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21.
Numerical computations concerning geochemical processes in porous media require a knowledge of the values of the macroscopic
parameters. In the context of the interpretation of leaching tests one such parameter is the apparent macroscopic diffusivity.
In this paper, a mathematical model for dissolution in the presence of diffusion is considered. It is shown that the constant
diffusion coefficient can be identifiable when the time integral of the flux is known. Moreover, a practical algorithm for
computing the diffusion coefficient is proposed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Astrid Holstad 《Computational Geosciences》2000,4(2):103-139
We formulate mathematical and numerical models for multispecies, multi-phase and non-isothermal reactive fluid flow in porous
media focusing on the chemical reactions and the transport of solutes. Mass conservation and stability in the time integration
are emphasized. We use cell-centered finite volume differencing in space and an implicit Runge-Kutta method in time. Assuming
two space dimensions, we introduce flux approximation for arbitrarily shaped convex quadrilaterals. On equidistant and variable
sized rectangular grids we choose limited κ=
related schemes to approximate the advective flux and the central difference scheme for the diffusive flux. On non-rectangular
grids we recommend the VF9 scheme for the estimation of the diffusive flux. Our model exists as a code.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
24.
ROTSE‐IIId observations of the Be/X‐ray transient system KS 1947+300 obtained between September 2004 and December 2005 make it possible to study the correlation between optical and X‐ray activity. The optical outburst of 0.1 mag was accompanied by an increase of the X‐ray flux in the 2004 observations. A strong correlation between the optical and X‐ray light curves suggests that the neutron star directly accretes from the outflowing material of the Be star. The nearly zero time lag between X‐ray and optical light curves suggests a heating of the disk of Be star by X‐rays. No optical brightening and X‐ray enhancement was seen in the 2005 observations. There is no indication of an orbital modulation in the optical light curve. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Silicon-32 as a tool for dating the recent past 总被引:2,自引:2,他引:0
Silicon-32, with a half-life of approximately 140 years, has the potential to fill the dating gap that lies between those chronologies based on the shorter-lived isotopes of 3H and 210Pb, and those based on the longer-lived 14C. Silicon-32 is produced in the atmosphere by cosmic ray bombardment of argon, and falls out on the Earth's surface in precipitation. Silicon-32 methods may be used to date siliceous sediments and sponges, groundwater and glacier ice. Measurement of 32Si concentrations in these archives is, however, not straightforward. Two methods are available: radioactive-decay counting of the activity of the daughter nucleus, 32P, and accelerator mass spectrometry, but in both cases the detection of 32Si pushes the boundaries of the technique. Even the half-life of 32Si is not known to a precision of better than ±10%. In this paper, we review efforts to determine the isotope's half-life, survey the detection methods and discuss the applications of 32Si chronology. We show that at least some of the chronometric potential of this radioisotope is close to being realised as a result of recent improvements in methods of measurement. 相似文献
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近年来,柴达木盆地英西地区渐新统E32获得了持续的重大勘探发现。基于岩心观察、系统的微观岩石学、矿物学以及地球化学分析,系统总结了柴达木盆地英西地区渐新统咸化湖盆中盐类矿物特征、成因及成藏作用:(1)英西地区渐新统E32 4种重要的盐类矿物包括石盐、硬石膏、钙芒硝以及天青石等,或聚集成为具有一定厚度的盐层,或以矿物颗粒形式赋存于基质碳酸盐岩中。上部的盐间油层组的盐层较厚,以石盐为主,下部的盐下油层组的盐层较薄,以石膏为主;(2)盐类矿物“低锰”的元素地球化学特征、与盐类矿物伴生的基质碳酸盐岩具有的“低温成因”的碳氧同位素地球化学特征、未见热液矿物发育的岩石学特征以及分布面积极广的平面展布特征均显示了盐类矿物为典型的咸化湖盆沉积型,而非热液卤水析出型;(3)“盐”在油气成藏过程中发挥着重要作用,包括盐类矿物对裂缝的充填和防止油气逸散的封堵作用、盐层因具有很高的毛管突破压力和塑性特征而具有良好的封盖作用、地层条件下促进白云岩次生孔隙发育的作用以及占据一定的储集空间的消极作用等。这一研究成果可为盐下湖相碳酸盐岩的油气勘探提供重要的指导作用。 相似文献
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