Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems     

R.E. Villanueva  R.M. Prol-Ledesma  M.A. Torres-Vera  C. Canet  M.A. Armienta  C.E.J. de Ronde 《Journal of Geochemical Exploration》2006,89(1-3):414

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.  相似文献   

Water chemistry and water quality variation in the Danjiangkou Reservoir, as a function of water management for the Middle Route of South to North Water Divert Project, China     

Siyue LI Quanfa ZHANG 《中国地球化学学报》2006,25(B08):274-274

As the diversion dike of the Middle Route of the South to North Water Transfer Project （MRSNWTP）, the water quality and water quantity of Danjiangkou Reservoir is critical to the project. At present, the rates of industrial wastewater treatment and sewage discharge, which belongs to Chinese State Standard in the districts near the reservoir except Shiyan city, are less than 60% and 40% respectively. The point source pollutants will be controlled because of the project after some time, but the non-point source pollutants caused by vegetation degradation and water-soil erosion will not be controlled effectively in a long time. Water samples were collected from the Danjiangkou Reservoir during 2004 and 2005 and analyzed for trace metals, i.e., silver （Ag）, aluminum （Al）, arsenic （As）, barium （Ba）, bismuth （Bi）, calcium （Ca）, cadmium （Cd）, cobalt （Co）, chromium （Cr）, copper （Cu）, iron （Fe）, mercury （Hg）, potassium （K）, lithium （Li）, magnesium （Mg）, manganese （Mn）, molybdenum （Mo）, sodium （Na）, nickel （Ni）, lead （Pb）, antimony （Sb）, selenium （Se）, silicon （Si）, strontium （Sr）, vanadium （V）, zinc （Zn）, chemicophysical parameters and nutrients, i.e., temperature （T）, pH, dissolved oxygen （DO）, turbidity, total suspended solid （TSS）, nitrate/ammonia/ammonium-nitrogen （NO3^-/NH3/NH4^＋-N）, total nitrogen （TN）, dissolved inorganic nitrogen （DIN）, total phosphorus （TP）, potassium permanganate index （IMn）, biochemical oxygen demand （BOD）, dissolved inorganic carbon （HCO3^-）. Our results are water quality belongs to Chinese standard level II, trace metals are low, but they are accumulating, and many of which, i.e., As, Pb, will endanger reservoir water security.  相似文献   

Effect of heat treatment on tourmaline from Brazil   总被引：4，自引：0，他引：4  

Cristiane Castañeda  Sigrid G. Eeckhout  Geraldo Magela da Costa  Nilson F. Botelho  Eddy De Grave 《Physics and Chemistry of Minerals》2006,33(3):207-216

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.  相似文献   

Avalanche Risk During Backcountry Skiing – An Analysis of Risk Factors     

Harpa Grímsdóttir  David Mcclung 《Natural Hazards》2006,39(1):127-153

Skier-triggered avalanches are the main cause of avalanche accidents in backcountry skiing. The risk of accidents during backcountry skiing was analysed statistically and related to factors such as elevation level, aspect, stability rating and the time of the year. The analysis is based on a database about terrain usage and avalanche accidents from a large heli-skiing operator in Canada, which makes it possible to study the conditional probability of accidents given the recorded pattern of terrain usage. This study shows that the historical risk of accidentally triggering an avalanche greater than size 1 depends highly on the stability rating, with the highest risk occurring during “poor” stability. The risk is greater at high elevations, and it is lower during the late season than earlier on. Skier risk does not depend as much on aspect as may be indicated from avalanche data alone. However, it is relatively high in the N–NE–E sector. These factors are not independent of each other and therefore analyses of combined factors were also performed. Questionnaires and interviews were used to gain knowledge about the terrain selection of professional mountain guides. These results indicate that when selecting terrain, guides first look at the overall shape and size of the terrain, but avalanche history of terrain and inclination are also important factors. Finally, remarks in avalanche reports were analysed, and common human factors identified.  相似文献   

Cyclicity in the Main and Upper Zones of the Bushveld Complex, South Africa: Crystallization from a Zoned Magma Sheet   总被引：9，自引：0，他引：9  

TEGNER  CHRISTIAN; CAWTHORN  R. GRANT; KRUGER  F. JOHAN 《Journal of Petrology》2006,47(11):2257-2279

The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock ⁸⁷Sr/⁸⁶Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial ⁸⁷Sr/⁸⁶Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetite–ilmenite–apatite)layers and changes up-section from gabbronorite (An₇₂ plagioclase;Mg# 74 clinopyroxene) to magnetite–ilmenite–apatite–fayaliteferrodiorite (An₄₃; Mg# 5 clinopyroxene; Fo₁ olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V₂O₅ of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO₂ and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO₂ and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation  相似文献   

