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61.
Abstract: Pyrite rich in Zn, up to 3.1 wt%, was found in the TAG active mound of the TAG hydrothermal field, the slow-spreading Mid-Atlantic Ridge at 26°08'N and 44°49'W. The Zn-rich pyrite is characterized by an optical homogeneity, a homogeneous distribution of Zn in the back-scattered electron images, both at a magnification of about 500, a negative correlation between Fe and Zn contents of the pyrite and a rather small unit cell edge (a0 = 5.4117 ± 0.0008Å), strongly indicating that the detected Zn is present in the pyrite in solid solution. Such Zn concentrations are observed exclusively in dendritic pyrite, suggesting that the Znrich pyrite grew from hydrothermal fluids of a high degree of supersaturation due to quenching on the seafloor.  相似文献   
62.
Organic-rich samples derived from a Middle Cambrian Formation in the Georgina Basin, and from the Middle Proterozoic of the McArthur Basin in northern and central Australia, yielded alginite ranging from immature oil shale material to overmature residue. A maturation scale has been developed based on the thermal evolution of alginite as determined from reflectance and fluorescence. The coalification path of alginite is marked by jumps in contrast to the linear path of wood-derived vitrinite. Six zones have been recognised, ranging from undermature (zone I), through the mature (zones II/III), followed by a stable stage of no change (zone IV) to the overmature (zones V and VI). The onset of oil generation in alginite as evident from the present study is at 0.3% Ro Alg. and is expressed in a change of fluorescence from yellow to brown, and a coalification jump from 0.3 to 0.6% Ro of Alg. In many boreholes zone III can be distinguished between 0.6 and 0.8% Ro of Alg. where subsequent oil generation occurs. Zones II and III represent the oil window.A zone of little or no change designated zone IV, at of alginite follows zones II/III. A marked coalification jump characterises zone V, where a pronounced change in reflectance occurs to >1.0% Ro Alg., signifying peak gas generation. The border of oil preservation lies at the transition of zone V and VI, at 1.6% Ro Alg. In zone VI gas generation only occurs.Comparison of reflectance results with experimental and geochemical pyrolysis data supports high activation energies for hydrocarbon generation from alginite, and therefore a later onset of oil generation than other liptinite macerals (i.e. cutinite, exinite, resinite) as well as a narrow oil window.Transmission electron microscopy (TEM) confirms that alginite does not go through a distinct intermediate stage but that the percentage of unreacted organic matter decreases as maturation proceeds. A clear distinction can be made in TEM between immature alginite, alginite after oil generation, and alginite residue following gas generation. Alginite beyond 1.6% Ro acquires very high densities and the appearance of inertinite in TEM.Bitumens/pyrobitumens make a pronounced contribution to the organic matter throughout the basins and have been shown to effect pyrolysis results by suppressing Tmax. The bitumens/pyrobitumens have been divided into four groups, based on their reflectance and morphology, which in turn appears to be an expression of their genetic history. Their significance is in aiding the understanding of the basins' thermal history, and the timing of oil and gas generation.  相似文献   
63.
A horizontal saltation layer of glass particles in air is investigated experimentally over a flat bed and also over a triangular ridge in a wind tunnel. Particle concentrations are measured by light scattering diffusion (LSD) and digital image processing, and velocities using particle image velocimetry (PIV). All the statistical moments of the particle concentration are determined such as mean concentration, root mean square concentration fluctuations, skewness and flatness coefficients. Over the flat bed, it is confirmed that the mean concentration decreases exponentially with height, the mean dispersion height being a significant length scale. It is shown that the concentration distribution follows quite well a lognormal distribution. Over the ridge, measurements were made at the top of the ridge and in the cavity region and are compared with measurements without the ridge. On the hill crest, particles are retarded, the saltation layer decreases in thickness and concentration is increased. Downwind of the ridge, particle flow behaves like a jet, in particular no particle return flow is observed. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
64.
C18固相膜萃取-气相色谱法测定饮用水中12种有机氯农药   总被引:13,自引:10,他引:13  
利用C18固相萃取膜提取水样,气相色谱法(电子捕获检测器)测定饮用水中12种有机氯农药。对洗脱液、水样pH值、萃取压力等条件进行了优化选择,并与液-液萃取做了比较。结果表明,与液-液萃取相比,固相膜萃取具有操作简单、富集倍数高、节省溶剂和耗时短等优点,是萃取水中有机氯农药的有效方法。12种有机氯农药的回收率为85.97%~127.7%,相对标准偏差(RSD,n=5)为4.74%~12.2%,方法检出限为0.014~0.047μg/L。  相似文献   
65.
