Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A     

Lui-Heung Chan  Jeffrey C Alt 《Earth and Planetary Science Letters》2002,201(1):187-201

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.  相似文献   

国道219线新-藏公路改建工程地质灾害评价   总被引：1，自引：0，他引：1  

李铁锋  刘长兵  李欣 《中国地质灾害与防治学报》2003,14(4):26-29

国道219线新-藏区界至红土达坂路段全长109．55km。大部分路段穿越湖盆槽谷中央部位，部分线路沿湖盆边缘台地布设，海拔高度介于5000-5400m之间，地势平坦开阔，多年冻土发育，工程地质条件较差；现有公路路基高度低，几乎没有排水设施。冬季易产生路基冻胀和涎流冰危害，春、夏季因冻土融化，常引起路基沉陷和翻浆，严重危害公路运输安全甚至阻断交通。公路工程修建活动将极大地改变冻土环境，使天然状态下的水分循环发生改变，导致多年冻土退化，上限加深，进一步诱发冻胀、融沉、热融滑塌等冻土灾害，加剧风沙灾害、诱发公路边坡失稳破坏。在即将进行的公路改、扩建工程中，应采取保护冻土的设计原则，优选线路，加强侧向排水，合理设置取弃土场。  相似文献   

Facies of slurry-flow deposits, Britannia Formation (Lower Cretaceous), North Sea: implications for flow evolution and deposit geometry   总被引：4，自引：0，他引：4  

Donald R. Lowe  Martin Guy†  Andrew Palfrey† 《Sedimentology》2003,50(1):45-80

ABSTRACT Mud‐rich sandstone beds in the Lower Cretaceous Britannia Formation, UK North Sea, were deposited by sediment flows transitional between debris flows and turbidity currents, termed slurry flows. Much of the mud in these flows was transported as sand‐ and silt‐sized grains that were approximately hydraulically equivalent to suspended quartz and feldspar. In the eastern Britannia Field, individual slurry beds are continuous over long distances, and abundant core makes it possible to document facies changes across the field. Most beds display regular areal grain‐size changes. In this study, fining trends, especially in the size of the largest grains, are used to estimate palaeoflow and palaeoslope directions. In the middle part of the Britannia Formation, stratigraphic zones 40 and 45, slurry flows moved from south‐west and south towards the north‐east and north. Most zone 45 beds lens out before reaching the northern edge of the field, apparently by wedging out against the northern basin slope. Zone 40 and 45 beds show downflow facies transitions from low‐mud‐content, dish‐structured and wispy‐laminated sandstone to high‐mud‐content banded units. In zone 50, at the top of the formation, flows moved from north to south or north‐west to south‐east, and their deposits show transitions from proximal mud‐rich banded and mixed slurried beds to more distal lower‐mud‐content banded and wispy‐laminated units. The contrasting facies trends in zones 40 and 45 and zone 50 may reflect differing grain‐size relationships between quartz and feldspar grains and mud particles in the depositing flows. In zones 40 and 45, quartz grains average 0·30–0·32 mm in diameter, ≈ 0·10 mm coarser than in zone 50. The medium‐grained quartz in zones 40 and 45 flows may have been slightly coarser than the associated mud grains, resulting in the preferential deposition of quartz in proximal areas and downslope enrichment of the flows in mud. In zone 50 flows, mud was probably slightly coarser than the associated fine‐grained quartz, resulting in early mud sedimentation and enrichment of the distal flows in fine‐grained quartz and feldspar. Mud particles in all flows may have had an effective grain size of ≈ 0·25 mm. Both mud content and suspended‐load fallout rate played key roles in the sedimentation of Britannia slurry flows and structuring of the resulting deposits. During deposition of zones 40 and 45, the area of the eastern Britannia Field in block 16/26 may have been a locally enclosed subbasin within which the depositing slurry flows were locally ponded. Slurry beds in the eastern Britannia Field are ‘lumpy’ sheet‐like bodies that show facies changes but little additional complexity. There is no thin‐bedded facies that might represent waning flows analogous to low‐density turbidity currents. The dominance of laminar, cohesion‐dominated shear layers during sedimentation prevented most bed erosion, and the deposystem lacked channel, levee and overbank facies that commonly make up turbidity current‐dominated systems. Britannia slurry flows, although turbulent and capable of size‐fractionating even fine‐grained sediments, left sand bodies with geometries and facies more like those deposited by poorly differentiated laminar debris flows.  相似文献   

Beds comprising debrite sandwiched within co-genetic turbidite: origin and widespread occurrence in distal depositional environments   总被引：11，自引：0，他引：11  