内蒙乌拉山金矿床钾长石的矿物化学及有序度的分析   总被引：2，自引：0，他引：2       下载免费PDF全文

胡萍赵令湖  边秋娟 《岩石矿物学杂志》2005,24(3):221-230

采用电子探针显微分析(EMPA)和粉末X射线衍射(XRD)分析了采自乌拉山金矿床含金钾长石石英脉、石英脉以及其他类型岩石中的10 0多个钾长石样品的化学成分和结果状态,并采用R和Q模式聚类分析、Spearman等级相关分析方法对实验数据进行了统计分析。结果表明,含金矿脉、岩浆热液脉和蚀变花岗岩中的钾长石为中等到最大微斜长石,其特征为K2 O含量高,但相对而言,Na2 O、CaO和BaO的含量低。其他岩石类型中的钾长石的化学成分和结果状态变化很大,可以从透长石、正长石到微斜长石,其特征为K2 O的含量相对较低,但Na2 O、CaO和BaO的含量相对较高。含金样品中的钾长石通常更富K2 O ,表明金的成矿作用与富钾的热液流体和碱质交代作用有关。乌拉山金矿床的成矿作用分为两个阶段,主要的含金钾长石石英脉中的钾长石富K2 O ,形成温度为30 7～379℃,平均为35 3℃;第二阶段含金石英脉中的钾长石含K2 O较低,形成温度为2 6 0～318℃,平均为2 81℃。这些结果表明成矿流体与岩浆热液作用有关,流体朝温度降低、K2 O含量降低的方向演化,K2 O含量高的热液流体和2 6 0～380℃的形成温度有利于金的成矿作用。  相似文献   

中国大陆科学钻探工程主孔榴辉岩的岩石学研究   总被引：19，自引：0，他引：19       下载免费PDF全文

张泽明张金凤  许志琴刘福来杨经绥  肖益林沈 昆 《中国地质》2005,32(2):205-217

中国大陆科学钻探工程5000m主孔位于苏鲁超高压变质带南部。该钻孔0～2000m主要由榴辉岩、片麻岩、石榴石橄榄岩和少量片岩和石英岩组成。累积厚度达1000多米的榴辉岩具有不同的矿物组成、不同的矿物含量和不同的全岩化学成分,可划分成富Si的石英榴辉岩、富Ti的金红石榴辉岩、富Al的多硅白云母和蓝晶石榴辉岩、富Mg的双矿物榴辉岩和具有正常玄武岩成分的普通榴辉岩。榴辉岩的原岩包括基性层状侵入岩和变质表壳岩。榴辉岩全岩成分对石榴石和绿辉石中某些化学组分的含量有明显控制,而且直接影响到变质条件估算的准确性。扩散成分环带的广泛发育表明超高压矿物在早期退变质过程中发生了成分再平衡。这一事实以及具有成分生长环带石榴石变斑晶的存在,为榴辉岩形成在更高温度(>940℃)和更高压力(>4.5GPa)条件下提供了有力的证据。  相似文献   

中国南极长城站1998年大气降水化学特征的初步研究   总被引：3，自引：0，他引：3  

于晓岚  汤洁  师昱锋  程红兵  王国贵 《气象学报》2002,60(4):494-501

文中报告了 1998年 1～ 12月 ,在中国南极长城站 (6 2°13′S ,5 8°5 8′W ,海拔 10 .0m)采集的 115个有效降水样品的 pH值、电导率和化学组分分析结果。长城站地区降水的年平均 pH值为 5 .6 2 ,电导率年平均值为 85 .16 μS/cm。秋季期间降水的 pH值和电导率较高 ,其它季节较低。降水中最主要的离子为Cl-,Na+ ,其他离子按平均浓度值依次排列为SO42 -,Mg2 + ,Ca2 + ,K+ ,NO3 -,NH4+ 。除NO3 -,NH4+ 外 ,各主要离子浓度间呈显著正相关 ,表明其来源具有同一性。降水样品的离子组成比例与周围海区的海水接近 ,显示了海盐是降水中可溶性离子的主要来源 ,而其它源只对Ca2 + 有一定贡献。该地区的降水具有较典型的海洋性降水的化学特征  相似文献   

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?     

Sandro Fuzzi  Maria Cristina Facchini  Stefano Decesari  Emanuela Matta  Mihaiela Mircea 《Atmospheric Research》2002,64(1-4)

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.  相似文献   

柯树背岩体的元素地球化学特征及其成矿意义   总被引：1，自引：0，他引：1  

胡恭任  陈培荣等 《地质与勘探》2002,38(6):25-29

对柯树背岩体的岩石化学，稀土元素，微量元素及铀金成矿元素进行了系统的研究。研究结果表明：柯树背岩体F9大断裂（鹰潭－安远深大断裂）以东部分（东体）与F9大断裂以西部分（西体）在稀土分布模式，微量元素，铀金成矿元素及矿化特征上存在很大的差别，东体与寨背岩体类似，为同熔系列花岗岩，对铀成矿不利；西体为重熔再生岩浆成因的改造型花岗岩，对铀成矿有利，具有良好的成矿远景。  相似文献