Euphotic depth can be defined as the portion of wa- ter column that supports the net primary productivity. Its lower end is the critical depth, namely, the depth measured when the daily net primary productivity is zero[1]. In the ecosystems of oceans, lakes and rivers, phytoplankton live in the euphotic depth and euphotic depth is usually taken as the lower boundary, when studying the primary productivity and biomass of phytoplankton; therefore the corresponding depth is sometimes called the t…  相似文献   
66.
辽宁深井承压水位潮汐响应函数的初步研究   总被引:1,自引:0,他引:1  
介绍了辽宁省地震水动态监测网19口井固体潮汐响应函数的计算结果,基于M2波潮汐因子及其月离散相对误差,分析了各观测井潮汐响应函数对地壳应变的响应灵敏度、潮汐因子的动态稳定性和监测效能。结果表明:在所列19口观测井中,如果以M2波潮汐因子0.2m/10-9作为潮汐响应幅值的下限,则除甘沟子以外的18口井可用于潮汐响应函数的研究;如果以M2波潮汐因子的月离散相对误差20%作为选择观测井的上限,则除瓦房店楼房井、岫岩1井、周家井、丹东变电所井、牛四井、容2井和阜新市甘沟子等井以外的12口井可用于潮汐参数的动态特征研究。  相似文献   
67.
宁波地震台数字垂直摆倾斜仪记录的EW、NS向固体潮在同一数量级,与理论固体潮有较大的差异,且与浙江省其它地区地震台的记录迥然不同。该台倾斜资料与海水潮汐关系密切,用其分钟值绘出的矢量图日规律性较强。本文对此作了初步分析与探讨。  相似文献   
68.
龙门山国家地质公园飞来峰成因的新证据   总被引:1,自引:0,他引:1  
周自隆  阮明德 《地质论评》2006,52(4):501-509
近来发现四川彭州(原称彭县)、什邡一带的飞来峰是第四纪冰川作用形成的。笔者等在塘坝子、葛仙山等飞来峰的底界及周边,多次发现飞来峰是压在早更新世的冰水堆积层之上。葛仙山北寨门、丁家湾,什邡大垭口等剖面的地质现象,充分说明塘坝子、葛仙山等飞来峰是第四纪中更新世时“飞”来,压盖上去的。同时可见飞来峰与第四系之间是“冷接触”,找不到确切的断层证据。笔者等还用现有的区域地质调查资料及新的地质成果,编制了1:10万更新世时的彭县至汶川的地质剖面图,并设想了冰雪层掩盖情况。那时岷江尚未剥蚀下切,按现在标高计的5000m处,即在光光山、太子城之上约1000m的“天”上。当时应在该处出露的石炭系-二叠系石灰岩,就是塘坝子、葛仙山飞来峰的根部。塘坝子、葛仙山就是从那里被冰川作用剪切、从母体分离的石灰岩,滑动、随冰川固体流,滑移到彭县来的。笔者还从理论上阐述了塘坝子、尖峰顶、天台山等如此巨大的山体,能被冰川作用拔起、挖掉、推走的原因和根据。从而解释了飞来峰“飞”行的过程。顺理成章,合乎自然,揭开了飞来峰之迷。  相似文献   
69.
Windos XP版储量计算程序是作者90年代DOS版的全面升级。该程序按照目前地质工作普遍采用的公式和做法,符合现行规范规定和要求。程序对储量计算中矿体圈定等难点解决较好。该程序已经多个矿区应用检验,最近又为南非英铂公司采用推广。  相似文献   
70.
鄂尔多斯盆地能源矿产氯仿沥青Sm-Nd同位素研究   总被引:2,自引:0,他引:2       下载免费PDF全文
对鄂尔多斯盆地石油、煤、含铀砂岩及其围岩的氯仿沥青进行了Sm-Nd同位素研究。结果表明,盆地流体(包括深部流体)活动具有多期性,且后期的流体活动对铀矿床的形成具有重要作用;赋存于同一套地层中的含铀砂岩沥青、煤沥青及石油沥青,虽然均具有富集地幔特征,但并非同期活动的产物;东胜矿区侏罗系直罗组煤沥青和盆地西南部陈家山矿区侏罗系延安组的煤沥青,源区时代上存在较大差异,伴生沥青并非全部由煤的热演化形成,可能还存在外来流体的加入,且东胜直罗组煤的伴生沥青较延安组煤的伴生沥青来源深度更大;盆地内马岭油田的直罗组石油沥青、陈家山延安组煤层石油沥青及其煤沥青在源区特征上具有内在联系。  相似文献   
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