谷氨酸插层水滑石组装、包裹及缓释性能研究     

潘国祥  曹枫  郑卫红  陈海锋  唐培松  罗阳坡  袁彩君 《矿物学报》2012,32(3):455-460

采用共沉淀法和离子交换法实现了谷氨酸与Zn/Al水滑石的插层组装,并采用X射线粉末衍射、差热分析、红外光谱表征了谷氨酸插层水滑石的结构,并在模拟胃液和肠液中测试了复合材料中谷氨酸的缓释性能。结果表明,合成的水滑石前躯体（LDHs-NO3）结构规整、晶相单一,层间距为0.879 nm;2种方法合成的谷氨酸插层水滑石,其层间距分别增加到1.251 nm和1.334 nm,可以推测谷氨酸以垂直方式分布于水滑石层间。插层后水滑石样品在1588 cm-1和1346 cm-1处出现了谷氨酸中羧酸根的不对称伸缩振动和对称伸缩振动峰,也佐证了氨基酸插层成功。谷氨酸插层水滑石后,其热稳定性大大提高,热分解温度由230℃升高至397～434℃。与物理混合法相比,谷氨酸与水滑石复合后增加了谷氨酸的耐酸性,使其具有较好的缓释性能。谷氨酸释放曲线符合Bhaskar方程,表明微粒间的扩散作用是谷氨酸分子释放的限速步骤。LDHs-Glu经海藻酸钠包裹后,在模拟肠液中缓慢释放而在模拟胃液中不释放,起到了肠液定向释放的效果。  相似文献   

电感耦合等离子体发射光谱法测定铝土矿中镓——酸溶和碱熔预处理方法比较   总被引：4，自引：3，他引：1  

文加波  商丹  宋婉虹  彭国萍 《岩矿测试》2011,30(4):481-485

研究了盐酸-硝酸-氢氟酸-高氯酸酸溶和氢氧化钠碱熔两种测定铝土矿石样品中镓的前处理方法,利用电感耦合等离子体发射光谱法(ICP-AES)进行测定。对熔矿试剂及条件、分析谱线的选择和元素的干扰进行了讨论,采用不同含量的铝土矿石国家标准物质样品进行了条件实验。分析结果表明:采用盐酸-硝酸-氢氟酸-高氯酸溶解样品,会导致铝土矿石样品溶解不完全,得到的数据失真;而采用氢氧化钠碱熔法处理铝土矿石样品后,用ICP-AES法测定,镓的测定值准确度高,方法检出限为0.15μg/g,相对标准偏差(RSD,n=11)为2.51%～5.97%,回收率为94.8%～108.2%。该方法灵敏度高,精密度好,分析时间短,易于流程操作。方法经国家一级标准物质分析验证,测定结果与标准值相符,特别适用于铝土矿石样品中镓的测定。  相似文献   

高铝粉煤灰碱溶法制备氢氧化铝的研究     

苏双青  马鸿文  邹丹  李歌 《岩石矿物学杂志》2011,30(6):981-986

实验研究了采用两步碱溶法从高铝粉煤灰中提取氢氧化铝的可行性。首先采用浓度为8 mol/L的NaOH溶液,在95℃的条件下溶出高铝粉煤灰中部分非晶态SiO2;所得脱硅粉煤灰再与适量CaO混合均匀,在260~280℃下以浓度18~20 mol/L的NaOH溶液溶出Al2O3,得到高苛性比的铝酸钠溶液;经降低苛性比、脱硅和碳酸化分解,制得氢氧化铝制品。化学成分分析结果表明,该氢氧化铝制品符合GB/T 4294-1997规定的一级标准。与其他从高铝粉煤灰中提取氧化铝的工艺相比,该方法避免了粉煤灰原料的高温烧结过程,生产能耗显著降低,加工过程的环境相容性良好。  相似文献   

