. Spate  D. I. Smith  M. A. Greenaway 《地球表面变化过程与地形》1995,20(6):501-514

Results from long term microerosion meter (MEM) studies indicate that microenvironments are characterized by different erosion rates. A complementary study, carried out on the same sites, examines the microscale morphology in each environment. Optical and scanning electron microscopy were used to identify a range of features thought to reflect different processes. Under subaerial conditions micromorphology is dominated by biological weathering features owing to the presence of microflora. Sites permanently covered by soil or stream water have only dissolution etch features, though stream sites may exhibit microfractures. Sites with periodic exposure exhibit both dissolution and biological etch features. The natural environment is more accurately reflected by allowing some microflora colonization of MEM sites rather than preventing colonization by artificial means.  相似文献   

鲜水河断裂带大震复发机制和时空分布原因     

安欧 《地震》1995,(3):214-221

岩石接触面在高温高围压下经过几天便烧结起来而有很高但低于原岩的剪切强度。烧结面与主压应力方向夹角大于55—65°时,便不再断裂而沿其它方向剪断。实验最低温压相当地壳10km深,这应是地壳大断裂的上部裂面与下部烧结层的界限深度,受力后便向下延裂,在下部形成震源。这可能是鲜水河断裂带震源在10—25km深重复发生的原因。由带内大震机制解P轴方向与地球自转速率变化趋势的关系、区域残余应力场水平主压应力分布方向与断裂带走向的关系,讨论了带内大震活动时段的原因。由带内裂面烧结条件、残余和现今应力高值区、岩体低强度区及储存弹性应变能高值区的分布,研究了带内大震空间分布原因。  相似文献   

计算最小走时和射线路径的界面网全局方法   总被引：27，自引：16，他引：27       下载免费PDF全文

刘洪  孟凡林 《地球物理学报》1995,38(6):823-832

用慢度分块均匀正方形模型将介质参数化，仅在正方形单元的边界上设置计算结点，这些结点构成界面网．根据Ｈｕｖｓｅｎｓ和Ｆｅｒｍａｔ原理，由不断扩张、收缩的波前点扫描代替波前面搜索，在波前点附近点的局部最小走时计算中对波前点之间的走时使用双曲线近似，通过比较确定最小走时和相应的次级源位置，记录在以界面网点位置为指针的３个一维数组中．借助这些数组通过向源搜索可计算任意点（包括界面网以外的点）上的全局最小走时和射线路径．这一方法不受介质慢度差异大小限制，占内存少，计算速度较快，适于走时反演和以Ｍａｓｌｏｖ射线理论为基础的波场计算．  相似文献   

A Combined Three-Dimensional Geological-Geostatistical-Numerical Model of Underground Excavations in Rock   总被引：1，自引：1，他引：1  

M. Stavropoulou  G. Exadaktylos  G. Saratsis 《Rock Mechanics and Rock Engineering》2007,40(3):213-243

Summary. This paper exploits geological and borehole geotechnical data obtained in the exploratory phase of a tunneling project to investigate in a first place if the kriging interpolation scheme may effectively reproduce the spatial variability of rock mass quality (Rock Mass Rating, RMR) in the vicinity of tunnels. For this purpose a quick solver in Fortran has been developed that performs variography analysis of 3D spatial data, fast kriging estimations of RMR between borehole sampling locations at the centroids of the elements of the numerical model, and model validation. For the purpose of an integrated underground excavation design, a step further is made by incorporating into the 3D mechanical numerical model of the rock mass, the three-dimensional (3D) solid geological model, thus coupling the geology with the ground (geotechnical) model (i.e. each element of the numerical model is assigned a geological material). The mechanical properties of each finite difference cell (or Representative Elementary Volume) of the ground model were then prescribed according to its geological type, the spatial heterogeneity of the rock mass expressed quantitatively with the kriging model, and the upscaling calculations of the mechanical properties of the intact rocks determined in the laboratory, based on the size-effect (strength dependence on size) and Damage Theory. Furthermore, a preliminary numerical simulation of the advance of unsupported tunnels in the model of the heterogeneous rock mass was performed for illustration purposes.  相似文献   

Application of Load/Unload Response Ratio in the Study of Seismicity in the Region of Iran     

Zhang Langping 《中国地震研究》2007,21(2):147-155

The variation of Load/Unload Response Ratio (LURR) against time for earthquakes in Kerman Province, Iran, on February 22, 2005, M6.4 and in Lorestan Province, Iran, on March 31, 2006, M6.1, has been calculated and analysed in this paper. The tempo-spatial scanning of LURR in the region of Iran during January 1, 2003 to March 31, 2006 has been conducted, with 1 year as a time-window, 1 month as a time-step, and the comparison of the LURR anomalous regions in 2004 with the actual earthquakes with M≥5.0 in the next year (2005) is also given, which shows that 11 earthquakes with M≥5.0 occurred in LURR anomalous regions while 12 earthquakes with M≥5.0 in LURR regions in 2005. Furthermore, the seismicity in this region is studied by investigating the evolvement of the anomalous LURR regions.  相似文献   

地面起伏对成像及雷达景象匹配的影响   总被引：5，自引：0，他引：5  

叶勤  李启炎 《测绘学报》2002,31(Z1):50-55

景象匹配是飞行器导航与定位的一种重要手段,其中的雷达图像匹配由于具有全天候的特征而受到人们的重视.在分析了实时雷达图像成像方式的基础上,具体分析了地面高程起伏对雷达图像构像的影响,并进一步推导出在实时雷达图像上,图像像点位移与地面高程起伏的具体关系;以及为了保证一定的匹配定位精度,对于实飞地区地面起伏的定量要求.同时还对导航定位匹配所用的参考基准图受地面高程起伏的影响情况进行了定量的分析,并对理论情况和实际图像进行了计算分析与比较,最后得出在给定匹配精度的情况下,生成参考图时对成像区域内点之间的高差限制要求.  相似文献