Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River     

Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,  相似文献   

川中丘陵区土壤颗粒分形特征     

林正雨邓良基  高雪松 《山地学报》2006,24(B10):120-125

分析了27个紫色土丘陵区土壤样品的机械组成，运用分形模型计算出土壤颗粒分形维数D（D=2．817—3．030），探讨了分形维数D与土壤粒度组成、土壤抗蚀性之间的关系，并分析了不同土地利用方式下土壤颗粒分形维数D与土壤有机质含量（O．M）、土壤容重（B.D）的相关关系。研究表明：土壤颗粒分形维数D能够很好的表征土壤质地，重点反映〈0．05mm的细颗粒物质，尤其是粘粒，其次是粉粒；与土壤有机质含量（O．M）、土壤容重（B．D）均达到极显著水平；其次分形维数D还能作为评价土壤水土流失和土壤生态恢复的指标。  相似文献   

大气CO2浓度升高对土壤中不同粒级碳的影响   总被引：4，自引：0，他引：4  

马红亮朱建国  谢祖彬刘钢 曾青 《亚热带资源与环境学报》2006,1(1):33-40

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．  相似文献   

应用PIV系统研究横流中近壁水平圆柱绕流旋涡特性   总被引：9，自引：0，他引：9       下载免费PDF全文

吴剑  齐鄂荣  李炜  黄明海  李国亚 《水科学进展》2005,16(5):628-633

应用粒子图像测速(PIV)系统对横流中近壁水平圆柱绕流进行了试验研究。介绍了试验原理及装置,讨论了试验参数的选取和粒子的跟随性问题。分析了上游来流的流动特性,显示了亚临界雷诺数下间隙比为0.5时圆柱后尾流区旋涡产生、发展和消亡的动态过程,比较了时均流场和瞬时流场旋涡结构。对圆柱尾迹的旋涡脱落特性进行了分析,得出在试验条件下斯特劳哈尔数保持为常数0.2的结论。  相似文献   

Particle size dependent response of aerosol counters     

A. Ankilov  A. Baklanov  M. Colhoun  K. -H. Enderle  J. Gras  Yu. Julanov  D. Kaller  A. Lindner  A. A. Lushnikov  R. Mavliev  F. McGovern  T. C. O'Connor  J. Podzimek  O. Preining  G. P. Reischl  R. Rudolf  G. J. Sem  W. W. Szymanski  A. E. Vrtala  P. E. Wagner  W. Winklmayr  V. Zagaynov 《Atmospheric Research》2002,62(3-4)

During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles.  相似文献   

Natural hydraulic cracking: numerical model and sensitivity study   总被引：2，自引：0，他引：2  

Xiaorong Luo 《Earth and Planetary Science Letters》2002,201(2):431-446

Natural hydrofracturing caused by overpressure plays an important role in geopressure evolution and hydrocarbon migration in petroliferous basins. Its mechanism is quite well understood in the case of artificial hydraulic fracturing triggered by high-pressure fluid injection in a well. This is not so for natural hydraulic fracturing which is assumed to initiate as micro-cracks with large influence on the permeability of the medium. The mechanism of natural hydraulic cracking, triggered by increasing pore pressure during geological periods, is studied using a fracturing model coupled to the physical processes occurring during basin evolution. In this model, the hydraulic cracking threshold is assumed to lie between the classical failure limit and the beginning of dilatancy. Fluid pressure evolution is calculated iteratively in order to allow dynamic adjustment of permeability so that the fracturing limit is always preserved. The increase of permeability is interpreted on the basis of equivalent fractures. It is found that fracturing is very efficient to keep a stress level at the rock’s hydraulic cracking limit: a fracture permeability one order of magnitude larger than the intrinsic permeability of the rock would be enough. Observations reported from actual basins and model results strongly suggest that natural hydraulic cracking occurs continuously to keep the pressure at the fracturing limit under relaxed stress conditions.  相似文献   

银川市初夏气溶胶粒子谱分布特征   总被引：4，自引：5，他引：4  

桑建人  杨有林 《中国沙漠》2003,23(3):328-330

利用美制APS—3310A型激光粒谱仪，在中国西北城市银川对大气气溶胶粒子进行现场观测，结合气象条件，并通过理论计算分析，给出了银川市初夏大气气溶胶的日变化特征、3种不同粒径粒子分布特点及飘尘谱分布特征，以期为银川市大气污染总量控制方案及对策提供科学依据。  相似文献   

粘粒含量对南京粉细砂液化影响的试验研究   总被引：16，自引：1，他引：16  

刘雪珠  陈国兴 《地震工程与工程振动》2003,23(3):150-155

南京粉细砂是一种以片状颗粒成分为主的粉细砂，与通常的圆形颗粒石英砂有一定区别，片状颗粒成分使得南京粉细砂具有各向异性的性质。通过对不同粘粒含量的南京粉细砂进行液化试验，分析其试验结果发现：对于粘粒含量ρc＝5％、10％和15％三种情况，在均压固结情况下，当南京粉细砂达到初始液化时，采用变形标准和孔压标准是一致的；而偏压固结时，只能采用变形标准作为南京粉细砂达到初始液化的标准，此时振动孔压仅达到围压的50％-70％。粘粒含量对南京粉细砂的抗液化强度影响很大，随粘粒含量增加，在不同固结比时，其抗液化强度并不是单调变化，而是在粘粒含量ρc＝10％左右处于一个低谷，其抗液化强度最低。  相似文献   

Comparison of the Langrangian Footprint     

N. Kljun  R. Kormann  M. W. Rotach  F. X. Meixer 《Boundary-Layer Meteorology》2003,106(2):349-355

We compare flux and concentration footprint estimates of athree-dimensional Lagrangian stochastic dispersion modelapplying backward trajectories with the results of ananalytical footprint model by Kormann and Meixner.The comparison is performed for varying stability regimesof the surface layer as well as for different measurementheights. In general, excellent correspondence is found.  相似文献   

铂族元素迁移富集机理的新探   总被引：2，自引：1，他引：2  

郑大中 《四川地质学报》1997,(2)

在岩浆及高温热液中，拍族元素以纳米液态铂族元素单质、铂族元素与其它金属元素的纳米液态合金、纳米液态铂族元素的硫、砷化物迁移。在中、低温热液及表生条件下，除呈上述固态纳米铂族矿物随流体迁移外，还呈配合物形式迁移。然后它们在合适的条件下沉淀富集形成矿床。此外，还讨论了铂族元素与金地球化学条件的异同。  相似文献