白云岩酸解法制备轻质氧化镁和碳酸钙实验研究   总被引：1，自引：0，他引：1  

姚文贵  马鸿文  姜晓谦  刘玉芹 《现代地质》2011,25(1):151-156

以河南卢氏县黄跃沟纯质白云岩为原料,利用盐酸进行分解,制得MgCl2-CaCl2溶液。经过通氨气调节pH值除铁、氨化反应、陈化反应以及碳化反应等过程,制备轻质氧化镁和轻质碳酸钙,研究氨化过程中温度和时间对Mg2+沉淀率的影响,以及碳化时间对碳酸钙制品晶型的影响。采用化学分析方法和扫描电镜分析对制品进行表征,结果表明:轻质氧化镁制品颗粒形貌呈片状,粒径为150 nm左右,其性能达到HG/T2573—2006优等品标准;轻质碳酸钙制品颗粒形貌呈球状,粒径为100 nm左右,其性能达到HG/T2567—1994优等品的标准。实验采用的工艺路线具有能耗低、白云石资源利用率高、加工过程符合清洁生产要求等优点,是白云岩资源高效利用的有效途径之一。  相似文献   

电感耦合等离子体发射光谱法测定含刚玉的铝土矿中硅铝铁钛   总被引：5，自引：5，他引：0  

王琰  孙洛新  张帆  张华  陈志慧 《岩矿测试》2013,32(5):719-723

铝土矿具有较强的化学稳定性,常含有少量刚玉,属于比较难处理的样品。常用的四酸溶解法对不含刚玉的铝土矿能取得较好的效果,但对高铝及含刚玉的样品分解不完全且无法同时测定硅。本文对含刚玉的铝土矿样品在镍坩埚中用氢氧化钠-过氧化钠熔融,盐酸酸化后用电感耦合等离子体发射光谱法同时测定硅铝铁钛四种元素。对氢氧化钠-过氧化钠的熔样效果、过氧化钠用量、熔样温度、共存离子的影响及基体干扰进行了试验,结果表明,加入3.0 g氢氧化钠和1.0 g过氧化钠在650~700℃保温10 min,能较好地熔解含少量刚玉的铝土矿样品。利用铝土矿标准物质制备标准溶液,可消除镍坩埚和熔融试剂产生的镍盐和钠盐基体对硅铝铁钛测定的干扰。方法检出限为0.0025%~0.063%,精密度小于4%。铝土矿国家标准物质的测定值与标准值相符,实际样品的测定值与其他分析方法的测定值相吻合。本方法样品分解完全,消解时间短,分析步骤简单,适用于高铝及含少量刚玉的铝土矿样品分析。  相似文献   

Occurrence and characteristics of sporadic sodium layer observed by lidar at a mid-latitude location     

S. S. Gong  G. T. Yang  J. M. Wang  B. M. Liu  X. W. Cheng  J. Y. Xu  W. X. Wan 《Journal of Atmospheric and Solar》2002,64(18)

Na lidar observations of SSL during the past 5 years at a mid-latitude location (Wuhan, China, 31°N, 114°E) are reported in this paper. From 26 SSL events detected in about 230 h of observation, an SSL occurrence rate of 1 event/9 h at our location was obtained. This result, combined with that reported by Nagasawa and Abo (Geophys. Res. Lett. 22 (1995) 263) at Tokyo, Japan, reveals that the SSL occurrence can be relatively frequent at some mid-latitude locations. The statistical analyses of main parameters for the 26 SSL events were made, and the results were compared with those previously reported. By examining the corresponding data from a nearby ionosonde, it was found that there was a fairly good correlation between SSL and Es. Of the 18 pairs of SSL and Es events checked, 15 of SSL were accompanied by Es, and 8 pairs of them were correlated within 1 h in time and within 5 km in altitude. From the analyses of observed perturbations during SSL development, the role of dynamic processes of atmosphere in the SSL formations were emphasized.  相似文献   

表面活性剂的应用研究—：——动力学光度法测定痕量硒蹄   总被引：3，自引：0，他引：3  

管希云  李玉珍 《岩矿测试》2000,19(1):14-19

研究了表面活性剂在Ｓｅ和Ｔｅ诱导反应中的作用,对反应机理进行了初步探讨。实验表明,在选定条件下,加入适量非离子表面活性剂Ｔｗｅｅｎ－８０,使Ｔｅ的诱导反应速度加快,灵敏度提高１倍,并利用其对Ｓｅ有抑制反应速度的作用,使Ｔｅ对Ｓｅ的抗干扰能力增强。阴离子表面活性剂十二烷基苯磺酸钠对Ｓｅ和Ｔｅ均有加速反应的作用,Ｓｅ的灵敏工提高１．３倍：Ｔｅ的灵敏主提高４０％。基于此,所建立的中用于地质样品中纳克级Ｓ  相似文献   