P. J. Talling  L. A. Amy†  R. B. Wynn‡  J. Peakall†  M. Robinson 《Sedimentology》2004,51(1):163-194

Co‐genetic debrite–turbidite beds occur in a variety of modern and ancient turbidite systems. Their basic character is distinctive. An ungraded muddy sandstone interval is encased within mud‐poor graded sandstone, siltstone and mudstone. The muddy sandstone interval preserves evidence of en masse deposition and is thus termed a debrite. The mud‐poor sandstone, siltstone and mudstone show features indicating progressive layer‐by‐layer deposition and are thus called a turbidite. Palaeocurrent indicators, ubiquitous stratigraphic association and the position of hemipelagic intervals demonstrate that debrite and enclosing turbidite originate in the same event. Detailed field observations are presented for co‐genetic debrite–turbidite beds in three widespread sequences of variable age: the Miocene Marnoso Arenacea Formation in the Italian Apennines; the Silurian Aberystwyth Grits in Wales; and Quaternary deposits of the Agadir Basin, offshore Morocco. Deposition of these sequences occurred in similar unchannellized basin‐plain settings. Co‐genetic debrite–turbidite beds were deposited from longitudinally segregated flow events, comprising both debris flow and forerunning turbidity current. It is most likely that the debris flow was generated by relatively shallow (few tens of centimetres) erosion of mud‐rich sea‐floor sediment. Changes in the settling behaviour of sand grains from a muddy fluid as flows decelerated may also have contributed to debrite deposition. The association with distal settings results from the ubiquitous presence of muddy deposits in such locations, which may be eroded and disaggregated to form a cohesive debris flow. Debrite intervals may be extensive (> 26 × 10 km in the Marnoso Arenacea Formation) and are not restricted to basin margins. Such long debris flow run‐out on low‐gradient sea floor (< 0·1°) may simply be due to low yield strength (? 50 Pa) of the debris–water mixture. This study emphasizes that multiple flow types, and transformations between flow types, can occur within the distal parts of submarine flow events.  相似文献   

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS   总被引：6，自引：1，他引：6  

Alistair B. Jeffcoate  Tim Elliott  Alex Thomas  Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.  相似文献   

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)     

M. Roy-Barman  C. Jeandel  M. Souhaut  M. Rutgers van der Loeff  I. Voege  N. Leblond  R. Freydier 《Earth and Planetary Science Letters》2005,240(3-4):681-693

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.  相似文献   

海上钻孔灌注桩成孔施工技术     

曾定帮  彭文祥 《岩土工程技术》2005,19(1):53-54,F003

介绍了东海大桥钻孔灌注桩基础的施工技术 ,对一些关键技术做了详细说明 ,还讨论了海上钻孔灌注桩施工成孔设备的选择及所用的淡水泥浆的配制  相似文献   

基于分光光度法的多量程海水营养盐原位传感器检测系统设计     

綦声波  任军博  马然  张述伟 《海洋科学》2019,43(11):76-83

针对传统海水营养盐检测方法不能满足海水营养盐长期原位监测需求的问题,研制了一种基于分光光度法的多量程海水营养盐原位传感器检测系统,通过对系统的高度集成及对多量程检测、低功耗技术、漏液保护技术的应用,实现了对海水5项营养盐参数快速、宽范围、高精度的原位测量。经过实验室和青岛中苑码头现场测试,表明本营养盐传感器检测系统具有低功耗、高可靠性能,可满足对5项营养盐参数的快速精确测量要求,实现了对海水营养盐参数的原位监测,为相关部门及时了解海洋生态环境和水体富营养化程度提供了数据支持,具有重大现实意义。  相似文献   

Elastic lateral dynamic impedance functions for a rigid cylindrical shell type foundation          下载免费PDF全文

R. He  R.Y.S. Pak  L.Z. Wang 《国际地质力学数值与分析法杂志》2017,41(4):508-526

Elastic lateral dynamic impedance functions are defined as the ratio of the lateral dynamic force/moment to the corresponding lateral displacement/rotation at the top ending of a foundation at very small strains. Elastic lateral dynamic impedance functions have a defining influence on the natural frequencies of offshore wind turbines supported on cylindrical shell type foundations, such as suction caissons, bucket foundations, and monopiles. This paper considers the coupled horizontal and rocking vibration of a cylindrical shell type foundation embedded in a fully saturated poroelastic seabed in contact with a seawater half‐space. The formulation of the coupled seawater–shell–seabed vibration problem is simplified by treating the shell as a rigid one. The rigid shell vibration problem is approached by the integral equation method using ring‐load Green's functions for a layered seawater‐seabed half‐space. By considering the boundary conditions at the shell–soil interface, the shell vibration problem is reduced to Fredholm integral equations. Through an analysis of the corresponding Cauchy singular equations, the intrinsic singular characteristics of the problem are rendered explicit. With the singularities incorporated into the solution representation, an effective numerical method involving Gauss–Chebyshev method is developed for the governing Fredholm equations. Selected numerical results for the dynamic contact load distributions, displacements of the shell, and lateral dynamic impedance functions are examined for different shell length–radius ratio, poroelastic materials, and frequencies of excitation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

刘公岛海洋牧场底层海水溶解氧浓度的变化特征     

李兆钦  李欣  孙利元  刘子洲  顾艳镇  翟方国  李培良 《海洋与湖沼》2019,50(1):86-99

由于缺乏长期观测资料,前人对山东半岛邻近海域海水溶解氧的时间变化和空间分布特征的研究较少。本文基于威海刘公岛海洋牧场于2016年7月20日至2017年3月14日期间,利用生态环境实时在线观测系统获得的底层海水的温度、盐度、水深、溶解氧数据,分析了该牧场海水溶解氧浓度的时间变化特征及其影响因素,并探讨了低氧灾害发生的可能性。结果表明在观测期间,该牧场海水溶解氧浓度以季节变化为主,冬季最大、夏季最小,其中2月份平均值最高,约为10.86mg/L,8月份平均值最低,约为5.91mg/L。同时海水溶解氧浓度也存在显著的小时变化和日变化,且变化幅度于8月份最大、3月份最小。影响海水溶解氧浓度变化的主要因素是海水温度,溶解氧浓度随着温度的季节性变化而变化。夏季,水体分层会使溶解氧浓度发生大幅度的降低,大风过程对于溶解氧浓度也有一定的影响,通过打破夏季的季节性温跃层使水体发生垂向混合从而为海底提供氧气,但大风过程之后的几天会出现溶解氧浓度降低的现象。本次研究发现刘公岛海洋牧场在观测期间不存在低氧现象。  相似文献