钝顶螺旋藻营养生理的研究 I：钝顶螺旋藻对无机碳的吸收利用     

Zhang Xuecheng 《中国海洋大学学报(自然科学版)》2000,30(Z1):173-178

碳源对于进行光合作用的各种藻类是必不可少的。螺旋藻的生 态习性是在高pH环境下生长,因此螺旋藻碳代谢的研究有特殊的意义。文中报道了螺旋藻对 无机碳的吸收利用以及与其生长的关系,结果表明螺旋藻培养基中碳酸氢钠的浓度50～100mm ol/dm3时,不仅可以满足螺旋藻生长的需要,而且有助于保持藻体生长的pH值。结果还表 明适当添加碳酸氢氨有利于螺旋藻的生长。  相似文献   

Short timescale variability of the mesospheric sodium layer     

C. O'Sullivan  R. M. Redfern  N. Ageorges  H.-C. Holstenberg  W. Hackenberg  T. Ott  S. Rabien  R. Davies  A. Eckart 《Experimental Astronomy》2000,10(1):147-156

In this article we investigate the short-term characteristics of the sodium layer and their implications for laser guide star systems. We report measurements of sodium density andcentroid-height variations on timescales of 100 ms upwards. Significant centroid-height variations on short timescales may necessitate frequent refocussing of the beam and wavefront sensor system.We present results from observations of the mesospheric sodium layer taken at the Max Planck observatory in Calar Alto, Spain in September 1997 and August 1998. We describe our experiment which uses the resonant optical backscatter of 589.2 nm laser light from the upper atmosphere as a measure of sodium abundance.Short-term variations are dominated by the formation of dense sporadic layers in the normal sodium layer. Measurements were made on 3 nights in 1997 and on 2 nights in 1998. Somewhat unexpectedly for a mid-latitude site, sporadic sodium layers were seen on 4 of these 5 nights. One of the sporadic layers was observed for its duration. The 2 km wide layer reached a maximum intensity of approximately two and a half times that of the background layer and could be distinguished from the background for over five hours. Centroid height variations of up to 400 m were observed on timescales of 1–2 min. In 1998 we were sensitive to variations of 5% or more in total sodium abundance on timescales of 100 ms upwards. We found no evidencefor variations of this level on these short timescales.  相似文献   

The Ultimate CCD for Laser Guide Star Wavefront Sensing on Extremely Large Telescopes     

James W. Beletic  Sean Adkins  Barry Burke  Robert Reich  Bernie Kosicki  Vyshnavi Suntharalingham  Charlie Bleau  Ray DuVarney  Richard Stover  Jerry Nelson  Francois Rigaut 《Experimental Astronomy》2005,19(1-3):103-109

All of the extremely large telescopes (ELTs) will utilize sodium laser guide star (LGS) adaptive optics (AO) systems. Most of these telescopes plan to use the Shack-Hartmann approach for wavefront sensing. In these AO systems, the laser spots in subapertures at the edge of the pupil will suffer from spot elongation due to the 10 km extent of the sodium layer and the large separation from the projection laser. This spot elongation will severely degrade the performance of standard geometry wavefront sensing systems. In this paper, we present a CCD with custom pixel morphology that aligns the pixels of each subaperture with the radial extension of the LGS spot. This CCD design will give better performance than a standard geometry CCDs for continuous wave lasers. In addition, this CCD design is optimal for a pulsed sodium laser. The pixel geometry enables each subaperture to follow a laser pulse traversing the sodium layer, providing optimal sampling of a limited number of detected photons. In addition to novel pixel layout, this CCD will also incorporate experimental JFET sense amplifiers and use CMOS design approaches to simplify the routing of biases, clocks and video output. This CCD will attain photon-noise limited performance at high frame rates, and is being incorporated in the plans for the Thirty Meter Telescope (TMT).  相似文献